ES2715660T3 - Use of an active carboxamide derivative as a soil pesticide and seed application and treatment methods - Google Patents

Abstract

Use of the active compound pesticide carboxamide of formula (I): ** Formula ** or tautomers, enantiomers, diastereomers or salts thereof, wherein the active compound I of formula (I) is combined and / or applied together with at least one other compound active in agricultural function selected from the group of insecticides and / or fungicides consisting of fluxapiroxad, epoxiconazole, triticonazole, abamectin, emamectin, canthanyliprole, chlorantraniliprole, thiacloprid to control and / or combat animal pests in application methods in the soil and in the seed treatment methods, wherein the active compound of formula (I) is applied directly and / or indirectly to the plant and / or to the plant propagation material soaking the soil, by drip application in the soil, by soil injection, by immersion or by seed treatment.

Description

DESCRIPTION

Use of an active carboxamide derivative as a pesticide in the soil and methods of application and treatment of seeds.

The present invention relates to the use of a carboxamide compound of formula (I) combined and / or applied together with at least one other agriculturally active compound selected from the group of insecticides and / or fungicides consisting of fluxapiroxad, epoxiconazole, triticonazole, abamectin, emamectin, ciantraniliprole, chlorantraniliprole, thiacloprid to control live pests in the soil by methods of application in the soil such as soaking, drip application, application in furrows, application by immersion or injection into the soil or by seed treatment.

The present invention further relates to a method for the protection of plant propagation material with said combination of compounds and to the seeds of transgenic plants comprising said combination.

Pests of invertebrates, arthropods and nematodes, and in particular insects and arachnids, destroy growing and harvested crops and attack wooden homes and commercial structures, causing large economic losses in food supply and property. While a large number of pesticidal agents are known, due to the ability of the target pests to develop resistance to such agents, there is a constant need for new agents to combat invertebrate pests such as insects, arachnids and nematodes.

Especially pests that live in the soil, arthropod pests, including insects and arachnids that live in the soil, and especially mites and nematodes, are often controlled and fought by applying an effective amount of a suitable pesticide compound to the soil, for example by soaking, application by dripping, application by immersion or injection into the ground. The pesticidal compounds may be additionally applied as a solid or liquid composition, for example such as a powder or granule formulation comprising an inert carrier, for example such as clay.

The methods of application to the ground can suffer several problems. Pesticide compounds are not always particularly suitable for application by different methods of application in the soil, such as by soaking, drip application, immersion application or injection into the soil. Its pesticidal activity may be affected in some cases.

Therefore, an object of the present invention is to provide compounds that have good pesticidal activity and good applicability in soil treatment techniques against a large number of different invertebrate pests, especially against pests that live in the soil, which are hard to control

Some pesticide compositions applied to the soil may also have leaching potential. Therefore, care must be taken to minimize both surface and groundwater contamination. In addition, the effectiveness of the pesticide may vary depending on environmental conditions, for example, properly programmed rain is needed for the successful operation of the chemical in the soil, but too much rain can reduce the effectiveness and can cause leaching.

Therefore, it is also an object of the present invention to provide compositions that are suitable for fighting pests that live in the soil and that overcome the problems associated with known techniques. In particular, the compositions must be easily applicable and provide lasting action against pests that live in the soil. In addition, environmental conditions should not have an adverse effect on the effectiveness of the pesticide.

Methods of application in the soil are considered as techniques to apply pesticide compounds directly or indirectly to the soil and / or the earth, such as drip applications or drip irrigation (on the ground), or soil injection, additional methods for soaking soil. Additional known methods of soil application are furrow and T-band applications

Additionally, the object of the present invention are the methods of application by immersion of roots, tubers or bulbs (called application by immersion), by hydroponic systems or also by seed treatment.

Another problem facing the farmer in this context is that the seeds and roots of plants and shoots are constantly threatened by leaf and soil insects and other pests.

Therefore, an additional difficulty in relation to the use of such pesticides for seed protection is that repeated and exclusive application of an individual pesticide compound also leads in many cases to a rapid selection of soil pests, which have developed a natural or adapted resistance against the active compound in question. Therefore, there is a need for seed protection agents that help prevent or overcome resistance.

Therefore, a further object of the present invention is to provide compounds that solve the protection problems of the protection of growing seeds and plants, reducing the dosage rate, improving the spectrum of activity and / or for managing pest resistance .

Therefore, the present invention also provides methods for the protection of plant propagation material, especially seeds, from soil insects and from the roots and shoots of the plant resulting from soil and leaf insects.

The invention also relates to plant propagation material, especially seeds, which are protected from soil and leaf insects.

Therefore, it is especially an object of the present invention to provide application methods that are suitable for combating pests that live in the soil. Surprisingly, it has now been found that the carboxamide compounds of formula (I)

or the tautomers, enantiomers, diastereomers or salts thereof, in combination with at least one other agriculturally active compound selected from the group of insecticides and / or fungicides consisting of fluxapiroxad, epoxiconazole, triticonazole, abamectin, emamectin, cantraniliprole, chlorantraniliprole, thiachlopridid, Suitable highly suitable for controlling and / or combating animal pests in soil application methods and seed treatment methods as defined in the claims.

Carboxamide derivatives that show a generally pesticidal activity have been described above. WO200573165 and WO2010018714 describe carboxamide compounds, their preparation and their use as pest control agents. WO2007013150, JP2011-157294, JP2011-157295 and JP2011-157296 describe mixtures of carboxamides with other active ingredients. The application of some carboxamide derivatives in vegetable seeds has been described in JP2011-157295.

However, its surprisingly excellent applicability for soil application techniques, as well as in seed treatment methods, and its extraordinary activity against pests that live in the soil, especially in combination with other active agricultural ingredients, are not have described above.

Formulations

The invention also relates to the use of agrochemical compositions suitable for application in soil treatment methods comprising an auxiliary combination of active compounds as defined in the claims.

An agrochemical composition comprises an effective amount as a pesticide of a compound of formula (I). The term "effective amount" denotes an amount of the composition or compounds I, which is sufficient to control harmful pests in cultivated plants or in the protection of materials and which does not produce substantial damage to the treated plants. Such amount may vary over a wide range and depends on various factors, such as the species of animal pests to be controlled, the plant or the cultivated material treated, the climatic conditions and the specific compound I used.

The compounds of formula (I), their N-oxides and salts can be converted into usual types of agrochemical compositions, for example solutions, emulsions, suspensions, powders, sprays, pastes, granules, presses, capsules and mixtures thereof. Examples of composition types are suspensions (for example, SC, OD, FS), emulsifiable concentrates (for example, EC), emulsions (for example, EW, EO, ES, ME), capsules (for example, CS, ZC) , pastes, lozenges, powders or wettable powders (e.g., WP, SP, WS, DP, DS), pressed (e.g., BR, TB, DT), granules (e.g., WG, SG, GR, FG, GG , MG), insecticidal articles (for example, LN), as well as gel formulations for the treatment of plant propagation materials such as seeds (for example, GF). These and additional types of compositions are defined in the "Catalog of pesticide formulation types and international coding system", Technical Monograph No. 2, 6th Ed. May 2008, CropLife International.

The compositions are prepared in a known manner, as described by Mollet and Grubemann, Formulation technology, Wiley VCH, Weinheim, 2001; or Knowles, New developments in crop protection product formulation, Agrow Reports DS243, T&F Informa, London, 2005.

Suitable auxiliary agents are solvents, liquid vehicles, vehicles or solid fillers, surfactants, dispersants, emulsifiers, humectants, adjuvants, solubilizers, penetration enhancers, protective colloids, adhesion agents, thickeners, humectants, repellents, stimulants feed, compatibilizers, bactericides, antifreeze agents, antifoaming agents, colorants, tackifiers and binders.

Suitable solvents and liquid carriers are water and organic solvents, such as medium to high boiling mineral oil fractions, for example kerosene, diesel oil; oils of vegetable or animal origin; aliphatic, cyclic and aromatic hydrocarbons, for example toluene, paraffin, tetrahydronaphthalene, alkylated naphthalenes; alcohols, for example ethanol, propanol, butanol, benzyl alcohol, cyclohexanol; glycols; DMSO; ketones, for example cyclohexanone; esters, for example lactates, carbonates, fatty acid esters, gamma-butyrolactone; fatty acids; phosphonates; amide amines, for example N-methylpyrrolidone, fatty acid dimethylamides; and mixtures thereof.

Suitable solid carriers or fillers are mineral earths, for example silicates, silica gels, talc, kaolin, limestone, lime, chalk, clays, dolomite, diatomaceous earth, bentonite, calcium sulfate, magnesium sulfate, oxide of magnesium; polysaccharides, for example, cellulose, starch; fertilizers, for example ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas; products of plant origin, for example cereal flour, tree bark flour, wood flour, nutshell flour and mixtures thereof.

Suitable surfactants are compounds with surface activity, such as anionic, cationic, nonionic and amphoteric surfactants, block polymers, polyelectrolytes and mixtures thereof. Such surfactants can be used as emulsifiers, dispersants, solubilizers, humidifiers, penetration enhancers, protective colloids or adjuvants. Examples of surfactants are listed in McCutcheon's, Vol. 1: Emulsifiers & Detergents, McCutcheon's Directories, Glen Rock, USA, 2008 (International Ed. Or North American Ed.).

Suitable anionic surfactants are alkaline, alkaline earth or ammonium salts of sulfonates, sulfates, phosphates, carboxylates and mixtures thereof. Examples of sulfonates are: alkylarylsulfonates, diphenylsulfonates, alpha-olefin sulfonates, lignin sulfonates, fatty acid and oil sulfonates, ethoxylated alkylphenol sulfonates, alkoxylated arylphenol sulfonates, condensed naphthalene sulfonates, dodecylbenzene sulfonates, naphthalenes and alkyl naphthalenes, sulfosuccinates or sulfosuccinamates. Examples of sulfates are sulfates of fatty acids and oils, of ethoxylated alkylphenols, alcohols, ethoxylated alcohols or fatty acid esters. Examples of phosphates are phosphate esters. Examples of carboxylates are alkyl carboxylates and carboxylated alcohol or alkylphenol ethoxylates.

Suitable non-ionic surfactants are alkoxylates, N-substituted fatty acid amides, amine oxides, esters, sugar-based surfactants, polymeric surfactants and mixtures thereof. Examples of alkoxylates are compounds such as alcohols, alkylphenols, amines, amides, arylphenols, fatty acids or fatty acid esters that have been alkoxylated with 1 to 50 equivalents. Ethylene oxide and / or propylene oxide can be used for alkoxylation, preferably ethylene oxide. Examples of N-substituted fatty acid amides are fatty acid glucamides or fatty acid alkanolamides. Examples of esters are fatty acid esters, glycerol esters or monoglycerides. Examples of sugar-based surfactants are sorbitan, ethoxylated sorbitan, sucrose and glucose esters or alkyl polyglycosides. Examples of polymeric surfactants are the homo compounds or copolymers of vinyl pyrrolidone, vinyl alcohols or vinyl acetate.

Suitable cationic surfactants are quaternary surfactants, for example quaternary ammonium compounds with one or two hydrophobic groups, or salts of primary long chain amines. Suitable amphoteric surfactants are alkyl betaines and imidazolines. Suitable block polymers are block polymers of type A-B or A-B-A comprising blocks of polyethylene oxide and polypropylene oxide, or of type A-B-C comprising alkanol, polyethylene oxide and polypropylene oxide. Suitable polyelectrolytes are polyacids or polybases. Examples of polyacids are alkaline salts of polyacrylic acid or polyacid comb polymers. Examples of polybases are polyvinylamines or polyethyleneamines.

Suitable adjuvants are compounds, which have negligible or even zero pesticidal activity, and which improve the biological performance of compound I in the target. Examples are surfactants, mineral oils or Vegetables and other auxiliaries. Additional examples are listed by Knowles, Adjuvants and additives, Agrow Reports DS256, T&F Informa United Kingdom, 2006, chapter 5.

Suitable thickeners are polysaccharides (for example, xanthan gum, carboxymethyl cellulose), anorganic clays (organically modified or unmodified), polycarboxylates and silicates.

Suitable bactericides are bronopol and isothiazolinone derivatives such as alkylisothiazolinones and benzisothiazolinones.

Suitable antifreeze agents are ethylene glycol, propylene glycol, urea and glycerin.

Suitable antifoaming agents are silicones, long chain alcohols and fatty acid salts.

Suitable dyes (for example, in red, blue or green) are pigments of low water solubility and water soluble dyes. Examples are inorganic dyes (for example, iron oxide, titanium oxide, iron hexacyanoferrate) and organic dyes (for example, alizarin, azo and phthalocyanine dyes).

Suitable tackifiers or binders are polyvinylpyrrolidones, polyvinylacetate, polyvinyl alcohols, polyacrylates, biological or synthetic waxes and cellulose ethers.

The agrochemical compositions generally comprise between 0.01 and 95%, preferably between 0.1 and 90%, and in particular between 0.5 and 75% by weight of active substance. The active substances are used in a purity of 90% to 100%, preferably 95% to 100% (according to the NMR spectrum).

Solutions for seed treatment (LS), Suspoemulsions (SE), fluid concentrates (FS), dry treatment powders (DS), water dispersible powders for sludge treatment (WS), water soluble powders (SS) ), emulsions (ES), emulsifiable concentrates (EC) and gels (GF) are usually used for the treatment of plant propagation materials, particularly seeds. The compositions in question provide, after a two to ten fold dilution, active substance concentrations of 0.01 to 60% by weight, preferably 0.1 to 40% by weight, in ready-to-use preparations. The application can be done before or during sowing. The methods for applying the compound I and the compositions thereof, respectively, on the plant propagation material, especially the seeds include the methods of covering, coating, pelletizing, sprinkling, soaking and furrowing the propagation material. Preferably, the compound I or the compositions thereof, respectively, are applied to the plant propagation material by a method such that germination is not induced, for example by seed covering, pelletization, coating and dusting.

When used in plant protection, the amounts of active substances applied are, depending on the type of effect desired, from 0.001 to 2 kg per ha, preferably from 0.005 to 2 kg per ha, more preferably from 0.05 to 0.9 kg per ha , and in particular from 0.1 to 0.75 kg per ha. In the treatment of plant propagation materials such as seeds, for example by spraying, coating or soaking seeds, amounts of active substance of 0.1 to 1000 g, preferably 1 to 1000 g, more preferably 1 to 100 g and lo are generally required. more preferably 5 to 100 g, per 100 kilograms of plant propagation material (preferably seeds). When used in the protection of stored materials or products, the amount of active substance applied depends on the type of application area and the desired effect. The amounts that are usually applied in the protection of materials are from 0.001 g to 2 kg, preferably from 0.005 g to 1 kg, of active substance per cubic meter of treated material.

Various types of oils, humectants, adjuvants, fertilizers or micronutrients, and additional pesticides (eg, herbicides, insecticides, fungicides, growth regulators, protectors) can be added to the active substances or compositions comprising them as premix or, if applicable not until immediately before using (tank mixing). These agents can be mixed with the compositions according to the invention in a weight ratio of 1: 100 to 100: 1, preferably 1:10 to 10: 1. The user applies the composition according to the invention usually from a device of predosing, a backpack sprayer, a spray tank, a spray plane or an irrigation system. Usually, the agrochemical composition is composed of water, regulator and / or additional auxiliaries for the desired application concentration and thus the ready-to-use spray liquor or the agrochemical composition according to the invention is obtained. Usually, 20 to 2000 liters, preferably 50 to 400 liters, of the ready-to-use spray liquor are applied per hectare of area useful for agriculture.

Applications

The present invention relates to the methods used in natural substrates (soil) or artificial (growth) substrates (for example, rock wool, glass wool, quartz sand, gravel, expanded clay, vermiculite), in open or closed systems (for example, greenhouses. or under film mulch) and in annual crops (such as vegetables, spices, ornamentals) or perennial crops (such as citrus plants, fruits, tropical crops, spices, nuts, vines, coniferous and ornamental). It has now been found that the problems associated with the fight against pests that live in the soil by treatment with soil pesticides can be overcome with the application methods defined in the claims.

With respect to the use and for the purpose of the present invention, it should be understood that vegetables mean, for example, fruit vegetables and inflorescences such as vegetables, that is, peppers, peppers, tomatoes, varieties of eggplants, cucumbers, zucchini, variety of Zucchini, beans, beans, climbing and dwarf beans, peas, artichokes and corn. In addition, also leafy vegetables, such as head lettuce, chicory, endives, various types of watercress, arugula, lamb lettuce, iceberg lettuce, leeks, spinach and chard. Additionally, tuber vegetables, root vegetables and stalk vegetables, such as celery / celery variety, beet root, carrots, radish, horseradish, scorzonera, asparagus, beet for human consumption, bamboo beets and bamboo shoots. In addition also bulb vegetables such as onions, leeks, fennel and garlic. Brassica vegetables such as cauliflower, broccoli, kohlrabi, red cabbage, white cabbage, kale, Savoy cabbage, Brussels sprouts and Chinese cabbage are also vegetables within the meaning of this application .

With respect to the use and for the purposes of the present invention, perennial crops should be understood as citrus, for example, oranges, grapefruits, tangerines, lemons, limes, Seville oranges, cumquats and satsumas. Also nugget fruits such as, for example, apples, pears and quinces, and stone fruits such as, for example, peaches, nectarines, cherries, plums, quetsch, apricots. In addition vines, hops, olives, tea and tropical crops such as, for example, mangoes, papayas, figs, pineapples, dates, bananas, durianes, kaki fruit, coconuts, cocoa, coffee, avocados, lychees, passion fruit, and guavas. Additionally, soft fruits such as, for example, currants, currants, raspberries, blackberries, cranberries, strawberries, blueberries, kiwi fruit and American cranberries. Almonds and walnuts such as, for example, hazelnuts, walnut, pistachios, cashews, paranueces, pecan nuts, white walnuts, chestnuts, pecan nuts, macadamia nuts and peanuts are also fruits within the meaning of the present invention . With respect to the use and for the purposes of the present invention, it is understood that ornamental plants mean annual and perennial plants, for example, cut flowers such as, for example, roses, carnations, gerbera, lilies, marguerites, chrysanthemums, tulips, daffodils, anemones, poppies, amaryllis, dahlias, azaleas, hibiscus, but also for example border plants, pot plants and perennials such as, for example, roses, Tagetes, violas, geraniums, fuchsia, hibiscus, chrysanthemums, busy lizzie , cyclamen, African violet, sunflowers, begonias. Additionally, for example, also shrubs and conifers such as, for example, ficus, rhododendron, firs, spruce, pine, yew, juniper, umbrella pines, oleander.

In terms of use, spices are understood as annual and perennial plants such as, for example, anise, chili, paprika, pepper, vanilla, marjoram, thyme, clove, juniper berries, cinnamon, tarragon, coriander, saffron, ginger.

In addition, the uses and methods of the present invention are particularly important in the control of a multitude of insects in various cultivated plants, such as cereals and oil crops, for example, durum wheat or other wheat seeds, barley, oats, rye, corn (cob corn and sugar corn / sweet corn and field corn), soybeans, oil crops, cruciferous, cotton, bananas, rice, oilseed rape, nabina rapeseed, sugar beet, fodder beet, eggplant, potatoes, grass, grass, grass, forage grass, sugar cane or tobacco.

The uses and methods as defined in the claims can also be applied preventively to places where the appearance of pests is expected. "Locus" means a habitat, breeding ground, plant, seed, soil, area, material or environment in which a pest or parasite is growing or can grow. The term "plant propagation material" should be understood to denote all generative parts of the plant, such as seeds and vegetative plant material such as cuttings and tubers (for example, potatoes), which can be used for multiplication of the plant. plant. This includes seeds, roots, fruits, tubers, bulbs, rhizomes, shoots, shoots and other parts of plants. Seedlings and young plants can also be included, which will be transplanted after germination or after the emergence of the soil. These plant propagation materials can be treated prophylactically with a plant protection compound, either during or before planting or transplanting. The term "cultivated plants" should be understood to include plants that have been modified by reproduction, mutagenesis or genetic engineering. Genetically modified plants are plants, whose genetic material has been modified so much by the use of recombinant DNA techniques that, under natural circumstances, cannot be easily obtained by cross-breeding, mutations or natural recombination. Typically, one or more genes have been integrated into the genetic material of a genetically modified plant to improve certain properties of the plant. Such genetic modifications also include, but are not limited to, the directed post-transtional modification of poly (oligo- or polypeptide) proteins, for example, by glycosylation or polymer additions such as pre-stacked, acetylated or farnesylated structural units or structural units. of PEG (for example, as disclosed in Biotechnol Prog. 2001 Jul-Aug; 17 (4): 720-8., Protein Eng Des Sel. 2004 Jan; 17 (1): 57-66, Nat Protoc. 2007; 2 (5): 122535., Curr Opin Chem Biol. 2006 Oct; 10 (5): 487-91. Epub 2006 Aug 28., Biomaterials. 2001 Mar; 22 (5): 405-17, Bioconjug Chem. 2005 Jan-Feb; 16 (1): 113-21).

The term "cultivated plants" should also be understood to include plants that have become tolerant to applications of specific classes of herbicides, such as hydroxyphenylpyruvate dioxygenase (HPPD) inhibitors; acetolactate synthase (ALS) inhibitors, such as sulfonylureas (see, for example, US 6,222,100, WO 01/82685, WO 00/26390, WO 97/41218, WO 98/02526, WO 98/02527 , WO 04/106529, WO 05/20673, WO 03/14357, WO 03/13225, WO 03/14356, WO 04/16073) or imidazolinones (see, for example, US 6,222,100, WO 01/82685 , WO 00/26390, WO 97/41218, WO 98/0252626, WO 98/02527, WO 04/106529, WO 05/20673, WO 03/14357, WO 03/13225, WO 03/14356, WO 04/16073 ); Enolpiruvilshikimato-3-phosphate synthase (EPSPS) inhibitors, such as glyphosate (see, for example, WO 92/00377); glutamine synthetase (GS) inhibitors, such as glufosinate (see, for example, EP-A-0242236, EP-A-242246) or oxinyl herbicides (see, for example, US 5,559,024) as result of conventional methods of reproduction or genetic engineering. Several cultivated plants have become herbicide tolerant by conventional breeding methods (mutagenesis), for example, Clearfield® summer canola (Canola) is tolerant of imidazolinones, for example imazamox. Genetic engineering methods have been used to produce cultivated plants, such as soybeans, cotton, corn, beets and rape, herbicide tolerant, such as glyphosate and glufosinate, some of which are commercially available under the trade names RoundupReady ® (glyphosate) and LibertyLink. ® (glufosinate).

The term "cultivated plants" should be understood to also include plants that are through the use of recombinant DNA techniques capable of synthesizing one or more insecticidal proteins, especially those known from the bacterial genus Bacillus, particularly Bacillus thuringiensis, such as a-endotoxins for example CrylA (b), CrylA (c), CrylF, CrylF (a2), CrylIA (b), CrylIIA, CrylIIB (b1) or Cry9c; vegetative insecticidal proteins (VIP), for example VIP1, VIP2, VIP3 or VIP3A; insecticidal proteins of bacterial colonizing nematodes, for example Photorhabdus spp. or Xenorhabdus spp .; toxins produced by animals, such as scorpion toxins, arachnid toxins, wasp toxins or other insect-specific neurotoxins; toxins produced by fungi, such as streptomycete toxins, plant lectins, such as pea or barley lectins; agglutinins; proteinase inhibitors, such as trypsin inhibitors, serine protease inhibitors, patatin, cystatin or papain inhibitors; inactivating ribosome proteins (RIP), such as ricin, corn RIP, abrina, lufina, saporina or briodina; steroid metabolism enzymes, such as 3-hydroxysteroid oxidase, ecdysteroid-IDP-glycosyl transferase, cholesterol oxidases, ecdysone inhibitors or HMG-CoA reductase; ionic channel blockers, such as sodium or calcium channel blockers; juvenile hormone esterase; diuretic hormone receptors (helicoquinine receptors); stilbe synthase, bibenzyl synthase, chitinases or glucanases. In the context of the present invention, these insecticidal proteins or toxins must also be expressly understood as pre-toxins, hybrid proteins, truncated or otherwise modified proteins. Hybrid proteins are characterized by a new combination of protein domains (see, for example, WO 02/015701). Additional examples of such toxins or genetically modified plants capable of synthesizing such toxins are disclosed, for example, in EP-A 374 753, WO 93/007278, WO 95/34656, EP-A 427 529, EP-A 451 878 , WO 03/018810 and WO 03/052073. The methods for producing such genetically modified plants are generally known to those skilled in the art and are described, for example, in the publications mentioned above. These insecticidal proteins contained in genetically modified plants provide the plants that produce these proteins with protection against the harmful pests of certain taxonomic groups of arthropods, particularly beetles (Coleoptera), flies (Diptera) and butterflies and moths (Lepidoptera) and nematodes plant parasites (Nematoda).

The term "cultivated plants" should also be understood to include plants that are through the use of recombinant DNA techniques capable of synthesizing one or more proteins to increase the resistance or tolerance of those plants to bacterial, viral or fungal pathogens. Examples of such proteins are the so-called "pathogenesis-related proteins" (PR proteins, see, for example, EP-A 0 392 225), plant disease resistance genes (for example, potato cultivars, which express genes of resistance that act against derivatives of Phytophthora infestans of the Mexican wild potato Solanum bulbocastanum) or T4-liso-zym (for example, potato cultivars capable of synthesizing these proteins with greater resistance against bacteria such as Erwinia amylvora). The methods for producing such genetically modified plants are generally known to those skilled in the art and are described, for example, in the publications mentioned above.

The term "cultivated plants" should be understood to also include plants that are through the use of recombinant DNA techniques capable of synthesizing one or more proteins to increase productivity (for example, biomass production, grain yield, starch content, content of oil or protein content), tolerance to drought, salinity or other environmental factors that limit the growth or tolerance to fungal, bacterial or viral pests and pathogens of those plants.

The term "cultivated plants" should also be understood to include plants that contain, by the use of recombinant DNA techniques, a modified amount of content substances or new content substances, specifically to improve human or animal nutrition, for example in oil crops that produces long-chain omega-3 fatty acids that promote health or unsaturated omega-9 fatty acids (for example, Nexera® rapeseed).

The term "cultivated plants" should also be understood to include plants that contain a modified amount of content substances or new content substances by using recombinant DNA techniques, specifically to improve the production of raw material, for example potatoes that produce larger amounts of amylopectin (for example, Amflora® potato).

In general, "effective amount as a pesticide" means the amount of active ingredient necessary to achieve an observable effect on growth, including the effects of necrosis, death, retardation, prevention and elimination, destruction or, otherwise, decreased incidence. and activity of the target organism. The amount effective as a pesticide may vary for the various compounds / compositions used in the invention. An effective amount as a pesticide of the compositions will also vary according to prevailing conditions, such as the effect and duration of desired pesticides, climate, target species, locus, mode of application and the like.

In the case of soil treatment, the amount of active ingredient varies from 0.0001 to 500 g per 100 m2, preferably from 0.001 to 20 g per 100 m2. As mentioned above, the methods of application to the soil include among other known techniques applications in grooves and T-band. The active compound can be applied as granular, as T-band treatments or in groove. Granular or liquid T-band applications are placed in front of the groove closing wheels using plastic diffusers. In general, the band coverage pattern is approximately a couple of inches wide over an open groove. Groove treatments are directed towards the open groove using plastic tubes. Liquid formulations are applied as a T band over an open groove. For example, the seeds are planted with cone seeders and drop nozzles are placed over the seed groove. The pen can be moved up or down to change the width of the band. A flat fan nozzle can also be used: perpendicular to the row for the bands and parallel to the row for the groove. The position of the boom is between the groove opener and the pressure wheel that directs something (band) or all (in groove) of the spray towards the groove before the groove is closed. When used in furrow applications, the active compounds can be applied simultaneously with the sowing of the seeds, for example as granular, liquid or other formulation. Alternatively, the nozzles can also be placed behind the press wheel to obtain a completely surface spray of the liquid formulation comprising the active compounds.

The uses and methods defined in the claims are also suitable for the treatment of seeds in order to protect the seeds against insect pests, in particular against insect pests living in the soil and the resulting plant roots and shoots against pests. of soil and leaf insects.

The uses and methods defined in the claims are particularly useful for the protection of the seed from soil pests and the roots and shoots of the resulting plant against soil pests and leaf insects. The protection of the roots and shoots of the resulting plant is preferred. More preferred is the protection of plant sprouts resulting from perforating and sucking insects, where protection against aphids is the most preferred. The method as defined in the claims comprises a method for the protection of insect seeds, in particular of soil insects and of roots and shoots of seedlings of insects, in particular of soil and leaf insects, said method comprising contact the seeds before sowing and / or after pregermination with the combinations defined in the claims. Particularly preferred is a method, where the roots and shoots of the plant are protected, more preferably a method, where the shoots of the plants are protected from perforating and sucking insects, most preferably it is a method, where the shoots of The plants are protected from aphids. The term "seed" encompasses seeds and propagules of plants of all kinds, which include but are not limited to true seeds, seed pieces, renewals, seedlings, bulbs, fruits, tubers, grains, cuttings, cut buds and the like, and in one embodiment Preferred true seeds. The term "seed treatment" comprises all suitable seed treatment techniques known in the art, such as seed coating, seed coating, seed sprinkling, seed soaking and seed pelletization. The present invention also comprises seeds coated with or containing the active compound. The term "coated with and / or containing" generally means that the active ingredient is mostly on the surface of the propagation product at the time of application, although a greater or lesser part may penetrate the propagation product, Depending on the method of application. When said propagation product is (re) planted, it can absorb the active ingredient. Suitable seeds are cereal seeds, root crops, oil crops, vegetables, spices, ornamental plants, for example, durum wheat or other wheat seeds, barley, oats, rye, corn (cob corn and sugar corn / corn sweet and field), soybeans, oil crops, cruciferous, cotton, sunflowers, bananas, rice, oilseed rape, nabina rapeseed, sugar beet, fodder beet, eggplant, potatoes, grass, grass, fodder grass, tomatoes, leeks, zucchini / pumpkins, cabbage, iceberg lettuce, pepper, cucumbers, melons, Brassica species, melons, beans , peas, garlic, onions, carrots, tuberous plants such as potatoes, sugar cane, tobacco, grapes, petunias, geraniums / pelargoniums, thoughts and impatiens.

In addition, suitable seeds may also be plant seeds, which tolerate the action of herbicides or fungicides or insecticides due to reproduction, including genetic engineering methods.

For example, plant seeds that are resistant to herbicides of the group consisting of sulfonylureas, imidazolinones, ammonium glufosinate or isopropylammonium glyphosate and analogous active substances (see, for example, EP-A-0242236, EP-A -242246) (WO 92/00377) (EP-A-0257993, U.S. Patent No.

5,013,659) or in transgenic crops, for example cotton, with the ability to produce Bacillus thuringiensis toxins (Bt toxins) that make plants resistant to certain pests. (EP-A-0142924, EP-A-0193259). Additionally, the active compound can also be used for the treatment of plant seeds, which have modified characteristics compared to existing plants, which can be generated, for example, by traditional means. methods of reproduction and / or generation of mutants, or by recombinant procedures). For example, several cases of recombinant modifications of crop plants have been described in order to modify the starch synthesized in plants (for example, WO 92/11376, WO 92/14827, WO 91/19806) or plants of transgenic cultures having a modified fatty acid composition (WO 91/13972).

The application of seed treatment can be carried out by spraying or sprinkling the seeds before planting the plants and before the emergence of the plants. Compositions that are especially useful for seed treatment are, for example:

A Soluble concentrates (SL, LS)

D Emulsions (EW, EO, ES)

E Suspensions (SC, OD, FS)

F Water dispersible granules and water soluble granules (WG, SG)

G Water dispersible powders and water soluble powders (WP, SP, WS)

H Gel formulations (GF)

I Sprayable powders (DP, DS)

Conventional seed treatment formulations include, for example, FS fluid concentrates, LS solutions, DS dry treatment powders, water dispersible powders for WS sludge treatment, SS water soluble powders and ES and EC emulsion and GF gel formulation. These formulations can be applied to the diluted or undiluted seed. The application to the seeds is done before sowing, either directly on the seeds or after having pre-germinated the latter. In a preferred embodiment, an FS formulation is used for seed treatment. Typically, an FS formulation may comprise 1-800 g / l of active ingredient, 1-200 g / l of surfactant, 0 to 200 g / l of antifreeze agent, 0 to 400 g / l of binder, 0 to 200 g / l of a pigment and up to 1 liter of solvent, preferably water.

Especially preferred FS formulations for seed treatment generally comprise 0.1 to 80% by weight (1 to 800 g / l) of compound (I), 0.1 to 20% by weight (1 to 200 g / l) of at least one surfactant, for example 0.05 to 5% by weight of a wetter agent and 0.5 to 15% by weight of a dispersing agent, up to 20% by weight, for example 5 to 20% of an antifreeze agent , from 0 to 15% by weight, for example 1 to 15% by weight of a pigment and / or a dye, from 0 to 40% by weight, for example 1 to 40% by weight of a binder (adhesive / bonding agent adhesion), optionally up to 5% by weight, for example 0.1 to 5% by weight of a thickener, optionally 0.1 to 2% of an antifoaming agent, and optionally a preservative such as a biocide, antioxidant or the like, for example in an amount of 0.01 to 1% by weight and a filler / vehicle of up to 100% by weight. Formulations for seed treatment may also comprise binders and optionally dyes. Binders can be added to improve the adhesion of the active materials in the seeds after treatment. Suitable binders are homo- and copolymers of alkylene oxides such as ethylene oxide or propylene oxide, polyvinyl acetate, polyvinyl alcohols, polyvinyl pyrrolidones and copolymers thereof, ethylene-vinyl acetate copolymers, homo and acrylic copolymers, polyethyleneamines , polyethyleneamides and polyethyleneimines, polysaccharides such as celluloses, tilose and starch, homo and copolymers of polyolefins such as olefin / maleic anhydride copolymers, polyurethanes, polyesters, homo and polystyrene copolymers.

Optionally, dyes can also be included in the formulation. Suitable dyes or dyes for seed treatment formulations are Rhodamin B, C.I. Pigment Red 112, C.I. Solvent Red 1, pigment blue 15: 4, pigment blue 15: 3, pigment blue 15: 2, pigment blue 15: 1, pigment blue 80. pigment yellow 1, pigment yellow 13, pigment red 112, pigment red 48: 2, pigment red 48: 1, pigment red 57: 1, pigment red 53: 1, pigment orange 43, pigment orange 34, pigment orange 5, pigment green 36, pigment green 7, pigment white 6, pigment brown 25, basic violet 10. basic violet 49, acid red 51, acid red 52, acid red 14, acid blue 9, acid yellow 23, basic red 10. basic red 108.

Examples of a gelling agent is carrageenan (Satiagel®)

In the treatment of seeds, the rates of application of compounds I are generally from 0.1 g to 10 kg per 100 kg of seed, preferably from 1 g to 5 kg per 100 kg of seed, more preferably from 1 g to 1000 g per 100 kg of seed and, in particular, from 1 g to 200 g per 100 kg of seed.

Therefore, the invention also relates to seeds comprising a compound of the formula I, or a salt I useful in agricultural function, as defined herein. The amount of compound I or the agricultural salt useful thereof will generally vary from 0.1 g to 10 kg per 100 kg of seed, preferably from 1 g to 5 kg per 100 kg of seed, in particular from 1 g to 1000 g per 100 kg. of seed. For specific crops such as lettuce, the rate may be higher.

Pests and fungi

The invention in particular relates to methods of application in the soil to combat pests of arthropods living in the soil and pests of nematodes, which comprises applying to the soil an effective amount as a pesticide of a compound of the present invention.

The term "living in the soil" means that the habitat, breeding grounds, area or environment in which a pest or parasite grows or can grow is the soil.

The use of the compounds according to the present invention extends to a wide range of different animal pests, especially soil pests. These include but are not limited to the following families:

Insects of the order of the lepidoptera (Lepidoptera), for example Agrotisypsilon, Agrotis segetum, Alabama argillacea, Anticarsia gemmatalis, Argyrestia conjugella, Autographa gamma, Bupalus piniarius, Cacoecia murinana, Capua reticulana, Cheimatobia brumataum, Choristoneumura, Choristoneumura, Choristoneumura, Choristoneumura, Choristoneumura, Choristoneumumum, Choristoneumura, Choristoneumumum, Choristoneumura, Choristoneumumumum, Choristoneumumumum, Choristoneum, Choristoneumumumum, Choristoneumumumumum, Choristoneumura, Choristoneumumumumum, Choristoneumumumumum, Choristoneumumum, Choristumumumumumumum, Choristoneumura, Choristoneum, Choristoneum, Choristoneum, Choristoneum, Choristone, Western Cydia pomonella, Dendrolimus pini, Diaphania nitidalis, Diatraea grandiosella, Insulana Earias, Elasmopalpus lignosellus, eupoecilia ambiguella, Evetria bouliana, subterranea Feltia, Galleria mellonella, funebrana Grapholitha, Grapholitha upset, Heliothis armigera, Heliothis virescens, Heliothis zea, Hellula undalis, Hibernia defoliaria , Hyphantria cunea, Hyponomeuta malinellus, Keiferia lycopersicella, Lambdina fiscellaria, Laphygma exigua, Leucoptera coffeella, Leucoptera scitella, Lithocolletis blancardella, Lobesia botrana, Loxostege sticticalis, Lymantria dispar, Lymantriamaiaiamaiaiamaiamaiamaiamaiamaiamaiamaiamaia, Brass eudotsugata, Ostrinia nubilalis, Panolis flammea, Pectinophora gossypiella, Peridroma saucia, Phalera bucephala, Phthorimaea operculella, Phyllocnistis citrella, Pieris brassicae, Plathypena scabra, Plutella xylostella, Pseudoplusia scanapulapulapulapulapulapulapulapulapulapulapulapulapulapulapula, Grapitacrogalagalagalagalagalagalagalagalagalagalagalagalagalagalagalagala, Runacionotunapolalagalagalagalagalagalagalagalagalagalagalagalagalagalagalagalagalagalagalagala, Sliecrobielagalagalagalagalagalagalagalagalagalagalagalagalagalagala, Pugliappellapispierna, Sparrowaperiala, Spaghetti p. Spodoptera littoralis, Spodoptera litura, Thaumatopoea pityocampa, Tortrix viridana, Trichoplusia ni, Tuta absolute, and Zeiraphera canadensis,

Beetles (Coleoptera), for example Agrilus sinuatus, Agriotes lineatus, Agriotes obscurus, Amphimallus solstitialis, Anisandrus dispar, Anoplophora glabripensis, Anthonomus grandis, Anthonomus pomorum, Aphthona euphoridae, Athous haemorrhoidaeptisdata, Bomatis, Cassomatis, Cassomatis, Bomatis, Cassomatis, Cassomatis, Bomatus nebulosa, Cerotoma trifurcata, Cetonia aurata, Ceuthorrhinchus assimilis, Ceuthorrhinchus napi, Chaetocnema tibialis, Conoderus vespertinus, Crioceris asparagi, Ctenicera ssp., Diabrotica longicornis, Diabrotica semipunctata, Diabrotica 12-punctata Diabrotica speciosa, Diabrotica virgifera, Epilachna varivestis, Epitrix hirtipennis, Hylobius abietis, Hypera brunneipennis, Hypera postica, Ips typographus, Lema bilineata, Lema melanopus, Leptinotarsa decemlineata, Limonius californicus, Lissorhoptrus oryzophilus, Melanotus communis, Meligethes aeneus, Melolontha otiorstahin ochunae, Musa otorstatus, Oelastatus ochteraeus, Muscle us, Phaedon cochleariae, Phyllobius piri, Phyllotreta chrysocephala, Phyllophaga sp., Phyllopertha horticola, Phyllotreta nemorum, Phyllotreta striolata, Popillia japonica, Sitona lineatus and,

flies and mosquitoes (Diptera), for example Ceratitis capitata, Contarinia sorghicola Dacus cucurbitae, Dacus oleae, Dasineura brassicae, Delia antique, Delia coarctata, Delia platura, Delia radicum, Liriomyza sativae, Liriomyza trifolii, Oscinella frit, Pegomyahorquaquacycy Porsche Phorbia brassicae, Phorbia coarctata, Psila rosae, Psorophora discolor, Rhagoletis cerasi, Rhagoletis pomonella, Tipula oleracea, and Tipula paludosa

trips (Thysanoptera), for example Dichromothrips corbetti, Dichromothrips ssp., Frankliniella fusca, Frankliniella occidentalis, Frankliniella tritici, Scirtothrips citri, Thrips oryzae, Thrips palmiand Thrips tabaci,

termites (Isoptera), for example Calotermes flavicollis, Leucotermes flavipes, Heterotermes aureus, Reticulitermes flavipes, Reticulitermes virginicus, Reticulitermes lucifugus, Reticulitermes santonensis, Reticulitermes grassei, Termes natalensis, and Coptoterdas insects (Hemiptera), for example, Acrosternum hilare, Blissus leucopterus, Cyrtopeltis notatus, Dysdercus cingulatus, Dysdercus intermedius, Eurygaster integriceps, Euschistus impictiventris, Leptoglossus phyllopus, Lygus lineolaris, Lygus prateapisisis, Thramantaisis, Neus prasantaisis, Neus prasantaisis, Neus prasantaisis, Neus, , Adelges laricis, Aphidula nasturtii, Aphis fabae, Aphis forbesi, Aphis pomi, Aphis gossypii, Aphis grossulariae, Aphis schneideri, Aphis spiraecola, Aphis sambuci, Acyrthosiphon pisum, Aulacorthum solani, Bemisia argentifolii, Brachycaudus cardui, Brachycaudus helichrysi, Brachycaudus persicae, Brachycaudus prunicola, brev icorine brassicae, Capitophorus horni, Cerosipha gossypii, Chaetosiphon fragaefolii, Cryptomyzus ribis, Dreyfusia nordmannianae, Dreyfusia piceae, radicola Dysaphis, Dysaulacorthum pseudosolani, Dysaphis plantaginea, Dysaphis piri, Empoasca fabae, Euschistos heros, Euschistos servus, Halyomorpha halys, Hyalopterus pruni, Hyperomyzus lactucae , Macrosiphum avenae, Macrosiphum euphorbiae, Macrosiphon rosae, megacopta criberia, Megoura viciae, Melanaphis pirarius, Metopolophium dirhodum, Myzus persicae, Myzus ascalonicus, Myzus cerasi, Myzus varians, Nasonovia Nepalala perigrala, Nigrala perigrala, Nigrala perigrala, Nigrala perigrala, Nigrala perigrala, Nigrala perigrala, Nigrala perigrala, Nigrala perigrala, Nigrala perigrala, Nigrala perigrala, Perigula, Nigrala perigrala, Periglia, Nispala peris, Perigia, Nigrala peris, Perigia, Nispala peris, Periglia, Nigrala peris, Nigrala peris, Periglia, Nigrala peris Phorodon humuli Psylla mali Psylla piri Rhopalomyzus ascalonicus Rhopalosiphum maidis Rhopalosiphum padi Rhopalosiphum insertum Sappaphis mala Sappaphis mali Schizaphis graminum Schizoneura lanuginosa hemipterus, Reduv ius senilis, Triatoma spp., and Arilus critatus.

ants, bees, wasps, sawflies (Hymenoptera), for example Athalia rosae, Atta cephalotes, Atta capiguara, Atta cephalotes, Atta laevigata, Atta robusta, Atta sexdens, Atta texana, Crematogaster spp., Hoplocampa minuta, Hoplocampa testudinea, Lasius niger, Monomorium pharaonis, Solenopsis geminata, Solenopsis invicta, Solenopsis richteri, Solenopsis xyloni, Pogonomyrmex barbatus, Pogonomyrmex californicus, Pheidole megacephala, Dasymutilla occidentalis, Polistes rubiginosa, Camponotus floridanus, Camponotpit floridanus, Humonus

crickets, grasshoppers, lobsters (Orthoptera), for example, Acheta domestica, Gryllotalpa gryllotalpa, Locusta migratoria, Melanoplus bivittatus, Melanoplus femurrubrum, Melanoplus mexicanus, Melanoplus sanguinipes, Melanoplus spretus, Nomadacris septemfasiatousciatochatsustochatsachatsustochatsachatsustata, Schloctatuschischnochnochnochnostachum, Schlachnochnochnochnochumus, Schlachnochnochnochnochnochnochnostatachnochum, Chloe, Oedaleus senegalensis, Zonozerus variegatus, Hieroglyphus daganensis, Kraussaria angulifera, Calliptamus italicus, Chortoicetes terminifera, and Locustana pardalina,

Arachnoidea, such as arachnids (Acarina), for example of the families Argasidae, Ixodidae and Sarcoptidae, such as Amblyomma americanum, Amblyomma variegatum, Ambryomma maculatum, Argas persicus, Boophilus annulatus, Boophilus decoloratus, Boophilus dermacentorum, Dermacentmacentus, Dermacentmacentus, Dermacentmacentus, Dermacentmacentus, Dermacentmacent variabilis, Hyalomma truncatum, Ixodes ricinus, Ixodes rubicundus, Ixodes scapularis, Ixodes holocyclus, Ixodes pacificus, Ornithodorus moubata, Ornithodorus hermsi, Ornithodorus turicata, Ornithonyssus bacoti, Otobius megnini, Dermanyssus gallinae, Psoroptes ovis, Rhipicephalus sanguineus, Rhipicephalus appendiculatus, Rhipicephalus evertsi, Sarcoptes scabiei, and Eriophyidae spp. such as Aculus schlechtendali, Phyllocoptrata oleivora and Eriophyes sheldoni; Tarsonemidae spp. such as Phytonemus pallidus and Polyphagotarsonemus latus; Tenuipalpidae spp. such as Brevipalpus phoenicis; Tetranychidae spp. such as Tetranychus cinnabarinus, Tetranychus kanzawai, Tetranychus pacificus, Tetranychus telarius and Tetranychus urticae, Panonychus ulmi, Panonychus citri, and Oligonychus pratensis; Araneida, for example Latrodectus mactans, and Loxosceles reclusa,

Other animal pests that must be controlled and fought by the methods of the present invention are:

From the Pemphigidae family: Eriosoma spp., Pemphigus spp., Anuraphis spp., Brachycaudus spp., In crops such as, for example, pip fruit, conifers, vegetables and ornamental plants.

From the psyllid family (Psyllidae: Psylla spp., Paratrioza spp., Trioza spp., In crops such as, for example, citrus fruits, vegetables, potatoes, pip fruits.

From the cochineal insect family (Coccidae: Ceroplastes spp., Drosicha spp. Pulvinaria spp., Protopuhninaria spp., Saissetia spp., Coccus spp., In perennial crops such as, for example, citrus, vine, tea, pip fruits and bone) tropical, ornamental, coniferous, but also vegetable crops.

From the Diaspididae family: Quadraspidiotus spp., Aonidiella spp., Lepidosaphes spp., Aspidiotus spp., Aspis spp., Diaspis spp., Parcastoria sp., In crops such as citrus, tea, ornamental plants, conifers, pome and bone fruits, vines, tropical crops.

From the Pseudococcidae family: Pericerga, Pseudococcus spp., Planococcus spp., Phenacoccus spp., Dysmicoccus spp., In crops such as, for example, citrus fruits, pip and bone fruits, tea, vines, vegetables, ornamental plants, conifers, spices and tropical crops.

Additionally from the Aleyrodidae family: Bemisia argentifolii, Bemisia tabaci, Trialeurodes vaporariorum, Aleurothrixus floccosus, Aleurodes spp., Dialeurodes spp., Parabemisia myricae in crops such as, for example, vegetables, melons, potatoes, tobacco, soft fruits, citrus fruits, ornamentals , conifers, cotton, potatoes and tropical crops. Additionally from the Aphids family:

Myzus spp. in tobacco, stone fruit, pip fruit, soft fruits, brassica vegetables, fruit vegetables, leaf vegetables, root vegetables and tubers, melons, potatoes, spices, ornamentals and conifers.

Aphis spp. in cotton, tobacco, citrus fruits, melons, beets, soft fruit, oilseed rape, fruit vegetables, leafy vegetables, brassica vegetables, tuber and root vegetables, ornamentals, potatoes, zucchini, spices. Rhodobium porosum in strawberries,

Nasonovia ribisnigri in leafy vegetables,

Macrosiphum spp. in ornamental plants, cereals, potatoes, leafy vegetables, brassica vegetables and fruiting vegetables, strawberries, Phorodon humuli in hops, Toxoptera spp. in citrus fruits, stone fruits, almonds, nuts, cereals, spices,

Aulacorthum spp. in citrus fruits, potatoes, fruit vegetables and leafy vegetables.

Additionally the following from the Tetranychidae family: Tetranychus spp., Brevipalpus spp., Panonychus spp., Oligonycbus spp., Eotetranychus spp., Bryobia spp. in crops such as, for example, vegetables, ornamental plants, spices, conifers, citrus fruits, stone fruits and seeds, vines, cotton, soft fruits, melons, potatoes. The following from the Tarsonemidae family: Hermitarsonernus batus, Stenotarsonemus spp., Polyphagotarsonemus spp., Stenotarsonemus spinki in crops such as, for example, vegetables, ornamental plants, spices, conifers, tea, citrus fruits, melons.

In addition to the following from the thrips family (Thripidae): Anaphothrips spp., Baliothrips spp., Caliothrips spp., Frariklirúella spp., Heliothrips spp., Hercrnothrips spp., Rhipiphorothrips spp., Scirtothrips spp. and Thrips spp., in crops such as, for example, fruits, cotton, vines, soft fruits, vegetables, melons, ornamental plants, spices, conifers, tropical crops, tea.

Also the following from the whitefly family (Agromyzidae): Liriomyza spp., Pegomya spp. in crops such as, for example, vegetables, melons, potatoes and ornamentals.

Also the following from the family of leaf nematodes (Aphelenchoididae), for example, Aphelenchoides ritzemabosi, A. fragariae, A. besseyi, A. blastophthorus in crops such as soft and ornamental fruits.

The methods of the present invention are applied to control and combat arachnids, especially the following from the Tetranychidae family: Tetranychus spp., Brevipalpus spp., Panonychus spp., Oligonycbus spp., Eotetranychus spp. and Bryobia spp.

When combined with fungicidal active ingredients in the methods according to the present invention, mixtures of compounds of formula I are also especially suitable for effectively fighting phytopathogenic fungi.

These mixtures have excellent activity against a broad spectrum of phytopathogenic fungi, Ascomycetes, Basidiomycetes, Deuteromycetes and Peronosporomycetes (without. Oomycetes). Some of them are systemically effective and can be used in crop protection as foliar fungicides, as fungicides for seed preparation and as fungicides for soil. They can also be used to treat seeds. They are particularly important in controlling a multitude of fungi in various cultivated plants, such as wheat, rye, barley, oats, rice, corn, grass, bananas, cotton, soybeans, coffee, sugar cane, vines, fruits and ornamental plants , and vegetables such as cucumbers, beans, tomatoes, potatoes and cucurbitaceae, and in the seeds of these plants.

They are especially suitable for controlling the following plant diseases: Albugo spp. (white rust) in ornamental plants, vegetables (for example, A. candida) and sunflowers (for example, A. tragopogonis); Alternaria spp. (Alternaria leaf spot) in vegetables, rapeseed (A. brassicola or brassicae), sugar beet (A. tenuis), fruits, rice, soybeans, potatoes (for example, A. solani or A. alternata), tomatoes (for example, A. solani or A.

alternata) and wheat; Aphanomyces spp. in sugar beet and vegetables; Ascochyta spp. in cereals and vegetables, for example A. tritici (anthracnose) in wheat and A. hordei in barley; Bipolaris and Drechslera spp. (teleomorph: Cochliobolus spp.), for example Southern leaf blight (D. maydis) or northern leaf blight (B. zeicola) in corn, for example spot spot (B. sorokiniana) on cereals and for example B. oryzae in rice and grass; Blumeria (formerly Erysiphe) graminis (powdery mildew) in cereals (for example, in wheat or barley); Botrytis cinerea (teleomorph: Botryotinia fuckeliana: gray mold) in fruits and berries (for example, Strawberries), vegetables (for example lettuce, carrots, celery and cabbage), rapeseed, flowers, vines, forest plants and wheat; Bremia lactucae (hairy mildew) on lettuce; Ceratocystis (sin. Ophiostoma) spp. (rotting or wilting) in broadleaf trees and evergreens, for example C. ulmi (Dutch elm disease) in elms; Cercospora spp. (Cercospora leaf spots) on corn (for example, Gray leaf spot: C. zeae-maydis), rice, sugar beet (for example, C. beticola), sugarcane, vegetables, coffee, beans of soy (for example, C. sojina or C. kikuchii) and rice; Cladosporium spp. in tomatoes (for example, C. fulvum: spike mold) and cereals, for example C. herbarum (black spike) in wheat; Claviceps purpurea (ergot) in cereals; Cochliobolus (anamorph: Bipolaris helmintosporio) spp. (leaf spots) in corn (C. carbonum), cereals (for example, C. sativus, anamorph: B. sorokiniana) and rice (for example, C. miyabeanus, anamorph: H. oryzae); Colletotrichum (teleomorph: Glomerella) spp. (anthracnose) in cotton (for example, C. gossypii), corn (for example, C. graminicola: anthracnose stem rot), soft fruits, potatoes (for example, C. coccodes: black dot), beans (for example , C. lindemutianum) and soybeans (for example, C truncatum or C. gloeosporioides); Corticium spp., For example C. sasakii (sheath blight) on rice; Corinespora cassiicola (leaf spots) in soy and ornamental; Cicloconium spp., For example C. oleaginum in olive trees; Cylindrocarpon spp. (for example, fruit tree canker or young vine decline, teleomorph: Nectria or Neonectria spp.) in fruit trees, vines (for example, C. liriodendri, teleomorph: Neonectria liriodendri: Black foot disease) and ornamental plants; Dematophora (teleomorph: Rosellinia) necatrix (root and stem rot) in soybeans; Diaporthe spp., For example D. phaseolorum (foot rot) in soybeans; Drechslera (sin. Helminthosporium, teleomorph: Pirenophora) spp. in corn, cereals, such as barley (for example, D. teres, red spots) and wheat (for example, D. tritici-repentis: bronze colored spots), rice and grass; Esca (dieback, stroke) in vines, caused by Formitiporia (without. Phellinus) punctata, F. mediterranea, Phaeomoniella chlamydospora (formerly Phaeoacremonium chlamydosporum), Phaeoacremonium aleophilumand or Botryosphaeria derusa; Elsinoe spp. in fruits of seeds (E. piri), soft fruits (E. veneta: anthracnose) and vines (E. ampelina: anthracnose); Entyloma oryzae (leaf blight) in rice; Epicoccum spp. (black mold) in wheat; Erysiphe spp. (powdery mildew) in sugar beet (E. betae), vegetables (for example, E. pisi), such as cucurbits (for example, E. cichoracearum), cabbage, rapeseed (for example, E. cruciferarum); Eutypa can (Eutypa canker or wilting, anamorph: Cytosporina lata, without. Libertella blepharis) in fruit trees, vines and ornamental forests; Exserohilum (sin. Helminthosporium) spp. in corn (for example, E. turcicum); Fusarium (teleomorph: Gibberella) spp. (wilting, root or stem rot) in various plants, such as F. graminaarum or F. culmorum (root rot, scab or head blight) in cereals (eg wheat or barley), F. oxisporum in tomatoes, F. solani (f .ly. glycines now without. F. virguliforme) and F. tucumaniae and F. brasiliense causing sudden death syndrome in soybeans, and F. verticillioides in corn; Gaeumannomyces graminis (take-all) in cereals (for example, wheat or barley) and corn; Gibberella spp. in cereals (for example, G. zeae) and rice (for example, G. fujikuroi: Bakanae disease); Glomerella cingulataon vines, pip fruits and other plants and G. gossypii in cotton; grain staining complex in rice; Guignardia bidwellii (black rot) in vines; Gymnosporangium spp. in rosacea and juniper plants, for example G. sabinae (rust) in pears; Helminthosporium spp. (without Drechslera, teleomorph: Cochliobolus) in corn, cereals and rice; Hemileia spp., For example H. vastatrix (coffee leaf rust) in coffee; Isariopsis clavispora (without. Cladosporium vitis) in vines; Macrophomina phaseolina (without. Phaseoli) (root and stem rot) in soybeans and cotton; Microdochium (sin. Fusarium) nivale (pink snow mold) in cereals (for example, wheat or barley); Microsphaera diffusa (powdery mildew) in soybeans; Monilinia spp., For example M. laxa, M. fructicola and M. fructigena (blight of flowering and twig, brown rot) in stone fruits and other rosacea plants; Mycosphaerella spp. in cereals, bananas, soft fruits and ground nuts, such as for example M. graminicola (anamorph: Septoria tritici, Septoria spot) in wheat or M. fijiensis (black Sigatoka disease) in bananas; Peronospora spp. (hairy mildew) on cabbage (for example, P. brassicae), rapeseed (for example, P. parasitica), onions (for example, P. destructor), tobacco (P. tabacina) and soybeans (for example, P manshurica); Phakopsora pachyrhizi and P. meibomiae (soybean rust) in soybeans; Phialophora spp. for example in vines (for example, P. tracheiphila and P. tetraspora) and soybeans (for example, P. gregata: stem rot); Phoma lingam (root and stem rot) in rapeseed and cabbage and P. betae (root rot, leaf spot and foot rot) in sugar beet; Phomopsis spp. in sunflowers, vines (for example, P. viticola: can and leaf spot) and soybeans (for example, stem rot: P. phaseoli, teleomorph: Diaporthe phaseolorum); Physoderma maydis (brown spots) in corn; Phytophthora spp. (wilting, root, leaf, fruit and stem root) in various plants, such as paprika and cucurbitaceae (for example, P. capsici), soybeans (for example, P. megasperma, without P. sojae), potatoes and tomatoes (for example, P. infestans: late blight) and broadleaf trees (for example, P. ramorum: sudden death of oak); Plasmodiophora brassicae (club root) in cabbages, cabbages, radishes and other plants; Plasmopara spp., For example P. viticola (hairy mold) in vines and P. halstedii in sunflowers; Podosphaera spp. (powdery mildew) in pinkish plants, hops, nuggets and soft fruits, for example P. leucotricha in apples; Polymyxa spp., For example in cereals, such as barley and wheat (P. graminis) and sugar beet (P. betae) and, therefore, transmit viral diseases; Pseudocercosporella herpotrichoides (ocular spot, teleomorph: Tapesia yallundae) in cereals, for example wheat or barley Pseudoperonospora (hairy mildew) in various plants, for example P. cubensis in cucurbitaceae or P. humili in hops; Pseudopezicula tracheiphila (red fire disease or, rotbrenner ', anamorph: Phialophora) in vines; Puccinia spp. (rusts) in various plants, for example P. triticina (brown or leaf rust), P. striiformis (yellow stripe or rust), P. hordei (dwarf rust), P. graminis (black or stem rust) or P Recondite (brown or leaf rust) in cereals, such as wheat, barley or rye, P. kuehnii (orange rust) in sugarcane and P. asparagi in asparagus; Pyrenephora (anamorph: Drechslera) tritici-repentis (cinnamon stain) in wheat or P. teres (red spot) in barley; Piricularia spp., For example P. oryzae (teleomorph: Magnaporthe grisea, rice explosion) in rice and P. grisea in grass and cereals; Pythium spp. (foot rot) in grass, rice, corn, wheat, cotton, rapeseed, sunflowers, soybeans, sugar beets, vegetables and other plants (for example, P. ultimum or P. aphanidermatum); Ramularia spp., For example R. collo-cygni (Ramularia leaf spots, Physiological leaf spots) in barley and R. beticola in sugar beet; Rhizoctonia spp. in cotton, rice, potatoes, grass, corn, rapeseed, potatoes, sugar beets, vegetables and other plants, for example R. solani (root and stem rot) in soybeans, R. solani (pod blight) in rice or R. cerealis (Rhizoctonia spring blight) in wheat or barley; Rhizopus stolonifer (black mold, soft rot) in strawberries, carrots, cabbage, vines and tomatoes; Rhinchosporium secalis (scalded) in barley, rye and triticale; Sarocladium oryzae and S. attenuatum (pod rot) in rice; Sclerotinia spp. (stem rot or white mold) in vegetables and field crops, such as rapeseed, sunflowers (for example, S. sclerotiorum) and soybeans (for example, S. rolfsii or S. sclerotiorum); Septoria spp. in various plants, for example S. glycines (brown spot) in soybeans, S. tritici (Septoria spot) in wheat and S. (without. Stagonospora) nodorum (Stagonospora spot) in cereals; Uncinula (sin. Erysiphe) necator (powdery mildew, anamorph: Oidium tuckeri) in vines; Setospaeria spp. (leaf blight) in corn (for example, S. turcicum, sin. Helminthosporium turcicum) and grass; Sphacelotheca spp. (tizne) in corn, (for example, S. reiliana: head tizne), sorghum and sugarcane; Sphaerotheca fuliginea (powdery mildew) in cucurbitaceae; Spongospora subterranea (powder crust) in potatoes and, therefore, transmits viral diseases; Stagonospora spp. in cereals, for example S. nodorum (Stagonospora blotch, teleomorph: Leptosphaeria [sin. Phaeosphaeria] nodorum) in wheat; Sinchytrium endobioticum in potatoes (potato wart disease); Taphrina spp., For example T. deformans (disease of the curvature of the leaf) in peaches and T. pruni (pocket of plum) in plums; Thielaviopsis spp. (black root rot) in tobacco, grapefruit fruits, vegetables, soybeans and cotton, for example T. basicola (without. Chalara elegans); Tilletia spp. (common stinky or smelly blight) in cereals, such as T. tritici (sin. T. caries, stinky of wheat) and T. controversa (stinky dwarf) in wheat; Typhula incarnata (gray snow mold) in barley or wheat; Urocystis spp., For example U. occulta (stinky stalk) in rye; Uromyces spp. (rust) in vegetables, such as beans (for example, U. appendiculatus, without. U. phaseoli) and sugar beet (for example, U. betae); Ustilago spp. (loose stinky) in cereals (for example, U. nuda and U. avaenae), corn (for example, U. maydis: corn) and sugarcane; Venturia spp. (scabies) in apples (for example, V. inaequalis) and pears; and Verticillium spp. (wilting) in various plants, such as fruits and ornamentals, vines, soft fruits, vegetables and field crops, for example V. dahliae in strawberries, rapeseed, potatoes and tomatoes.

Mixtures and combinations of preferred compounds.

Preferred mixtures and combinations of the carboxamid compound of formula (I) with other active ingredients for soil application and seed treatment methods are described below.

In one embodiment of the present invention, the pesticidal active carboxamide compound of formula (I): or the tautomers, enantiomers, diastereomers or salts thereof are combined and used in admixture with at least one other agriculturally active compound selected from the group of insecticides and / or fungicides consisting of fluxapiroxad, epoxiconazole, triticonazole, abamectin, emamectin, ciantraniliprol, chlorantraniliprol, thiacloprid. In another embodiment of the invention, the pesticidal compound of formula (I) is combined and used in admixture with at least one active compound selected from fluxapiroxad, epoxiconazole, triticonazole, abamectin, emamectin, ciantraniliprole, chlorantraniliprole or thiacloprid and at least one other compound. active applied in agriculture such as another active insecticide, an active fungicide or a biopesticide. Therefore, in the embodiments described above, the pesticidal compound of formula (I) may be combined and used in admixture with one, two, three or four other agriculturally active compounds selected from fungicides and / or insecticides. Preferably, other compounds are active against said arthropod pests that live in the soil or phytopathogenic fungi of the soil. A person skilled in the art is familiar with such compounds and knows which compounds are active against a specific target organism.

The following lists M of pesticides and F of fungicides together with which the combinations according to the invention can be used and with which potential synergistic effects could also occur, are intended to illustrate the possible combinations, but not impose any limitations: List M of pesticides, grouped and numbered according to the Mode of Action Classification of the Insecticide Resistance Action Committee (IRAC), together with which the compounds according to the invention can be used and with which potential synergistic effects could occur, intends illustrate possible combinations, but not to impose any limitations:

M.1 Acetylcholine esterase (AChE) inhibitors of the class of

M.1A carbamates, for example aldicarb, alanycarb, bendiocarb, benfuracarb, butocarboxim, butoxycarboxim, carbaryl, carbofarulfan, ethiofencarb, fenobucarb, formetanate, furathiocarb, isoprocarb, methiocarb, methomyl, metolcarb, oxamyl, pirimicarb, propoxur, thiodicarb, thiofanox, trimethacarb , XMC, xylilcarb and triazamate; or of the M.1B class of organophosphates, for example, acetate, azamethifos, azinfos-ethyl, azinfosmethyl, cadusafos, chloretoxyphos, chlorfenvinfos, chlormephos, chlorpyrifos, chlorpyrifos-methyl, coumaphos, cyanophos, demeton-S-methyl, diazin, / DDVP, dicrotophos, dimethoate, dimethylvinphos, disulfoton, EPN, etion, ethoprophos, famphur, fenamiphos, fenitrotion, fention, fostiazato, heptenophos, imiciafos, isofenphos, isopropyl O- (methoxyaminotio-phosphoryl), methylate, methylamidium, methacrylate, methacrylamide, methacrylate, methacrylate, methacrylate, methacrylate, methacrylate, methacrylate, methacrylate, methacrylate, methacrylate, methacrylate, methacrylate, methacrylate, methacrylate, methacrylate, methacrylate, methacrylate, methacrylate, methacrylate, methacrylate, methacrylate, methacrylate, methacrylate, methacrylate, methacrylate, methylamotamide , metidation, mevinfos, monocrotophos, naled, ometoate, oxidemetonmethyl, paration, paration-methyl, fentoate, forate, fosalone, fosmet, fosfamidon, foxim, pyrimiphos-methyl, prophenophos, propetamfos, protiophos, pyraclophos, piridafentimotyp, quinal tepphthio, quinal , temefos, terbufos, tetrachlorvinfos, tiometon, triazofos, trichlorfon and vamidotion;

M.2. GABA regulated chloride channel antagonists, such as:

M.2A Organochlorine cyclodiene compounds, such as endosulfan or chlordane; or

M.2B fiproles (phenylpyrazols), such as etiprole, fipronil, flufiprole, pyrafluprole and pyriprole;

M.3 Sodium channel modulators of the class of

M.3A pyrethroids, for example acrinatrina alletrina d-cis-trans alletrina d-trans alletrina biphentrine bioallethrin bioallethrin S-cilclopentenyl, bioresmetrin, cycloprotrin, ciflutrin, beta-ciflutrin, cihalotrin, lambda-cihalotrin, gamma-cihalotrin, gamma-alpha-cihalotrin cypermethrin, beta-cypermethrin, teta-cypermethrin, zeta-cypermethrin, ciphenotrin, deltamethrin, empentrin, esfenvalerate, etofenprox, fenpropatrin, fenvalerate, flucitrinate, flumetrin, tau-fluvaltrininate, halfentrintin, methrintrintrintrin, heptatrinphthinphthrinphthintrin, heptatrintrinimine, halfentrintrintin, mothintrinrinthrinthintrin, methrintrintrinimin, halfenintrintrintin, halfentrinphthintrin, methopintrinimine, halfenintrintrintin, mothintrintrinin, halfenintrintrinin, methylentrintrintriniminomethophenimine, halfenintrintrin, permeate fenotrin, pralletrin, proflutrin, piretrin (piretrum), resmetrin, silafluofen, teflutrin, tetramethylflutrin, tetrametrin, tralometrin and transflutrin; or

M.3B sodium channel modulators such as DDT or methoxychlor;

M.4 Nicotinic acetylcholine receptor (nAChR) agonists of the class of

M.4A neonicotinoids, for example acteamiprid, clotianidin, cycloxaprid, dinotefuran, imidacloprid, nitenpyram, thiacloprid and thiamethoxam; or the compounds

M.4A.2: (2E -) - 1 - [(6-Chloropyridin-3-yl) methyl] -N'-nitro-2-pentylidenehydrazinecarboximidamide; or

M4.A.3: 1 - [(6-Chloropyridin-3-yl) methyl] -7-methyl-8-nitro-5-propoxy-1,2,3,5,6,7-hexahydroimidazo [1,2 -a] pridine;

or of the class M.4B nicotine;

M.5 Allosteric activators of the nicotinic acetylcholine receptor of the spinosyne class, for example, spinosad or spinetoram;

M.6 Chloride channel activators of the avermectin and milbemycin class, for example, abamectin, emamectin benzoate, ivermectin, lepimectin or milbemectin;

M.7 Juvenile hormone imitators, such as

M.7A analogs of juvenile hormones such as hydroprene, cinoprene and metoprene; or others like

M.7B phenoxycarb or M.7C pyriproxyphene;

M.8 several non-specific inhibitors (multiple sites), for example

M.8A alkyl halides such as methyl bromide and other alkyl halides, or

M.8B chloropicrin, or M.8C sulfuryl fluoride, or M.8D borax, or M.8E emetic tartar;

M.9 Selective homoptera feed blockers, for example M.9B pimetrozin, or M.9C flonicamid; M.10 Mite growth inhibitors, for example, M.10A clofentezine, hexithiazox and diflovidazine or M.10B ethoxazole;

M.11 Microbial switches of the midgut membranes of the insect, for example, bacillus thuringiensis or bacillus sphaericus, and the insecticdal proteins they produce, such as bacillus thuringiensis subsp. israelensis, bacillus sphaericus, bacillus thuringiensis subsp. aizawai, bacillus thuringiensis subsp. Kurstaki and bacillus thuringiensis subsp. tenebrionis, or Bt culture proteins: Cry1Ab, Cry1Ac, Cry1Fa, Cry2Ab, mCry3A, Cry3Ab, Cry3Bb and Cry34 / 35Ab1;

M.12 Mitochondrial ATP synthase inhibitors, for example

M.12A diafentiuron, or

M.12B organotin miticides such as azocyclotin, cyhexatin or fenbutatin oxide, or M.12C propargite, or M.12D tetradifon;

M.13 Decouplers of oxidative phosphorylation by interrupting the proton gradient, for example, chlorfenapir, DNOC or sulfluramide;

M.14 Nicotinic acetylcholine (nAChR) receptor channel blockers, for example, nereistoxin analogs such as bensultap, cartap hydrochloride, thiocyclam or sodium thiosultap;

M.15 Inhibitors of type 0 chitin biosynthesis, such as benzoylureas such as bistrifluron, chlorfluazuron, diflubenzuron, flucycloaluron, flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, teflubenzuron or triflumuron;

M.16 Type 1 chitin biosynthesis inhibitors, such as buprofezin;

M.17 Mute switches, Dipteran, such as chromazine;

M.18 Ecdyson receptor agonists, such as diacylhydrazines, for example, methoxyphenozide, tebufenozide, halofenozide, fuphenozide or chromaphenozide;

M.19 Octopamine receptor agonists, such as amitraz;

M.20 Electron transport inhibitors of the mitochondrial complex III, for example, M.20A hydramethylnon, or M.20B acequinocil, or M.20C fluacripirim;

M.21 Electron transport inhibitors of the mitochondrial complex I, for example, M.21A METI acaricides and insecticides such as fenazaquin, fenpyroximate, porimidifen, pyridaben, tebufenpirad or tolfenpirad, or M.21B rotenone; M.22 Voltage-dependent sodium channel blockers, for example

M.22A indoxacarb, or M.22B metaflumizone, or M.22B.1: 2- [2- (4-Cyanophenyl) -1- [3- (trifluoromethyl) phenyl] ethylidene] -N- [4- (difluoromethoxy) phenyl] -hydrazinecarboxamide or

M.22B.2: N- (3-Chloro-2-methylphenyl) -2 - [(4-chlorophenyl) [4- [methyl (methylsulfonyl) amino] phenyl] methylene] -hydrazinecarboxamide; M.23 Acetyl CoA carboxylase inhibitors, such as those derived from tetronic and tetramic acid, for example, spirodiclofen, spiromasifene or spirotetramate;

M.24 Electron transport inhibitors of the mitochondrial IV complex, for example, M.24A phosphine, such as aluminum phosphide, calcium phosphide, phosphine or zinc phosphide, or M.24B cyanide;

M.25 Electron transport inhibitors of the mitochondrial complex II, such as beta-ketoneitrile derivatives, for example, cenopyrophen or ciflumetophen;

M.28 Ryanodine receptor modulators of the diamides class, such as flubendiamide, chlorantraniliprol (rinaxypir®), Ciantraniliprol (cyazypir®), or phthalamide compounds

M.28.1: (R) -3-Chlor-N1- {2-methyl-4- [1,2,2,2-tetrafluor-1- (trifluoromethyl) ethyl] phenyl} -N2- (1-methyl-2 -methylsulfonylethyl) phthalamide and M.28.2: (S) -3-Chlor-N1- {2-methyl-4- [1,2,2,2-tetrafluor-1- (trifluoromethyl) ethyl] phenyl} -N2- ( 1-methyl-2-methylsulfonylethyl) phthalamide, or the compound

M.28.3: 3-bromo-N- {2-bromo-4-chloro-6 - [(1-cyclopropylethyl) carbamoyl] phenyl} -1- (3-chlorpyridin-2-yl) -1H-pyrazole-5- carboxamide (proposed ISO name: cyclaniliprole), or the compound

M.28.4: methyl-2- [3,5-dibromo-2 - ({[3-bromo-1- (3-chlorpyridin-2-yl) -1H-pyrazol-5-yl] carbonyl} amino) benzoyl] -1,2-dimethylhydrazinecarboxylate; or a compound selected from

M.28.5a) to M.28.51):

M.28.5a) N- [4,6-didoro-2 - [(diethyl-lambda-4-sulfaniliden) carbamoyl] -phenyl] -2- (3-doro-2-pyridyl) -5- (trifluoromethyl) pyrazole -3-carboxamide;

M.28.5b) N- [4-doro-2 - [(diethyl-lambda-4-sulfaniliden) carbamoyl] -6-methyl-phenyl] -2- (3-doro-2-pyridyl) -5- (trifluoromethyl ) pyrazol-3-carboxamide;

M.28.5c) N- [4-chloro-2 - [(di-2-propyl-lambda-4-sulfaniliden) carbamoyl] -6-methyl-phenyl] -2- (3-chloro-2-pyridyl) - 5- (trifluoromethyl) pyrazol-3-carboxamide;

M.28.5d) N- [4,6-dichloro-2 - [(di-2-propyl-lambda-4-sulfaniliden) carbamoyl] -phenyl] -2- (3-chloro-2-pyridyl) -5- (trifluoromethyl) pyrazol-3-carboxamide;

M.28.5e) N- [4,6-dichloro-2 - [(diethyl-lambda-4-sulfaniliden) carbamoyl] -phenyl] -2- (3-chloro-2-pyridyl) -5- (difluoromethyl) pyrazole -3-carboxamide;

M.28.5f) N- [4,6-dibromo-2 - [(di-2-propyl-lambda-4-sulfaniliden) carbamoyl] -phenyl] -2- (3-chloro-2-pyridyl) -5- (trifluoromethyl) pyrazol-3-carboxamide;

M.28.5g) N- [4-chloro-2 - [(di-2-propyl-lambda-4-sulfaniliden) carbamoyl] -6-cyano-phenyl] -2- (3-chloro-2-pyridyl) - 5- (trifluoromethyl) pyrazol-3-carboxamide;

M.28.5h) N- [4,6-dibromo-2 - [(diethyl-lambda-4-sulfaniliden) carbamoyl] -phenyl] -2- (3-chloro-2-pyridyl) -5- (trifluoromethyl) pyrazole -3-carboxamide;

M.28.5i) N- [2- (5-Amino-1,3,4-thiadiazol-2-yl) -4-chloro-6-methylphenyl] -3-bromo-1- (3-doro-2- pyridinyl) -1H-pyrazol-5-carboxamide;

M.28.5j) 3-Chloro-1- (3-chloro-2-pyridinyl) -N- [2,4-didoro-6 - [[(1-cyano-1-methylethyl) amino] carbonyl] phenyl] - 1H-pyrazol-5-carboxamide;

M.28.5k) 3-Bromo-N- [2,4-dichloro-6- (methylcarbamoyl) phenyl] -1- (3,5-didoro-2-pyridyl) -1 H -pyrazol-5-carboxamide;

M.28.51) N- [4-Chloro-2 - [[(1,1-dimethylethyl) amino] carbonyl] -6-methylphenyl] -1- (3-chloro-2-pyridinyl) -3- (fluoromethoxy) - 1H-pyrazol-5-carboxamide;

or a compound selected from

M.28.6: N- (2-cyanopropan-2-yl) -N- (2,4-dimethylphenyl) -3-iodobenzene-1,2-dicarboxamide; or

M.28.7: 3-Chloro-N- (2-cyanopropan-2-yl) -N- (2,4-dimethylphenyl) -benzene-1,2-dicarboxamide;

M.28.8a) 1- (3-Chloro-2-pyridinyl) -N- [4-cyano-2-methyl-6 - [(methylamino) carbonyl] phenyl] -3 - [[5- (trifluoromethyl) -2H -tetrazol-2-yl] methyl] -1 H -pyrazol-5-carboxamide; or

M.28.8b) 1- (3-Chloro-2-pyridinyl) -N- [4-cyano-2-methyl-6 - [(methylamino) carbonyl] phenyl] -3 - [[5- (trifluoromethyl) -1H -tetrazol-1-yl] methyl] -1 H -pyrazol-5-carboxamide;

M.UN. insecticidal active compounds of unknown or uncertain mode of action, such as afidopiropen, afoxolaner, azadiractin, amidoflumet, benzoximate, bifenazate, bromopropylate, quinomethionat, criolite, dicofol, flufenerim, flometoquin, fluensulfone, fluopiram, flupiradione, flupirazone , piflubumide, pyridalyl, pyrifluquinazon, sulfoxaflor, thioxazafen, triflumezopyrim, or the compounds

M.UN.3: 11- (4-chloro-2,6-dimethylphenyl) -12-hydroxy-1,4-dioxa-9-azadiespiro [4.2.4.2] -tetradec-11-en-10-one, or the compound

M.UN.4: 3- (4'-fluoro-2,4-dimethylbiphenyl-3-yl) -4-hydroxy-8-oxa-1-azaspiro [4.5] dec-3-en-2-one, or compound M.UN.5: 1- [2-fluoro-4-methyl-5 - [(2,2,2-trifluoroethyl) sulfinyl] phenyl] -3- (trifluoromethyl) -1H-1,2,4- triazol-5-amine, or active on the basis of bacillus firmus (Votive, I-1582); or a compound selected from the group of M.UN.6, wherein the compound is selected from M.UN.6a) to M.UN.6k):

M.UN.6a) (E / Z) -N- [1 - [(6-chloro-3-pyridyl) methyl] -2-pyridyliden] -2,2,2-trifluoroacetamide;

M.UN.6b) (E / Z) -N- [1 - [(6-chloro-5-fluoro-3-pyridyl) methyl] -2-pyridyliden] -2,2,2-trifluoroacetamide;

M.UN.6c) (E / Z) -2,2,2-trifluoro-N- [1 - [(6-fluoro-3-pyridyl) methyl] -2-pyridyliden] acetamide;

M.UN.6d) (E / Z) -N- [1 - [(6-bromo-3-pyridyl) methyl] -2-pyridyliden] -2,2,2-trifluoroacetamide;

M.UN.6e) (E / Z) -N- [1- [1- (6-doro-3-pyridyl) ethyl] -2-pyridyliden] -2,2,2-trifluoroacetamide;

M.UN.6f) (E / Z) -N- [1 - [(6-doro-3-pyridyl) methyl] -2-pyridyliden] -2,2-difluoroacetamide;

M.UN.6g) (E / Z) -2-doro-N- [1 - [(6-doro-3-pyridyl) methyl] -2-pyridyliden] -2,2-difluoroacetamide;

M.UN.6h) (E / Z) -N- [1 - [(2-doropyrimidin-5-yl) methyl] -2-pyridyliden] -2,2,2-trifluoroacetamide;

M.UN.6Í) (E / Z) -N- [1 - [(6-doro-3-pyridyl) methyl] -2-pyridyliden] -2,2,3,3,3-pentafluoro-propanamide.) ;

M.UN.6j) N- [1 - [(6-doro-3-pyridyl) methyl] -2-pyridyliden] -2,2,2-trifluoro-thioacetamide or compound

M.UN.6k) N- [1 - [(6-don> 3-pyridyl) methyl] -2-pyridyliden] -2,2,2-trifluoro-N-isopropN-acetamidma

or the compounds

M.UN.8: 8-doro-N- [2-doro-5-methoxyphenyl) sulfonyl] -6-trifluoromethyl) -imidazo [1,2-a] pyridine-2-carboxamide; or

M.UN.9: 4- [5- (3,5-didorophenyl) -5- (trifluoromethyl) -4H-isoxazol-3-yl] -2-methyl-N- (1-oxothietan-3-yl) benzamide ; or

M.UN.10: 5- [3- [2,6-didoro-4- (3,3-didoroalyloxy) phenoxy] propoxy] -1H-pyrazole; or a compound selected from the group of M.UN.11, wherein the compound is selected from M.UN.11b) to M.UN.11p):

M.UN.11.b) 3- (benzoylmethylamino) -N- [2-bromo-4- [1,2,2,3,3,3-hexafluoro-1- (trifluoromethyl) propyl] -6- (trifluoromethyl ) phenyl] -2-fluoro-benzamide;

M.UN.11.c) 3- (benzoylmethylamino) -2-fluoro-N- [2-iodo-4- [1,2,2,2-tetrafluoro-1- (trifluoromethyl) ethyl] -6- (trifluoromethyl ) phenyl] -benzamide;

M.UN.11.d) N- [3 - [[[2-iodo-4- [1,2,2,2-tetrafluoro-1- (trifluoromethyl) ethyl] -6- (trifluoromethyl) phenyl] amino] carbonyl] phenyl] -N-methylbenzamide;

M.UN.11.e) N- [3 - [[[2-Bromo-4- [1,2,2,2-tetrafluoro-1- (trifluoromethyl) ethyl] -6- (trifluoromethyl) phenyl] amino] carbonyl] -2-fluorophenyl] -4-fluoro-N-methyl-benzamide;

M.UN.11.f) 4-fluoro-N- [2-fluoro-3 - [[[2-iodo-4- [1,2,2,2-tetrafluoro-1- (trifluoromethyl) ethyl] -6 - (trifluoromethyl) phenyl] amino] carbonyl] phenyl] -N-methyl-benzamide;

M.UN.11.g) 3-fluoro-N- [2-fluoro-3 - [[[2-iodo-4- [1,2,2,2-tetrafluoro-1- (trifluoromethyl) ethyl] -6 - (trifluoromethyl) phenyl] amino] carbonyl] phenyl] -N-methyl-benzamide;

M.UN.11.h) 2-Chloro-N- [3 - [[[2-iodo-4- [1,2,2,2-tetrafluoro-1- (trifluoromethyl) ethyl] -6- (trifluoromethyl) phenyl] amino] carbonyl] phenyl] -3-pyridinecarboxamide;

M.UN.11.i) 4-cyano-N- [2-cyano-5 - [[2,6-dibromo-4- [1,2,2,3,3,3-hexafluoro-1- (trifluoromethyl) ) propyl] phenyl] carbamoyl] phenyl] -2-methyl-benzamide;

M.UN.11.j) 4-cyano-3 - [(4-cyano-2-methyl-benzoyl) amino] -N- [2,6-dichloro-4- [1,2,2,3,3 , 3-hexafluoro-1- (trifluoromethyl) propyl] phenyl] -2-fluoro-benzamide;

M.UN.11.k) N- [5 - [[2-chloro-6-cyano-4- [1,2,2,3,3,3-hexafluoro-1- (trifluoromethyl) propyl] phenyl] carbamoyl ] -2-cyano-phenyl] -4-cyano-2-methyl-benzamide;

M.UN.11.l) N- [5 - [[2-bromo-6-chloro-4- [2,2,2-trifluoro-1-hydroxy-1- (trifluoromethyl) ethyl] phenyl] carbamoyl] - 2-cyano-phenyl] -4-cyano-2-methyl-benzamide;

M.UN.11.m) N- [5 - [[2-bromo-6-chloro-4- [1,2,2,3,3,3-hexafluoro-1- (trifluoromethyl) propyl] phenyl] carbamoyl ] -2-cyano-phenyl] -4-cyano-2-methyl-benzamide;

M.UN.11.n) 4-cyano-N- [2-cyano-5 - [[2,6-dichloro-4- [1,2,2,3,3,3-hexafluoro-1- (trifluoromethyl) ) propyl] phenyl] carbamoyl] phenyl] -2-methyl-benzamide;

M.UN.11.o) 4-cyano-N- [2-cyano-5 - [[2,6-didoro-4- [1,2,2,2-tetrafluoro-1- (trifluoromethyl) ethyl] phenyl ] carbamoyl] phenyl] -2-methylbenzamide;

M.UN.11.p) N- [5 - [[2-bromo-6-doro-4- [1,2,2,2-tetrafluoro-1- (trifluoromethyl) ethyl] phenyl] carbamoyl] -2- cyano-phenyl] -4-cyano-2-methyl-benzamide;

or a compound selected from the group of M.UN.12, wherein the compound is selected from M.UN.12a) to M.UN.12m):

M.UN.12.a) 2- (1,3-Dioxan-2-yl) -6- [2- (3-pyridinyl) -5-thiazolyl] -pyridin;

M.UN.12.b) 2- [6- [2- (5-Fluoro-3-pyridinyl) -5-thiazolyl] -2-pyridinyl] -pyrimidine;

M.UN.12.c) 2- [6- [2- (3-Pyridinyl) -5-thiazolyl] -2-pyridinyl] -pi rimidine;

M.UN.12.d) N-Methylsulfonyl-6- [2- (3-pyridyl) thiazol-5-yl] pyridin-2-carboxamide

M.UN.12.e) N-Methylsulfonyl-6- [2- (3-pyridyl) thiazol-5-yl] pyridin-2-carboxamide

M.UN.12.f) N-Ethyl-N- [4-methyl-2- (3-pyridyl) thiazol-5-yl] -3-methylthio-propanamide

M.UN.12.g) N-Methyl-N- [4-methyl-2- (3-pyridyl) thiazol-5-yl] -3-methylthio-propanamide

M.UN.12.h) N, 2-Dimethyl-N- [4-methyl-2- (3-pyridyl) thiazol-5-yl] -3-methylthio-propanamide

M.UN.12.i) N-Ethyl-2-methyl-N- [4-methyl-2- (3-pyridyl) thiazol-5-yl] -3-methylthio-propanamide

M.UN.12.j) N- [4-Chloro-2- (3-pyridyl) thiazol-5-yl] -N-ethyl-2-methyl-3-methylthio-propanamide

M.UN.12.k) N- [4-Chloro-2- (3-pyridyl) thiazol-5-yl] -N, 2-dimethyl-3-methylthio-propanamide

M.UN.12.l) N- [4-Chloro-2- (3-pyridyl) thiazol-5-yl] -N-methyl-3-methylthio-propanamide

M.UN.12.m) N- [4-Chloro-2- (3-pyridyl) thiazol-5-yl] -N-ethyl-3-methylthio-propanamide; or the compound

M.UN.13: 2- (4-methoxyiminocyclohexyl) -2- (3,3,3-trifluoropropylsulfonyl) acetonitrile;

or the compounds

M.UN.14a) 1 - [(6-Chloro-3-pyridinyl) methyl] -1,2,3,5,6,7-hexahydro-5-methoxy-7-methyl-8-nitro-imidazo [1 , 2-a] pyridin; or M.UN.14b) 1 - [(6-Chloropyridin-3-yl) methyl] -7-methyl-8-nitro-1,2,3,5,6,7-hexahydroimidazo [1,2-a] pyridin-5-ol; or the compound M.UN.15: 1 - [(2-Chloro-1,3-thiazol-5-yl) methyl] -3- (3,5-dichlorophenyl) -9-methyl-4-oxo-4H- pyrido [1,2-a] pyrimidin-1-ium-2-olate. M.Y Biopesticides, which are pesticidal compounds of biological origin with insecticidal, acaricidal, molluscicidal and / or nematicidal activity, including

MY-1: Microbial pesticides: Bacillus firmus, B. thuringiensis ssp. israelensis, B. t. ssp. galleriae, B. t. ssp. Kurstaki, Beauveria bassiana, Burkholderia sp., Chromobacterium subtsugae, Cydia pomonella granulosis virus, Isaria fumosorosea, Lecanicillium longisporum, L. muscarium (formerly Verticillium lecanii), Metarhizium anisopliae, M. anisopliae var. acridum, Paecilomyces fumosoroseus, P. lilacinus, Paenibacillus poppiliae, Pasteuria spp., P. nishizawae (Clariva®, P. reneformis, P. usagae, Pseudomonas fluorescens, Steinernema feltiae, Streptomces galbus; or active on the basis of bacotus firmus ( Vocivous firmus) ®, l-1582),

MY-2 Biochemical pesticides: L-carvone, citral, (E, Z) -7,9-dodecadien-1-yl acetate, ethyl formate, (E, Z) -2,4-ethyl decadienoate (pear ester) , (Z, Z, E) -7,11,13-hexadecatrienal, heptyl butyrate, isopropyl myristate, lavenulyl senecioate, 2-methyl 1-butanol, methyl eugenol, methyl jasmonate, (E, Z) - 2,13-octadecadien-1-ol, acetate (E, Z) -2,13-octadecadien-1-ol, (E, Z) -3,13-octadecadien-1-ol, R-1-octen- 3-ol, pentatermanone, potassium silicate, sorbitol acetate, (E, Z, Z) -3,8,11-tetradecatrienyl acetate, (Z, E) -9,12-tetradecadien-1-yl acetate, Z-7-tetradecen-2-one, Z-9-tetradecen-1-yl acetate, Z-11-tetradecenal, Z-11-tetradecen-1-ol, black acacia extract, grapefruit seed and pulp extract , Chenopodium ambrosiodae extract, Catnip oil, Neem oil, Quillay extract Tagetes oil or components of the ginkgo tree selected from the group consisting of bilobalide, ginkgolida A, ginkgolida B, ginkgolida C, ginkgolida J yg inkgolida M.

Combinations of the carboxamide compound of formula (I) with one or more insecticidal active compounds selected from the group consisting of thiacloprid, abamectin, emamectin, chlorantraniliprole or ciantranyliprole are preferred.

More preferred is the combination of the carboxamide compound of formula (I) with abamectin. More preferred is the combination of the carboxamide compound of formula (I) with emamectin.

More preferred is the combination of the carboxamide compound of formula (I) with chlorantraniliprol. More preferred is the combination of the carboxamide compound of formula (I) with ciantraniliprol.

The combination of the carboxamide compound of formula (I) with thiacloprid is also highly preferred.

The commercially available compounds of group M listed above can be found in The Pesticide Manual, 15th Edition, C. D. S. Tomlin, British Crop Protection Council (2011) among other publications.

The neonicotinoid cycloxaprid is known from WO20120 / 069266 and WO2011 / 06946, and the neonicotinoid compound M.4A.2, sometimes also called Guadipir, is known from WO2013 / 003977, and the neonicotinoid compound M.4A.3 . (approved as paichongding in China) is known from WO2010 / 069266. The analogue of Metaflumizone M.22B.1 is described in CN 10171577 and the analogue M.22B.2 in CN102126994. Phthalamides M.28.1 and M.28.2 are known from WO 2007/101540. The anthranilamide M.28.3 has been described in WO2005 / 077934. The hydrazide compound M.28.4 has been described in WO 2007/043677. The anthranilamides M.28.5a) to M.28.5h) can be prepared as described in WO 2007/006670, WO2013 / 024009 and WO2013 / 024010, the anthranilamide compound M.28.5i) is described in WO2011 / 085575, compound M.28.5j) in WO2008 / 134969, compound M.28.5k) in US2011 / 046186 and compound M.28.5l) in WO2012 / 034403. The diamide compounds M.28.6 and M.28.7 can be found in CN102613183. The anthranilamide compounds M.28.8a) and M.28.8b) are known from WO2010 / 069502.

The quinoline derivative flometoquin is shown in WO2006 / 013896. Aminofuranone flupiradifurone compounds are known from WO 2007/115644. The sulfoximin sulfoxaflor compound is known from WO2007 / 149134. From the pyrethroid group, momfluorotrin is known from US6908945 and heptaflutrin from WO10133098. The oxadiazolone methoxadiazone compound can be found in JP13 / 166707. Pyrophilic pyrazole acaricide is known from WO2007 / 020986. The isoxazoline compounds have been described in the following publications: fluralaner in WO2005 / 085216, afoxolaner in WO2009 / 002809 and in WO2011 / 149749 and the isoxazoline compound M.UN.9 in WO2013 / 050317. The afidopiropen derived from pyripropylene has been described in WO 2006/129714. The nematicide thioxazaphene has been disclosed in WO09023721 and nematicide fluopiram in WO2008126922, nematicidal mixtures comprising flupiram in WO2010108616. The triflumezopyrim compound was described in WO2012 / 092115.

The spirochetal cyclic ketoenol derivative M.UN.3 is known from WO2006 / 089633 and the biphenyl spirocyclic ketoenol derivative M.UN.4 of WO2008 / 067911. The triazoiylphenylsulfide M.UN.5 has been described in WO2006 / 043635, and the biological control agents on the basis of bacillus firmus in WO2009 / 124707.

Compounds M.UN.6a) to M.UN.6i) listed in M.UN.6 have been described in WO2012 / 029672 and compounds M.UN.6j) and M.UN.6k) in the document WO2013129688. The nematicidal compound M.UN.8 in WO2013 / 055584 and the pyridalyl analogue M.UN.10 in WO2010 / 060379. Carboxamide compounds M.UN.11.b) to M.UN.11.h) can be prepared as described in WO 2010/018714 and carboxamide M.UN.11i) to M.UN.11. p) WO2010 / 127926 are described. Pyridylthiazoles M.UN.12.a) to M.UN.12.c) are known from WO2010 / 006713, M.UN.12.c) and M.UN.12.d) WO2012000896 and M.UN .12 .f) to M.UN.12.m) in WO2010129497. The malononitrile compound M.UN.13 was described in WO2009 / 005110. Compounds M.UN.14a) and M.UN.14b) are known from WO2007 / 101369. The compound M.UN.15 can be found in WO13192035.

The biopesticides of the M.Y. they are disclosed later in the paragraphs on biopesticides (from groups M.Y and F.XII).

The following list F of active fungicidal substances, together with which the combinations according to the invention can also be used, is intended to illustrate the possible combinations but does not limit them:

F.I) Breathing inhibitors

FI 1) Complex III inhibitors at the Qo site (for example strobilurin): azoxyetrobin, coumethoxystrobin, coumoxystrobin, dimoxystrobin, enestroburin, phenaminostrobin, phenoxystrobin / fluphenoxystrobin, fluoxaestrobin, kresoxim-methyl, mandestrobin, methinostrobin, orisaestrobin, picoxystrobin, pyraclostrobin, pyrometostrobin, pyrooxystrobin, trifloxystrobin and 2- (2- (3- (2,6-dichlorophenyl) -1-methyl-allylideneaminooxomethyl) -phenyl methoxyimino-N-methyl-acetamide, pyribencarb, triclopyricarb / chlorodincarb, famoxadone, fenamidone;

FI 2) Complex III inhibitors at the Qi site: ciazofamid, amisulbrom, [(3S, 6S, 7R, 8R) -8-benzyl-3 - [(3-acetoxy-4-methoxy-pyridin-2-carbonyl) amino ] -6-methyl-4,9-dioxo-1,5-dioxonan-7-yl] 2-methylpropanoate, [(3S, 6S, 7R, 8R) -8-benzyl-3 - [[3- (acetoxymethoxy) -4-methoxy-pyridin-2-carbonyl] amino] -6-methyl-4,9-dioxo-1,5-dioxonan-7-yl] 2-methylpropanoate, [(3S, 6S, 7R, 8R) -8 -benzyl-3 - [(3-isobutoxycarbonyloxy-4-methoxy-pyridin-2-carbonyl) amino] -6-methyl-4,9-dioxo-1,5-dioxonan-7-yl] 2-methylpropanoate, [( 3S, 6S, 7R, 8R) -8-benzyl-3 - [[3- (1,3-benzodioxol-5-ylmethoxy) -4-methoxy-pyridin-2-carbonyl] amino] -6-methyl-4, 9-dioxo-1,5-dioxonan-7-yl] 2-methylpropanoate; (3S, 6S, 7R, 8R) -3 - [[(3-hydroxy-4-methoxy-2-pyridinyl) carbonyl] amino] -6-methyl-4,9-dioxo-8- (phenylmethyl) -1, 5-dioxonan-7-yl 2-methylpropanoate

FI 3) Complex II inhibitors (for example carboxamide): benodanil, benzovindiflupir, bixafen, boscalid, carboxin, fenfuram, fluopiram, flutolanil, fluxapiroxad, furametpir, isofetamid, iso-pirazam, mepronil, oxicarboxin, penfluphenfen, penflufen, pefluphenphen, pefluphenfen , tifluzamide, N- (4'-trifluoromethylthiobiphenyl-2-yl) -3-difluoromethyl-1-methyl-1 H-pyrazol-4-carboxamide, N- (2- (1, 3,3-trimethyl-butyl) - phenyl) -1,3-dimethyl-5-fluoro-1H-pyrazol-4-carboxamide, 3- (difluoromethyl) -1-methyl-N- (1,1,3-trimethylindan-4-yl) pyrazol-4- carboxamide, 3- (trifluoromethyl) -1-methyl-N- (1,1,3-trimethylindan-4-yl) pyrazol-4-carboxamide, 1,3-dimethyl-N- (1,1,3-trimethylindan- 4-yl) pyrazol-4-carboxamide, 3- (trifluoromethyl) -1,5-dimethyl-N- (1,1,3-trimethylindan-4-yl) pyrazol-4-carboxamide, 1,3,5-trimethyl -N- (1,1,3-trimethylindan-4-yl) pyrazol-4-carboxamide, N- (7-fluoro-1,1,3-trimethyl-indan-4-yl) -1,3-dimethyl- pyrazol-4-carboxamide, N- [2- (2,4-dichlorophenyl) -2-methoxy-1-methyl-ethyl] -3- (difluoromethyl) -1-methylpyrazol-4-carboxamide, N- [2- ( 2,4-difluorophenyl) phenyl] -3- (trifluoromethyl) pyrazin-2-carboxamide; FI 4) other respiration inhibitors (for example, complex I, decouplers): diflumetorim, (5,8-difluoroquinazolin-4-yl) - {2- [2-fluoro-4- (4-trifluoromethylpyridin-2-yloxy ) -phenyl] -ethyl} -amine; nitrophenyl derivatives: binapacril, dinobuton, dinocap, fluazinam; ferimzone; organometallic compounds: phentine salts, such as phentine acetate, phentine chloride or phentine hydroxide; ametoctradine; and siltiofam; F.II) Sterile biosynthesis inhibitors (SBI fungicides)

F.II 1) C14 demethylase inhibitors (DMI fungicides): triazoles: azaconazole, bitertanol, bromuconazole, ciproconazole, diphenoconazole, diniconazole, diniconazole-M, epoxiconazole, fenbuconazole, fluquinconazole, flusilazole, flutriafol, hexaconazole, imconazole, imconaconazole, imconazole, ipconazole , miclobutanil, oxpoconazole, paclobutrazol, penconazole, propiconazole, protioconazole, simeconazole, tebuconazole, tetraconazole, triadimephon, triadimenol, triticonazole, uniconazole, 1- [re / - (2S; 3R) -3- (2-chlorophenyl) -2- ( 2,4-Difluorophenyl) -oxyranylmethyl] -5-thiocyanate-1H- [1,2,4] triazole, 2- [re / - (2S; 3R) -3- (2-chlorophenyl) -2- (2, 4-difluorophenyl) -oxyranylmethyl] -2H- [1,2,4] triazol-3-thiol, 2- [2-chloro-4- (4-chlorophenoxy) phenyl] -1- (1,2,4-triazole -1-yl) pentan-2-ol, 1- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1-cyclopropyl-2- (1,2,4-triazol-1-yl) ethanol , 2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1,2,4-triazol-1-yl) butan-2-ol, 2- [2-chloro-4- (4-chlorophenoxy) phenyl] -1- (1,2,4-triazol-1-yl) butan-2-ol, 2- [4- (4-chlorophenoxy) -2- (trifluorome til) phenyl] -3-methyl-1- (1,2,4-triazol-1-yl) butan-2-ol, 2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1 - (1,2,4-triazol-1-yl) propan-2-ol, 2- [2-chloro-4- (4-chlorophenoxy) phenyl] -3-methyl-1- (1,2,4- triazol-1-yl) butan-2-ol, 2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1,2,4-triazol-1-yl) pentan-2- ol, 2- [4- (4-fluorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1,2,4-triazol-1-yl) propan-2-ol; imidazoles: imazalil, pefurazoate, prochloraz, triflumizol; pyrimidines, pyridines and piperazines: fenarimol, nuarimol, pyrifenox, triforin, [3- (4-chloro-2-fluoro-phenyl) -5- (2,4-difluorophenyl) isoxazol-4-yl] - (3-pyridyl) methanol; F.II 2) Delta 14-reductase inhibitors: aldimorf, dodemorf, dodemorfate, fenpropimorf, tridemorf, fenpropidine, piperaline, spiroxamine;

F.II 3) Inhibitors of 3-keto reductase: fenhexamid;

F.III) Inhibitors of nucleic acid synthesis

F.III 1) acyl amino acid phenylamides or fungicides: benalaxil, benalaxil-M, kiralaxil, metalaxyl, metalaxyl-M (mefenoxam), ofurace, oxadixil;

F.III 2) other: himexazol, octylinone, oxolinic acid, bupirimate, 5-fluorocytosine, 5-fluoro-2- (p-tolylmethoxy) pyrimidin-4-amine, 5-fluoro-2- (4-fluorophenylmethoxy) pyrimidin 4 -amine;

F.IV) Inhibitors of cell division and cytoskeleton.

F.IV 1) tubulin inhibitors, such as benzimidazoles, thiophanates: benomyl, carbendazim, fuber-idazol, thiabendazole, thiophanate-methyl; triazolopyrimidines: 5-chloro-7- (4-methylpiperidin-1-yl) -6- (2,4,6-trifluorophenyl) - [1,2,4] triazolo [1,5-a] pyrimidine

F.IV 2) other cell division inhibitors: dietofencarb, ethaboxam, pencicuron, fluopicolide, zoxamide, metrafenone, pyrophenone;

F.V) Inhibitors of amino acid and protein synthesis.

F.V 1) inhibitors of the synthesis of methionine (anilino-pyrimidines): cyprodinyl, mepanipirim, pyrimethanil;

F.V 2) protein synthesis inhibitors: blasticidine-S, kasugamycin, kasugamycin-hydrochloride hydrochloride, mildiomycin, streptomycin, oxytetracycline, polyoxin, validamycin A;

F.VI) Signal transduction inhibitors.

F.VI 1) MAP / histidine kinase inhibitors: fluoroimid, iprodione, procimidone, vinclozolin, fenpiclonil, fludioxonil; F.VI2) Protein G inhibitors: quinoxifene;

F.VII) Inhibitors of lipid and membrane synthesis.

F.VII 1) Phospholipid biosynthesis inhibitors: ediphenphos, iprobenfos, pyrazophos, isoprotiolane;

F.VII 2) lipid peroxidation: dichloro, fifth-zen, technazene, tolclofos-methyl, biphenyl, chloroneb, etridiazole;

F.VII 3) phospholipid biosynthesis and cell wall deposition: dimetomorf, flumorph, mandipropamid, pyrimorph, bentiavalicarb, iprovalicarb, valifenalate and (4-fluorophenyl) N- (1- (1- (1- (4 (4 (fluoride)) -cyano-phenyl) -ethanesulfonyl) -but-2-yl) carbamic;

F.VII 4) Compounds that affect the permeability of the cell membrane and fatty acids: propamocarb, propamocarb hydrochloride

F.VII 5) fatty acid amide hydrolase inhibitors: oxathiapiproline;

F.VIII) Inhibitors with multisite action

F.VIII 1) inorganic active substances: Bordeaux mixture, copper acetate, copper hydroxide, copper oxychloride, basic copper sulfate, sulfur;

F.VIII 2) uncle and dithiocarbamates: ferbam, mancozeb, maneb, metam, metiram, propineb, thiram, zineb, ziram;

F.VIII 3) Organochlorine compounds (for example, phthalimides, sulfonamides, chloronitriles): anilazine, chlorothalonil, captafol, captan, folpet, dichlorofluanide, dichlorophen, hexachlorobenzene, pentachlorophenol and its salts, phthalamide, tolylfluoride, N- (4-) nitro-phenyl) -N-ethyl-4-methyl-benzenesulfonamide;

F. VIII 4) guanidines and others: guanidine, dodine, dodine-free base, guazatine, guazatine-acetate, iminoctadine, iminoctadine triacetate, iminoctadine-tris (albesilate), dithianon, 2,6-dimethyl-1H, 5H- [1 , 4] dithiino [2,3-c: 5,6-c '] dipyrrol-1,3,5,7 (2H, 6H) -tetraone;

F.IX) Inhibitors of cell wall synthesis.

F.IX 1) Glucan synthesis inhibitors: validamycin, polyoxin B;

F.IX 2) Melanin synthesis inhibitors: piroquilon, triciclazole, carpropamid, dicyclomet, phenoxyanil;

F.X) Plant defense inductors.

F.X 1) acibenzolar-S-methyl, probenazole, isothianyl, thiadinyl, prohexadione-calcium;

F.X2) phosphonates: phosphoryl, fosetyl aluminum, phosphorous acid and its salts, 4-cyclopropyl-N- (2,4-dimethoxyphenyl) thiadiazol-5-carboxamide;

F.XI) Unknown mode of action

bronopol, chinomethionat, cyflufenamid, cymoxanil, dazomet, debacarb, diclomezine, difenzoquat, difenzoquatmetilsulfato, difenilamin, fenpyrazamine, flumetover, flusulfamide, flutianil, methasulfocarb, nitrapyrin, nitrothal-isopropyl, oxatiapiprolin, picarbutrazox, tolprocarb, 2- [3,5-bis (difl uoromethyl) -1 H-pyrazol-1-yl] -1- [4- (4- {5- [2- (prop-2-in-1-yloxy) phenyl] -4,5-dihydro-1 , 2-oxazol-3-yl} -1, 3-thiazol-2-yl) piperidin-1-yl] ethanone, 2- [3,5-bis (difluoromethyl) -1 H-pyrazol-1-yl] - 1- [4- (4- {5- [2-Fluoro-6- (prop-2-in-1-yloxy) phenyl] -4,5-dihydro-1,2-oxazol-3-yl} -1 , 3-thiazol-2-yl) piperidin-1-yl] ethanone, 2- [3,5-bis (difluoromethyl) -1H-pi razol-1-yl] -1- [4- (4- {5- [2-Chloro-6- (prop-2-in-1-yloxy) phenyl] -4,5-dihydro-1,2-oxazol-3-yl} -1,3-thiazol-2-yl) piperidin- 1-yl] ethanone, oxin-copper, proquinazid, tebufloquin, tecloftalam, triazoxide, 2-butoxy-6-iodo-3-propylchromen-4-one, N- (cyclopropylmethoxyimino- (6-difluoro-methoxy-2,3- difluoro-phenyl) -methyl) -2-phenyl acetamide, N '- (4- (4-chloro-3-trifluoromethyl-phenoxy) -2,5-dimethyl -phenyl) -N-ethyl-N-methyl formamidine, N '- (4- (4-fluoro-3-trifluoromethyl-phenoxy) -2,5-dimethyl phenyl) -N-ethyl-N-methyl formamidine, N' - (2-methyl-5-trifluoromethyl-4- ( 3-Trimethylsilanyl-propoxy) -phenyl) -N-ethyl-N-methyl formamidine, N '- (5-difluoromethyl-2-methyl-4- (3-trimethylsilanyl-propoxy) -phenyl) -N-ethyl-N- methyl formamidine, 6-tert-butyl-8-fluoro-2,3-dimethyl-quinolin-4-yl ester of methoxy-acetic acid, 3- [5- (4-methylphenyl) -2,3-dimethyl-isoxazolidin- 3-yl] -pyridin, 3- [5- (4-chloro-phenyl) -2,3-dimethyl-isoxazolidin-3-yl] -pyridin (pyrisoxazole), N- (6-methoxy-pyridin-) acid amide 3-yl) cyclopropanecarboxylic, 5-chloro-1- (4,6-dimethoxy-pyrimidin-2-yl) -2-methyl-1 H -benzoimidazole, 2- (4-chloro-phenyl) -N- [4- ( 3,4-dimethoxy-phenyl) -isoxazol-5-yl] -2-prop-2-inyloxy-acetamide, (Z) -3-amino-2-cyano-3-phenyl-prop-2-enoate, N- [6 - [[(Z) - [(1-methyltetrazol-5-yl) -phenyl-methylene] amino] oxymethyl] -2-pyridyl] pentyl carbamate, 2- [2 - [(7,8- difluoro-2-methyl-3-quinolyl) oxy] -6-fluoro-phenyl] propan-2-ol, 2- [2-fluoro-6 - [(8-fluoro-2-methyl-3-quinolyl) oxy] phenyl] propan-2-ol, 3- (5-Fluoro-3,3,4,4-tetramethyl-3,4-dihydroisoquinolin-1-yl) quinoline, 3- (4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinolin- 1-yl) quinoline, 3- (4,4,5-trifluoro-3,3-dimethyl-3,4-dihydroisoquinolin-1-yl) quinoline;

F.XII) Biopesticides

F.XII 1) Microbial pesticides with fungal, bactericidal, viricidal and / or plant defense activating activity: Ampelomyces quisqualis, A mpelomyces quisqualis, Aspergillus flavus, Aureobasidium pullulans, Bacillus amyloliquefaciens, B. mojavensis, B. pumilus, B. pumilus, B. simplex, B. pumilus, B. simplex B. solisalsi, B. subtilis, B. subtilis var. amyloliquefaciens, Candida oleophila, C. saitoana, Clavibacter michiganensis (bacteriophages), Coniothyrium minitans, Cryphonectria parasitica, Cryptococcus albidus, Dilophosphora alopecuri, Fusarium oxisporum, Clonostachys rosea f. catenulate (also known as Gliocladium catenulatum), Gliocladium roseum, Lysobacter antibioticus, L. enzymogenes, Metschnikowia fructicola, Microdochium dimerum, Microsphaeropsis ochracea, Muscodor albus, Paenibacillus polymyxa, Pantoea vagans, Phlebiopsis floramaonasa, Pseudomosacomasaus pseudoamase, Pseudomosacomasaus pseudoamase, Pseudomosacomasaus, Pseudomosacomasaus pseudoamase. Anomala, Pythium oligandrum, Sphaerodes mycoparasitica, Streptomyces griseoviridis, S. lydicus, S. violaceusniger, Talaromyces flavus, Trichoderma asperellum, T. atroviride, T. fertile, T. gamsii, T. harmatum, T. harzianum; mixture of T. harzianum and T. viride; mixture of T. polysporum and T. harzianum; T. stromaticum, T. virens (also called Gliocladium virens), T. viride, Typhula phacorrhiza, Ulocladium oudemansii, Verticillium dahlia, zucchini yellow mosaic virus (avirulent strain);

F.XII 2) Biochemical pesticides with fungal, bactericidal, viricidal and / or plant defense activating activity: chitosan (hydrolyzed), harpin protein, laminarin, Menhaden fish oil, natamycin, plum pox virus layer protein , potassium or sodium bicarbonate, Reinoutria sachlinensis extract, salicylic acid, tea tree oil;

The combination of the carboxamide compound of formula (I) with fluxopirroxad, epoxiconazole or triticonazole is preferred.

Also highly preferred is the combination of the carboxamide compound of formula (I) with Fluxapiroxad.

Also highly preferred is the combination of the carboxamide compound of formula (I) with epoxiconazole.

Also highly preferred is the combination of the carboxamide compound of formula (I) with triticonazole. Chemical fungicidal pesticides described by common names, their preparation and their activity against pests are known (cf .: http: //www.alanwood.net/pesticidas/); These pesticides are often commercially available. The fungicidal pesticides described by the IUPAC nomenclature, their preparation and their pesticidal activity are also known (cf. Can. J. Plant Sci. 48 (6), 5587-94, 1968; EP-A 141 317; EP-A 152031; EP-A 226 917; EP-A 243970; EP-A 256503; EP-A 428941; EP-A 532022; EP-A 1028 125; EP-A 1035 122; EP-A 1201 648; EP-A 1122244, JP 2002316902; DE 19650197; DE 10021412; DE 102005009458; US 3,296,272; US 3,325,503; WO 98/46608; WO 99/14187; WO 99/24413; WO 99/27783; WO 00/29404; WO 00/46148; WO 00 / 65913; WO 01/54501; WO 01/56358; WO 02/22583; WO 02/40431; WO 03/10149; WO 03/11853; WO 03/14103; WO 03/16286; WO 03/53145; WO 03 / 61388; WO 03/66609; WO 03/74491; WO 04/49804; WO 04/83193; WO 05/120234; WO 05/123689; WO 05/123690; WO 05/63721; WO 05/87772; WO 05 / 87773; WO 06/15866; WO 06/87325; WO 06/87343; WO 07/82098; WO 07/90624, WO 11/028657, WO2012 / 168188, WO 2007/006670, WO 11/77514; WO13 / 047749, WO 10/069882, WO 13/047441, WO 03/16303, WO 09/90181, WO 13/007767, WO 13/010862, WO 13/024009 and WO 1 2/34010).

Biopesticides

The biopesticides of group II.MY or F.XII, their preparation and their pesticidal activity for example against harmful fungi or insects are known (e-Pesticide Manual V 5.2 (ISBN 978 1 901396 85 0) (2008-2011); http: //www.epa.gov/opp00001/biopesticides/, see product lists in it; http://www.omri.org/omri-lists, see lists in it; BPDB biopesticide databases http : //sitem.herts.ac.uk/aeru/bpdb/, see link A to Z in it) .The biopesticides of group II.MY or F.XII. It can also have insecticidal, fungicidal, acaricidal, molluscicidal, viricidal, bactericidal, pheromone, nematicidal activity, plant defense activator, plant stress reducer, plant growth regulator, plant growth promoter, plant growth regulator and / or performance increase. Many of these biopesticides are registered and / or are commercially available: aluminum silicate (Screen ™ Duo from Certis LLC, USA), Agrobacterium radio-bacter K1026 (e.g. NoGall® from Becker Underwood Pty Ltd., Australia), A. radiobacter K84 (Nature 280. 697- 699, 1979; for example GallTroll® from AG Biochem, Inc., C, USA), Ampelomyces quisqualis M-10 (for example AQ 10® from Intrachem Bio GmbH & Co. KG, Germany), Ascophyllum nodosum (Norwegian kelp, Brown kelp) extract or filtrate (e.g. ORKA GOLD from Becker Underwood, South Africa; or Goemar® from Laboratoires Goemar, France), Aspergillus flavus NRRL 21882 isolated from a peanut in Georgia in 1991 by the USDA, National Peanut Research Laboratory (for example, in Afla-Guard® of Singenta, CH), mixtures of Aureobasidium pullulans DSM14940 and DSM 14941 (for example blastoespores in BlossomProtect® from bio-ferm GmbH, Germany), Azospirillum Brazilian XOH (for example AZOS from Xtreme Gardening, EE .UU. Or RTI Reforestation Technologies International; USA), Bacillus amyloliquef aciens FZB42 (for example in RhizoVital® 42 from AbiTEP GmbH, Berlin, Germany), B. amyloliquefaciens IN937a (J. Microbiol Biotechnol 17 (2), 280-286, 2007; for example in BioYield® of Gustafson LLC, TX, USA), B. amyloliquefaciens IT-45 (CNCM I-3800) (for example Rhizocell C of ITHEC, France), B. amyloliquefaciens subsp. MBI600 plantarum (NRRL B-50595, deposited with the United States Department of Agriculture) (for example Integral®, Subtilex® NG from Becker Underwood, USA), B. cereus CNCM I-1562 (US 6,406,690), B. firmus CNCM I-1582 (WO 2009/126473, WO 2009/124707, US 6,406,690; Votivo® of Bayer Crop Science LP, USA), B. pumilus GB34 (ATCC 700814; for example in Gustafson's YieldShield® LLC, TX, USA), and Bacillus pumilus KFP9F (NRRL B-50754) (for example in BAC-UP or FUSION-P of Becker Underwood South Africa), B. pumilus QST 2808 (NRRL B-30087) ( for example Sonata® and Ballad® Plus from AgraQuest Inc., USA), B. subtilis GB03 (for example Kodiak® or BioYield® from Gustafson, Inc., USA; or Companion® from Growth Products, Ltd ., White Plains, NY 10603, USA), B. subtilis GB07 (Epic® of Gustafson, Inc., USA), B. subtilis QST-713 (NRRL B-21661 in Rhapsody®, Serenade® MAX and Serenade® ASO from AgraQuest Inc., USA), B. subtilis var. amylolique-faciens FZB24 (for example Taegro® from Novozyme Biologicals, Inc., USA), B. subtilis var. amyloliquefaciens D747 (for example Double Nickel 55 of Certis LLC, USA), B. thuringiensis ssp. aizawai ABTS-1857 (for example in Xen-Tari® from BioFa AG, Münsingen, Germany), B. t. ssp. aizawai SAN 401 I, ABG-6305 and ABG-6346, Bacillus t. ssp. israelensis AM65-52 (for example in VectoBac® from Valent BioSciences, IL, USA), Bacillus thuringiensis ssp. Kurstaki SB4 (NRRL B-50753; for example Beta Pro® from Becker Underwood, South Africa), B. t. ssp. kurstaki ABTS-351 identical to HD-1 (ATCC SD-1275; for example in Dipel® DF from Valent BioSciences, IL, USA), B. t. ssp. Kurstaki EG 2348 (for example in Lepinox® or Rapax® from CBC (Europe) Srl, Italy), B. t. ssp. tenebrionis DSM 2803 (EP 0585215 B1; identical to NRRL B-15939; Mycogen Corp.), B. t. ssp. tenebrionis NB-125 (DSM 5526; EP 0585215 B1; also known as SAN 418 I or ABG-6479; previous production strain of Novo-Nordisk), B. t. ssp. tenebrionis NB-176 (or NB-176-1) a high performance gamma irrigation strain mutant NB-125 (DSM 5480; EP 585215 B1; Novodor® from Valent BioSciences, Switzerland), Beauveria bassiana ATCC 74040 (for example in Naturalis® of CBC (Europe) Srl, Italy), B. bassiana DSM 12256 (US 200020031495; for example BioExpert® SC of Live Sytems Technology SA, Colombia), B. bassiana GHA (BotaniGard® 22WGP of Laverlam Int. Corp ., USA), B. bassiana PPRI 5339 (ARSEF number 5339 in the USDAARS collection of entomopathogenic fungal cultures; NRRL 50757) (for example BroadBand® from Becker Underwood, South Africa), B. brongniartii (for example in Melocont ® from Agrifutur, Agrianello, Italy, for bumblebee control; J. Appl. Microbiol. 100 (5), 1063-72, 2006), Bradyrhizobium sp. (e.g. Vault® from Becker Underwood, USA), B. japonicum (e.g. VAULT® from Becker Underwood, USA), Candida oleophila I-182 (NRRL Y-18846; for example Aspire® from Ecogen Inc., USA, Phytoparasitica 23 (3), 231-234, 1995), C. oleophila strain O (NRRL Y-2317; Biological Control 51, 403-408, 2009) ,, Candida saitoana (e.g. Biocure ® (in mixture with lysozyme) and BioCoat® from Micro Flo Company, USA (BASF SE) and Arysta), Chitosan (for example Armor-Zen® from BotriZen Ltd., NZ), Clonostachys rosea f. Catenulata, also called Gliocladium catenulatum (for example isolated J 1446: Prestop® from Verdera Oy, Finland), Chromobacterium subtsugae PRAA4-1 isolated from soil under an eastern spruce (Tsuga canadensis) in the Catoctin mountain region of central Maryland ( for example in GRANDE-VO of Marrone Bio Innovations, USA), Coniothyrium minitans CON / M / 91-08 (for example Contans® WG of Prophyta, Germany), Cryphonectria parasitica (for example, CNICM parasitic endotia, France) , Cryptococcus albidus (for example YIELD PLUS® of Anchor Bio-Technologies, South Africa), Cryptophlebia leucotreta granulovirus (CrleGV) (for example in CRYPTEX of Adermatt Biocontrol, Switzerland), Cydia pomonella granulovirus (CpGV) V03 (DSM GV 0006; for example in MADEX Max of Andermatt Biocontrol, Switzerland), CpGV V22 (DSM GV-0014; for example in MADEX Twin of Adermatt Biocontrol, Switzerland), Delftia acidovorans RAY209 (ATCC PTA-4249; WO 2003/57861; for example in BIOBOOST by Brett Young, Winnipeg, Canada ), Dilophosphora alopecuri (Becker Underwood Twist Fungus, Australia), Ecklonia maxima extract (kelp) (for example KEL-PAK SL of Kelp Products Ltd, South Africa), formononetin (for example in MYCONATE from Plant Health Care plc, Kingdom United), Fusarium oxisporum (e.g. BIOFOX® from SIAPA, Italy, FEE.UU.C-LEAN® from Natural Plant Protection, France), Glomus intraradices (e.g. MYC 4000 from ITHEC, France), Glomus intraradices RTI-801 ( for example MYKOS from Xtreme Gardening, USA. or RTI Reforestation Technologies International; USA), grapefruit seeds and pulp extract (for example BC-1000 from Chemie SA, Chile), harpin protein (alpha-beta) (for example MESSENGER or HARP-N-Tek from Plant Health Care plc, Kingdom United; Science 257, 1-132, 1992), Heterorhabditis bacteriophaga (e.g. Nemasys® G from Becker Underwood Ltd., United Kingdom), Isaria fumosorosea Apopka-97 (ATCC 20874) (PFR-97 ™ from Certis LLC, USA. UU.), Cis-jasmone (US 8,221,736), laminarin (for example in VAC-CIPLANT of Laboratoires Goemar, St. Malo, France or Stahler SA, Switzerland), Lecanicillium longisporum KV42 and KV71 (for example VERTALEC® of Koppert BV, The Netherlands), L. muscarium KV01 (formerly Verticillium lecanii) (for example MYCOTAL from Koppert BV, The Netherlands), Lysobacter antibioticus 13-1 (Biological Control 45, 288-296, 2008), L. antibioticus HS124 (Curr. Microbiol .59 (6), 608 615, 2009), L. enzymogenes 3.1T8 (Microbiol. Res. 158, 107-115; Biological Control 31 (2), 145-154, 2004), Metarhizium anisopliae var. acridum IMI 330189 (isolated from Ornithacris cavroisi in Nigeria; also NRRL 50758) (for example GREEN MUSCLE® from Becker Underwood, South Africa), M. a. var. acridum FI-985 (e.g. GREEN GUARD® SC from Becker Underwood Pty Ltd, Australia), M. anisopliae FI-1045 (e.g. BIOCANE® from Becker Underwood Pty Ltd, Australia), M. anisopliae F52 (DSM 3884, ATCC 90448 ; for example MET52® Novozymes Biologicals BioAg Group, Canada), M. anisopliae ICIPE 69 (for example METATHRIPOL from ICIPE, Nairobi, Kenya), Metschnikowia fructicola (NRRL Y-30752; for example SHEMER® from Agrogreen, Israel, now distributed by Bayer CropSciences, Germany; US 6,994,849), Microdochium dimerum (for example AN-TIBOT® from Agrauxine, France), Microsphaeropsis ochracea P130A (ATCC 74412 isolated from apple leaves of an abandoned orchard, St-Josephdu-Lac, Quebec, Canada in 1993; Mycologia 94 (2), 297-301, 2002), Muscodor albus QST 20799 originally isolated from the bark of a cinnamon tree in Honduras (for example in Muscudor ™ or QRD300 development products from AgraQuest, USA) , Neem oil (e.g. TRILOGY®, TRIACT® 70 EC from Certis LLC, USA), c epas of Nomuraea rileyi SA86101, GU87401, SR86151, CG128 and VA9101, Paecilomyces fumosoroseus FE 9901 (for example NO FLY ™ from Natural Industries, Inc., USA), P. lilacinus 251 (for example in BioAct® / MeloCon® from Prophyta, Germany; Crop Protection 27, 352-361,2008; originally isolated from infected nematode eggs in the Philippines), P. lilacinus DSM 15169 (for example NEMATA® SC from Live Systems Technology SA, Colombia), P. lilacinus BCP2 (NRRL 50756; for example PL GOLD from Becker Underwood BioAg SA Ltd, South Africa), mixture of Paenibacillus alvei NAS6G6 (NRRL B-50755), Pantoea vagans (formerly agglomerans) C9-1 (originally isolated in 1994 from apple stem tissue; BlightBan C9-1® from NuFrams America Inc., USA. UU., For the control of fire blight in apples; J. Bacteriol. 192 (24) 6486-6487, 2010), Pasteuria spp. ATCC PTA-9643 (WO 2010/085795), Pasteuria spp. ATCC SD-5832 (WO 2012/064527), P. nishizawae (WO 2010/80169), P. penetrans (US 5,248,500), P. ramose (WO 2010/80619), P. thornea (WO 2010/80169), P . usgae (WO 2010/80169), Penicillium bilaiae (for example Jump Start® from Novozymes Biologicals BioAg Group, Canada, originally isolated from soil in southern Alberta; Fertilizer Res. 39, 97-103, 1994), Phlebiopsis gigantea ( for example RotStop® from Verdera Oy, Finland), Pichia anomala WRL-076 (NRRL Y-30842; US 8,206,972), potassium bicarbonate (for example Amicarb® fromm Stahler SA, Switzerland), potassium silicate (for example Sil-MATRIX ™ from Certis LLC, USA), Pseudozyma flocculosa PF-A22 UL (for example Sporodex® from Plant Products Co. Ltd., Canada), Pseudomonas sp. DSM 13134 (WO 2001/40441, for example in PRORADIX of Sourcon Padena GmbH & Co. KG, Hechinger Str. 262, 72072 Tübingen, Germany), P. chloraphis MA 342 (for example in CERALL or CEDEMON of BioAgri AB, Uppsala, Sweden), P. fluorescens CL 145A (for example in ZEQUANOX from Marrone Biolnnovations, Davis, CA, USA; J. Invertebr. Pathol. 113 (1): 104-14, 2013), Pythium oligandrum DV 74 (ATCC 38472; for example POLYVERSUM® by Remeslo SSRO, Biopreparaty, Czech Rep. And GOWAN, USA; US 2013/0035230), Reinoutria sachlinensis extract (for example REGALIA® SC from Marrone Biolnnovations, Davis, CA, USA) .), Rhizobium leguminosarum bv. phaseolii (for example RHIZO-STICK from Becker Underwood, USA), RI trifolii RP113-7 (for example DORMAL from Becker Underwood, USA; Appl. Environ. Microbiol. 44 (5), 1096-1101) , RI bv. viciae P1NP3Cst (also known as 1435; New Phytol 179 (1), 224-235, 2008; for example in NODULATOR PL Peat Granule of Becker Underwood, USA; or in NODULATOR XL PL b of Becker Underwood, Canada), RI bv. Viciae SU303 (for example NODULAID Group E from Becker Underwood, Australia), RI bv. viciae WSM1455 (for example NODULAID Group F of Becker Underwood, Australia), R. tropici SEMIA 4080 (identical to PRF 81; Soil Biology & Biochemistry 39, 867-876, 2007), Sinorhizobium meliloti MSDJ0848 (INRA, France) also known as strain 2011 or RCR2011 (Mol Gen Genomics (2004) 272: 1-17; for example DORMAL ALFALFA from Becker Underwood, USA; NITRAGIN® Gold from Novozymes Biologicals BioAg Group, Canada), Sphaerodes mycoparasitica IDAC 301008-01 (WO 2011/022809), Steinernema carpocapsae (eg MILLENIUM® from Becker Underwood Ltd., United Kingdom), S. feltiae (NEMASHIELD® from BioWorks, Inc., USA; NEMASYS® from Becker Underwood Ltd., United Kingdom) , S. kraussei L137 (NEMASYS® L from Becker Underwood Ltd., United Kingdom), Streptomyces griseoviridis K61 (for example MY-COSTOP® from Verdera Oy, Espoo, Finland; Crop Protection 25, 468-475, 2006), S. lydicus WYEC 108 (for example Actinovate® from Natural Industries, Inc., USA, US 5,403,584), S. violaceusniger YCED-9 (for example DT- 9® from Natural Industries, Inc., USA, US 5,968,503), Talaromyces flavus V117b (e.g. PROTUS® from Prophyta, Germany), Trichoderma asperellum SKT-1 (e.g. ECO-HOPE® from Kumiai Chemical Industry Co. , Ltd., Japan), T. asperellum ICC 012 (for example in TENET WP, REMDIER WP, BIOTEN WP from Isagro NC, USA, BIO-TAM from AgraQuest, USA), T. atroviride LC52 ( for example SENTINEL® from Agrimm Technologies Ltd, NZ), T. atroviride CNCM I-1237 (for example in Esquive WG de Agrauxine SA, France, for example against diseases caused by pruning wounds in vine pathogens and plant roots), T. fertile JM41R (NRRL 50759; for example RICHPLUS ™ from Becker Underwood Bio Ag SA Ltd, South Africa), T. gamsii ICC 080 (for example in TENET WP, REMDIER WP, BIOTEN WP from Isagro NC, USA, BIO-TAM from AgraQuest, USA. UU.), T. harzianum T-22 (for example PLANTSHIELD® from Firma BioWorks Inc., USA), T. harzianum TH 35 (for example ROOT PRO® from Mycontrol Ltd., Israel), T. harzianum T -39 (for example TRICHODEX® and TRICHODERMA 2000® from Mycontrol Ltd., Israel and Makhteshim Ltd., Israel), T. harzianum and T. viride (for example TRICHOPEL from Agrimm Technologies Ltd, NZ), T. harzianum ICC012 and T ICC080 viride (for example REMEDIER® WP from Isagro Ricerca, Italy), T. polysporum and T. harzianum (for example BINAB® from BINAB Bio-Innovation AB, Sweden), T. stromaticum (for example TRICOVAB® from CEPLAC, Brazil), T. virens GL-21 (also called Gliocladium virens) (for example SOILGARD® from Certis LLC, USA), T. viride (for example TRIECO® by Ecosense Labs. (India) Pvt. Ltd., Indien, BIO-CURE® F by T. Stanes & Co. Ltd., India), T. viride TV1 (eg T. viride TV1 from Agribiotec srl, Italy ) and Ulocladium oudemansii HRU3 (for example in BOTRY-ZEN® from Botry-Zen Ltd, NZ). The strains can be obtained from genetic resources and deposition centers: American Type Culture Collection, 10801 University Blvd., Manassas, VA 20110-2209, USA. (strains with the prefix ATCC); CABI Europe - International Mycological Institute, Bakeham Lane, Egham, Surrey, TW20 9TINRRL, United Kingdom (strains with the prefixes CABI and IMI); Centraalbureau voor Schimmelcultures, Fungal Biodiversity Center, Uppsalaan 8, PO Box 85167, 3508 AD Utrecht, The Netherlands (strains with the CBS prefix); Division of Plant Industry, CSIRO, Canberra, Australia (strains with the prefix CC); Collection Nationale de Cultures de Microorganismes, Institut Pasteur, 25 rue du Docteur Roux, F-75724 PARIS Cedex 15 (strains with the prefix CNCM); Leibniz-Institut DSMZ-Deutsche Sammlung von Mikroorganismen und Zellkulturen GmbH, InhoffenstralJe 7 B, 38124 Braunschweig, Germany (strains with the prefix DSM); International Depositary Authority of Canada Collection, Canada (strains with the prefix IDAC); Interntional Collection of Microorgniasms from Plants, Landcare Research, Private Bag 92170. Auckland Mail Center, Auckland 1142, New Zealand (strains with the ICMP prefix); IITA, PMB 5320. Ibadan, Nigeria (strains with the prefix IITA); The National Collections of Industrial and Marine Bacteria Ltd., Torry Research Station, PO Box 31, 135 Abbey Road, Aberdeen, AB9 8DG, Scotland (strains with the prefix NCIMB); ARS Culture Collection of the National Center for Agricultural Utilization Research, Agricultural Research Service, US Department of Agriculture, 1815 North University Street, Peoria, Illinois 61604, USA. (strains with the prefix NRRL); Department of Scientific and Industrial Research Culture Collection, Applied Biochemistry Division, Palmerston North, New Zealand (strains with the prefix NZP); FEPAGRO-Fundagao Estadual de Pesquisa Agropecuária, Rua Gongalves Dias, 570. Bairro Menino Deus, Porto Alegre / RS, Brazil (strains with the prefix SEMIA); SARDI, Adelaide, South Australia (strains with the prefix SRDI); US Department of Agriculture, Agricultural Research Service, Soybean and Alfalfa Research Laboratory, BARC-West, 10300 Baltimore Boulevard, Building 011, Room 19-9, Beltsville, MD 20705, USA (strains with the USDA prefix: Beltsville Rhizobium Culture Collection Catalog March 1987 USDA-ARS ARS-30: http://pdf.usaid.gov/pdf_docs/PNAAW891.pdf); and Murdoch University, Perth, Western Australia (strains with the WSM prefix). Other strains can be found in the Global Catalog of Microorganisms .: http://gcm.wfcc.info/ and http://www.landcareresearch.co.nz/resources/collections/icmp and additional references to strain collections and their prefixes at http://refs.wdcm.org/collections.htm.Bacillus amyloliquefaciens subsp. Plantarum MBI600 (NRRL B-50595) is deposited under accession number NRRL B-50595 with the designation of strain Bacillus subtilis 1430 (and identical to NCIMB 1237). Recently, MBI 600 has been reclassified as Bacillus amyloliquefaciens subsp. plantarum based on polyphasic tests that combine classical microbiological methods based on a mixture of traditional tools such as crop-based methods) and molecular tools (such as genotyping and fatty acid analysis). Thus, Bacillus subtilis MBI600 (or MBI 600 or MBI-600) is identical to Bacillus amyloliquefaciens subsp. MBI600 plantarum. Formerly Bacillus subtilis MBI600. Bacillus amyloliquefaciens MBI600 is known as rice seed treatment that promotes the growth of Int. J. Microbiol. Res. 3 (2) (2011), 120-130 and further described for example in US 2012/0149571 A1. This MBI600 strain is, for example, commercially available as an INTEGRAL® liquid formulation product (Becker-Underwood Inc., USA). Bacillus subtilis strain FB17 was originally isolated from red beet roots in North America (System Appl. Microbiol 27 (2004) 372-379). This strain B. subtilis promotes plant health (US 2010/0260735 A1; WO 2011/109395 A2). B. subtilis FB17 has also been deposited with ATCC under the number PTA-11857 on April 26, 2011. Bacillus subtilis strain FB17 may be referred to elsewhere as UD1022 or UD10-22. Bacillus amyloliquefaciens AP-136 (NRRL B-50614), B. amyloliquefaciens AP-188 (NRRL B-50615), B. amyloliquefaciens AP-218 (NRRL B-50618), B. amyloliquefaciens AP-219 (NRRL B-50619) , B. amyloliquefaciens AP-295 (NRRL B-50620), B. japonicum SEMIA 5079 (for example Gelfix 5 or Adhere 60 of Nitral Urbana Laoboratories, Brazil, a BASF company), B. japonicum SEMIA 5080 (for example GELFIX 5 or ADHERE 60 from Nitral Urbana Laoboratories, Brazil, a BASF company), B. mojavensis AP-209 (NRRL B-50616), B. solisalsi AP-217 (NRRL B-50617), B. pumilus strain INR-7 (called de another way like BU-F22 (NRRL B-50153) and BU-F33 (NRRL B-50185)), B. simplex ABU 288 (NRRL B-50340) and B. amyloliquefaciens subsp. MBI600 plantarum (NRRL B-50595) has been mentioned in patent application US 20120149571, US 8,445,255, WO 2012/079073. Bradyrhizobium japonicum USDA 3 is known from US patent application 7,262,151. Jasmonic acid or salts (jasmonates) or derivatives include, without limitation, potassium jasmonate, sodium jasmonate, lithium jasmonate, ammonium jasmonate, dimethylammonium jasmonate, diolammonium jasmonate, diethylethyl ammonium diethylethyl ammonium jasmonic acid, jasmonic acid amide, jasmonic acid methylamide, jasmonic acid-L-amino acid conjugates (linked to amide) (for example, conjugates with L-isoleucine, L-valine, L-leucine, or L-phenylalanine), 12-oxo-phytodienoic acid, coronatin, coronafacoyl-L-serine, coronafacoyl-L-threonine, 1-oxo-indanyl-isoleucine methyl esters, 1-oxo-indanyl-leucine methyl esters, coronalon (2-acid methyl ester - [(6-Ethyl-l-oxo-indane-4-carbonyl) -amino] -3-methyl-pentanoic acid), linoleic acid or derivatives thereof and cis-jasmona, or combinations of any of the foregoing. Humates are humic and fulvic acids extracted from a form of brown coal, coal and clay, known as leonardite. Humic acids are organic acids that are produced in wet form and other organically derived materials, such as peat and some soft coal. It has been shown that they increase the efficiency of fertilizers in the absorption of phosphates and micronutrients by plants, as well as in the development of plant root systems. Bilobalide and ginkgolides are known components of the ginkgo tree. Bilobalide is the common name for (3aS, 5aR, 8aS, 9R, 10aR) -9-tert-butyl-8,9-dihydroxydihydro-9H-furo [2,3-b] furo [3 ', 2'; 2, 3] cidopenta [1,2-c] furan-2,4,7 (3H, 8H) -trione (CAS 33570-04-6) and the following ginkgolides Ginkgolida (CAS 15291-75-5), Ginkgolida B (CAS 15291-77-7), Ginkgolida C (15291-76-6), Ginkgolida J (15291-79 9), Ginkgolida M (15291-78-8) have also been previously described and registered. The compounds are commercially available, or can be obtained, preferably from ginkgo sheets by methods known in the art and described for example in US 5,700,468, EP-A 360556, EP-A 0431 535 and JP-A 09-110713. In addition, the compounds Bilobalide (in enantiopura form), Ginkgolida A (in its racemic form) and Ginkgolida B (in its racemic form) can be obtained by chemical synthesis, as disclosed for example in Tetrahedron Letters (1988), 29 (28 ), 3423-6, Tetrahedron Letters (1988), 29 (26), 3205-6 and Journal of the American Chemical Society (2000), 122 (35), 8453-8463, respectively.

Examples of mixtures

Examples of some mixtures for use in accordance with the present invention are described in the tables below.

An insecticide or fungicide in Table B-1 is abbreviated in accordance with the codes listed in Table B.

Table B

Thus, in the context of the present invention, each of the rows in Table B-1 corresponds to a mixture of compound I (of formula (I)) that will be applied in the methods according to the present invention.

In another embodiment of the present invention, the mixtures comprise the compound of formula (I) and two agriculturally active components (active compound II and active compound III) selected from the compounds listed in Table B. Therefore, in this additional embodiment , the mixtures comprise a compound of formula (I) and two fungicides or two insecticides or a compound of formula (I) and a fungicide and an insecticide, selected from Table B. Therefore, in the context of the present invention, each of the rows in table T 1 corresponds to a mixture of compound I (of formula I) that will be applied in the methods according to the present invention.

As mentioned above, the mixtures according to the present invention may comprise the compound of formula (I) combined with one, two, three or four other active ingredients. Therefore, the mixtures as described in Table T-1 above, may additionally comprise one or more active ingredients, selected from fungicides or insecticides.

According to one embodiment, the components of the composition according to the invention, such as parts of a kit or parts of a binary or ternary mixture, can be mixed by the user himself in a spray tank and other auxiliaries can be added , if appropriate.

In a further embodiment, either individual components of the composition according to the invention or partially premixed components, for example the components comprising the compounds I and / or active substances of groups M.1 to MY or FI) to F. XII listed above, may be mixed by the user in a spray tank and additional auxiliary agents and additives may be added, if applicable.

In a further embodiment, either individual components of the composition according to the invention or partially premixed components, for example the components comprising the compounds I and / or active substances of groups M.1 to MY or FI) to F. XII) listed above, can be applied together (for example, after mixing in tank) or consecutively. Biological examples

Biological tests

The applicability of the compounds of formula (I) alone in combination with other active ingredients in the application methods according to the present invention can be evaluated in the test examples provided hereinafter or in similar tests. These test examples should not be construed as limiting in any way.

As mentioned above, mixtures of the compound of formula (I) with other agriculturally active ingredients may show surprisingly synergistic effects, which can also be demonstrated in the biological test systems described below.

Synergy can be described as an interaction where the combined effect of two or more compounds is greater than the sum of the individual effects of each of the compounds. The presence of a synergistic effect in terms of percentage control, between two mixing pairs (X and Y) can be calculated using the Colby equation (Colby, SR, 1967, Calculation of synergistic and antagonistic responses in combinations of herbicides, weeds , 15, 20). 22):

When the observed combined control effect is greater than the expected combined control effect (E), then the combined effect is synergistic. The analysis of synergism or antagonism between mixtures or compositions was determined by the Colby equation.

B.1 Control of animal pests.

With respect to the control of animal pests that affect plant propagation material, especially seeds, the following test systems and results demonstrate the pesticidal activity of the carboxamide compound of formula I alone and its synergistic pesticidal activity in combination with other ingredients insecticidal assets

Test B.1.1 Control of the wire worm (Melanotus communis)

To evaluate the control of the wire worm (Melanotus communis) through the direct contact method, the individual insects were immersed directly in the compound solution. The compounds or mixtures were dissolved in acetone at different concentrations. The compounds or mixtures were formulated using a solution containing 50% (v / v) acetone in water with 0.02% by weight of Kinetic®. For experimental mixtures, identical volumes of both mixing partners were mixed to achieve the desired respective concentrations. The wire worms were immersed directly in the solution for three seconds and then allowed to air dry on a filter paper. Approximately 11 cm3 of water-soaked wet sand was dispensed in each 16 cm2 cell from a 32-cell aging tray. A treated wireworm larva was infested in each cell along with two germinating wheat seeds. The cells were then covered with adhesive bioassay tray covers. Each cell was a replica and replication was 10x. After the infestation, the test was kept in an incubator at 26 ± 1 ° C in the dark. Mortality (dying dead insects) was assessed 3 days after treatment (DAT) and the average percentage of mortality was calculated in relation to the untreated control. The results are listed in table B.1.1.

Table B.1.1:

* synergistic control effect according to the Colby equation

Test B.1.2 Worm control of western corn root (Diabrotica virgifera virgifera) To assess the control of the western corn root worm (Diabrotica virgifera virgifera) through the maximum exposure method, the insects were exposed to the treated soil. The compounds or mixtures were first dissolved in acetone and then mixed with the soil to obtain the different desired ppm concentrations (w / w) of compound / soil or mixture / soil. For experimental mixtures, identical volumes of both mixing partners were mixed to achieve the desired respective concentrations. The treatments were applied in solution to sifted loamy sand (sieve # 10) in a plastic bag. The treatments were incorporated completely by sealing and shaking each bag by hand and allowing the solution to soak through the soil mass for at least 10 minutes. The bags were then opened and kept open in an extraction hood overnight to evaporate the solvent from the soil. One day after treatment (DAT), moisture water and millet seeds soaked in water were added as a food source to each bag and completely incorporated. Approximately 11 cm3 of the millet and soil mixture were dispensed in a 1-ounce plastic cup. Each cup was infested with 10 larvae of the second stage of the western corn root worm and covered. Each cup was a replica and the replication was 3x. The test was kept in an incubator at 26 ± 1 ° C in the dark. Mortality (dying dead insects) was assessed 3 days after infestation (DAI) and the average percentage of mortality was calculated in relation to the untreated control. The results are listed in table B.1.2.

Table B.1,2:

* synergistic control effect according to the Colby equation

Test B.1.3 Control of the black cut worm (Agrotis ípsilon)

To evaluate the control of the black cutting worm (Agrotis Ípsilon) through the direct contact method, the individual insects were immersed directly in the compound solution. The compounds or mixtures were dissolved in acetone at different concentrations. The compounds or mixtures were formulated using a solution containing 50% (v / v) acetone in water with 0.02% by weight of Kinetic®. For experimental mixtures, identical volumes of both mixing partners were mixed to achieve the desired respective concentrations. The black cutting worms in the second stage were immersed directly in solution for three seconds and then allowed to air dry on filter paper. A treated black cutworm larva was infested in each 16 cm2 cell of a 32-cell aging tray along with the excised bud of a corn plant and a moistened cotton wick. The cells were then covered with adhesive bioassay tray covers. Each cell was a replica and replication was 16x. After the infestation, the test was maintained in an incubator at 25.5 ± 1 ° C and a light cycle of 14L: 10D. Mortality (dying dead insects) was evaluated 1 and 5 days after treatment (DAT) and the average percentage of mortality was calculated in relation to the untreated control. The results are listed in table B.1.3.

Table B.1.3:

To assess the control of the corn seed cress (Delia platura) through maximum exposure, the insects were exposed to the treated soil. The compounds or mixtures were first dissolved in acetone and then mixed with the soil to obtain the different desired ppm concentrations (w / w) of compound / soil or mixture / soil. For experimental mixtures, identical volumes of both mixing partners were mixed to achieve the desired respective concentrations. The treatments were applied in solution to dry and sifted game sand (sieve # 10) in a glass jar. The treatments were incorporated completely by covering and shaking each jar by hand and allowing the solution to soak through the sand mass for at least 10 minutes. Then, the jugs were uncovered and the sand was kept in an extraction hood for 4 hours to evaporate the solvent. After the sand was dry, 10 cm3 of the treated sand was dispensed in a 1-ounce plastic cup with bone meal at the bottom as a food source. Each cup was moistened with 4 ml of water, infested with five larvae of second stage corn kernel and covered. Each cup was a replica and the replication was 5x. The test was kept in an incubator at 22 ± 1 ° C in the dark. Mortality (dying dead insects) was evaluated 2 days after treatment (DAT) and the average percentage of mortality was calculated in relation to the untreated control. The results are listed in table B.1.4.

Table B.1.4

* synergistic control effect according to the Colby equation Test B.1.5 Control of root knot nematodes (Meloidogine spp.)

To assess the control of root knot nematodes (Meloidogine spp.) Through exposure by applying soaking, the nematodes were introduced into treated cucumber plants.

The compounds or mixtures were dissolved in acetone at different concentrations. The compounds or mixtures were formulated using a solution containing 50% (v / v) acetone in water with 0.02% by weight of Kinetic®. For experimental mixtures, identical volumes of both mixing partners were mixed to achieve the desired respective concentrations. Germinated cucumber seeds were sown in 1 oz black plastic cups (one seed per cup) with dry, sifted game sand (sieve # 10). The treatments were applied as a soak in 7 ml of solution to each cup that was kept in an extraction hood for 1 hour to allow the acetone to evaporate. The cups were transferred to an environmental chamber (25 ± 2 ° C, 24 L) and watered daily during the test. Each cup was a replica and the replication was 5x. In the cucumber cotyledon stage, each cup was infested with 500 juvenile root knot nematodes (J2s) in 1 ml of distilled water. Four weeks after the infestation, the cucumber roots were washed and the gills and egg masses were counted. The control was calculated as the reduction in gills or egg masses in relation to the untreated control. The average percentage of control was calculated for each treatment. The results are listed in table B.1.5.

Table B.1.5:

* Synergic control effect according to the Colby equation.

Additional examples of trials with which the control of pests that infest the soil can be evaluated are described below.

BP.1.1 Tests for spider veins (Tetranychus)

BP.1.2 Test Soaking soil test in Lima bean

The test solution comprising a compound of the present invention is prepared at the desired concentration using water and an organic solvent. Potted lime beans plants are treated with a test solution by soaking the soil. The test compounds are applied as soil soaked in 2 ml of solution at a rate of 4 mg of active ingredient / plant (2 mg / ml). The technical material is dissolved in acetone and distilled water is added to achieve a final concentration of 5% acetone. Four days after the treatment, a mixed population of two spotted spiders (Tetranychus urticae) is released on the leaves. After the infestation, the plants are stored in a light cart in the laboratory and irrigated daily.

Five days after the release of spider mites, acaricidal efficacy is measured by the classification of damage caused by spider mites or the mortality of spider mites: the number of SSTS is counted in plants, the percentage of damage as lesions is assessed visually and the means They are calculated for each treatment. The average percentage of population reduction in relation to solvent blank control is calculated. The average percentage of damage reduction in relation to the solvent blank is calculated as 100 - (average% of lesions being treated / average% of lesions in solvent blank) * 100.

Test BP.1.3 Cotton seed treatment test

The test solution comprising a compound of the present invention is prepared at the desired concentration using water and an organic solvent. The cotton seeds are coated with said test solution prepared to a 0.5 mg cup of active ingredient / seed and planted in the pots. After the emergence of the plant, a mixed population of two spider-spotted spiders is released. Four days after the release of spider veins, acaricidal efficacy is measured by rating the damage caused by spider veins or the mortality of spider veins: The percentage of damage according to the lesions was assessed visually and the means for each treatment are calculated. The average percentage of damage reduction in relation to the solvent blank is calculated as 100 - (average% of lesions being treated / average% of lesions in solvent blank) * 100.

Test BP.1.4 Cucumber seed treatment test

The test solution comprising a compound of the present invention is prepared at the desired concentration using water and acetone as an organic solvent. Cucumber seeds are coated with a prepared test solution that is applied to a 0.5 mg cup of active ingredient / seed and planted in the pots. After the emergence of the plant (eleven days after treatment and planting), a mixed population of two spider-spotted spiders is released. Four days after the release of spider veins, acaricidal efficacy is measured by rating the damage caused by spider veins. The percentage of damage depending on the lesions is assessed visually and the means for each treatment are calculated. The average percentage of harm reduction in Solvent blank ratio is calculated as 100 - (average% of lesions in treatment / average% of lesions in solvent blank) * 100.

BP.1.5 Tests for nematode (Meloidogine)

Test B.2.1 Soaking tomato soil against juvenile root knot nematodes

Tomatoes are grown in potting soil until the approximate first stage of the true leaf (approximately 2 weeks after planting). Tomatoes are transplanted into game sand. Seven days after the transplant, the technical material of the test compound is dissolved in acetone and then water is added to achieve a final concentration of 50% acetone. 1 ml of solution is transferred by pipette into the root zone of the tomato. One day after treatment (DAT), each pot is infested with approximately 500 juvenile root knot nematodes (Melyodogine spp.) In 1 ml of distilled water. Immediately after the infestation, the plants are placed in the greenhouse. Plants are watered and fertilized daily. At 14 DAT, the tomato roots are rinsed and the number of gills is counted. The replication is 5 times.

B.2 Control of phytopathological fungi.

With respect to the control of phytopathological fungi that affect plant propagation material, especially seeds, the following test systems and results demonstrate the fungicidal activity of the carboxamide compound of formula I alone and its synergistic fungicidal activity in combination with others fungicidal active ingredients.

Micro-tests for the evaluation of fungicidal activity.

The active compounds were formulated separately as a stock solution having a concentration of 10,000 ppm in dimethylsulfoxide.

B.2.1. Activity against the explosion of Piricularia oryzae rice

Stock solutions were mixed according to the indicated ratio, pipetted into a microtiter plate (MTP) and diluted with water at the indicated concentrations. Then a spore suspension of Piricularia oryzae in an aqueous solution of biomalt or yeast-bactopeptone-glycerin was added. The plates were placed in a saturated steam chamber at a temperature of 18 ° C. Using an absorption photometer, the MTPs were measured at 405 nm 7 days after inoculation. The results are given in table B.2.1 below.

Table B.2.1 .: Piricularia oryzae

B.2.2. Activity against the early blast caused by Alternaría solani.

Stock solutions were mixed according to the indicated ratio, pipetted into a microtiter plate (MTP) and diluted with water at the indicated concentrations. Then a suspension of spores of Alternaria solani in an aqueous solution of biomalt or yeast-bactopeptone-glycerin was added. The plates were placed in a saturated steam chamber at a temperature of 18 ° C. Using an absorption photometer, the MTPs were measured at 405 nm 7 days after inoculation. The results are given in table B.2.2 below.

Table B.2.2 .: Alternaria solani

B.2.3. Activity against Microdochium nivale

Stock solutions were mixed according to the indicated ratio, pipetted into a microtiter plate (MTP) and diluted with water at the indicated concentrations. A suspension of spores of Microdochium nivale in an aqueous solution of biomalt or yeast-bactopeptone-glycerin was then added. The plates were placed in a saturated steam chamber at a temperature of 18 ° C. Using an absorption photometer, the MTPs were measured at 405 nm 7 days after inoculation. The results are given in table B.2.3 below.

Table B.2.3 .: Microdochium nivale

B.2.4. Activity against Rhizoctonia solani.

Stock solutions were mixed according to the indicated ratio, pipetted into a microtiter plate (MTP) and diluted with water at the indicated concentrations. A suspension of Rhizoctonia solani spores in an aqueous solution of biomalt or yeast-bactopeptone-glycerin was then added. The plates were placed in a saturated steam chamber at a temperature of 18 ° C. Using an absorption photometer, the MTPs were measured at 405 nm 7 days after inoculation. The results are given in table B.2.4 below.

Table B.2.4 .: Rhizoctonia solani

The measured parameters were compared with the growth of the free control variant of active compound (100%) and the fungal free blank value and free of active compound to determine the relative growth in% of the pathogens in the respective active compounds. These percentages became efficiencies.

As mentioned earlier, the expected efficiencies of active compound mixtures were determined using the Colby formula [R.S. Colby, "Calculating sinergistic and antagonistic responses of herbicide combinations", Weeds 15, 20-22 (1967)] and in comparison with the observed efficiencies.

Claims (15)

1. Use of the active compound pesticide carboxamide of formula (I):

or tautomers, enantiomers, diastereomers or salts thereof, wherein the active compound I of formula (I) is combined and / or applied together with at least one other active compound in agricultural function selected from the group of insecticides and / or fungicides consisting of fluxapiroxad, epoxiconazole, triticonazole, abamectin, emamectin, cantaniliprol, chlorantraniliprol, thiacloprid to control and / or combat animal pests in soil application methods and seed treatment methods, wherein the active compound of formula (I) is applied directly and / or indirectly to the plant and / or to the propagation material of the plant soaking the soil, by application by dripping in the soil, by injection of soil, by immersion or by treatment of seeds. 2. Use according to claim 1, wherein at least one active compound in agricultural function selected from the group of insecticides and / or fungicides is combined and / or applied therewith. 3. Use according to claim 2, wherein at least one additional active compound is pyraclostrobin fungicide. 4. Use according to claim 2, wherein at least one additional active compound is the fungicide Metalaxil. 5. Use according to claim 2, wherein at least one additional active compound is the thiophanateomethyl fungicide. 6. Use according to claim 2, wherein at least one additional active compound is selected from the group consisting of 2- [2-chloro-4- (4-chlorophenoxy) phenyl] -1 (1,2,4- triazol-1-yl) pentan-2-ol, 1- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1 cyclopropyl-2- (1,2,4-triazol-1-yl) ethanol , 2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1,2,4-triazol-1-yl) butan-2-ol, 2- [2-chloro-4- (4-chlorophenoxy) phenyl] -1- (1,2,4-triazol-1-yl) butan-2-ol, 2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -3- methyl-1- (1,2,4-triazol-1-yl) butan-2-ol, 2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1,2,4 -triazol-1-yl) propan-2-ol, 2- [2-chloro-4- (4-chlorophenoxy) phenyl] -3-methyl-1- (1,2,4-triazol-1-yl) butan -2-ol, 2- [4- (4-chlorophenoxy) -2- (trifiuoromethyl) phenyl] -1- (1,2,4-triazol-1-yl) pentan-2-ol or 2- [4- (4-fluorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1,2,4-triazol-1-yl) propan-2-ol. 7. Use according to claim 2, wherein at least one additional active compound is an insecticide selected from the group consisting of acetate, chlorpyrifos, fipronil, methiocarb, thiodicarb, lamba-cyhalotrine, cypermethrin, alpha-cypermethrin, biphentrine, teflutrin , acetamipridine, clothianidine, dinotefuran, imidacloprid, thiacloprid, thiamethoxam, abamectin, emamectin, flubendiamide, chlorantraniliprole, ciantraniliprole, triflumezopyrim, spinosad, sulfoxaflor, or active on the basis of Bac or P. falus, based on Firmus or P.us. 8. Use according to claim 2, wherein at least one additional active compound is an insecticide selected from the group consisting of N- [4,6-dichloro-2 - [(diethyl-lambda-4-sulfaniliden) carbamoyl] -phenyl] -2- (3-chloro-2-pyridyl) -5- (trifluoromethyl) pyrazol-3-carboxamide, N- [4-chloro-2 - [(diethyl-lambda-4-sulfaniliden) carbamoyl] -6 -methyl-phenyl] -2- (3-chloro-2-pyridyl) -5- (trifluoromethyl) pyrazol-3-carboxamide or N- [4-chloro-2 - [(di-2-propyl-lambda-4- sulfaniliden) carbamoyl] -6-methyl-phenyl] -2- (3-chloro-2-pyridyl) -5- (trifluoromethyl) pyrazol-3-carboxamide. 9. Use according to claim 2, wherein at least one additional active compound is the thiamethoxam insecticide. 10. Use according to claim 2, wherein at least one additional active compound is Bacillus firmus I-1582. 11. Use of the pesticide carboxamide active compound of formula (I) in combination with at least one other active ingredient according to any one of claims 1 to 10, wherein the plant or plant propagation material to be treated is grown on a substrate of artificial growth. 12. Use of the active carboxamide pesticidal compound of formula (I) according to claim 11, wherein the artificial growth substrate is selected from rock wool, glass wool, quartz sand, gravel, expanded clay and vermiculite. 13. Use of the pesticide carboxamide active compound of formula (I) in combination with at least one other active ingredient according to any one of claims 1 to 10, wherein the plant or propagation material of the plant to be treated is planted or grown In a closed system. 14. A method for the protection of plant propagation material comprising contacting plant propagation material with the combination of compounds as defined in any of claims 1 to 10 in effective amounts as pesticides, wherein the material Plant propagation are seeds of transgenic plants. 15. Seed, comprising the combination of compounds as defined in any of claims 1 to 10 in an amount of 0.1 g to 10 kg per 100 kg of seeds, wherein the combination comprises the carboxamide compound of formula (I) or tautomers, enantiomers, diastereomers or salts thereof.