Fourteen species new for science are described, illustrated and compared with closely related taxa. Six species of them are from South Korea, i.e. Bryostigma huriellae S. Y. Kondr. et J.-S. Hur, Caloplaca ulleungensis S. Y. Kondr., L. Lokös et J.-S. Hur, Enterographa dokdoensis S. Y. Kondr. et J.-S. Hur, Neobrownliella salyangensis S. Y. Kondr. et J.-S. Hur, Rufoplaca aesanensis S. Y. Kondr. et J.-S. Hur, Squamulea coreana S. Y. Kondr. et J.-S. Hur, and seven species are from Chile: Caloplaca nothocitrina S. Y. Kondr. et J.-S. Hur, Caloplaca nothoholocarpa S. Y. Kondr. et J.-S. Hur, Caloplaca patagoniensis S. Y. Kondr., S.-O. Oh et J.-S. Hur, Follmannia suborthoclada S. Y. Kondr. et J.-S. Hur, 'Lecidea' buellielloides S. Y. Kondr. et J.-S. Hur, Massjukiella rusavskioides S. Y. Kondr. et J.-S. Hur, Rehmanniella poeltiana S. Y. Kondr. et J.-S. Hur, as well as one species, i.e. Pyrenodesmia vernadskiensis S. Y. Kondr., T. O. Kondratiuk et I. Yu. Parnikoza, similar to Antarctic endemic species Huea coralligera, is from Argentine Islands, Western Antarctic Peninsula. The member of the genus Pyrenodesmia A. Massal. is for the first time confirmed by molecular data from the Antarctic. Eighteen new combinations, i.e. Massjukiella impolita (for Caloplaca impolita Arup), Massjukiella pollinarioides (for Xanthoria pollinarioides L. Lindblom et D. M. Wright), Massjukiella stellata (for Caloplaca stellata Wetmore et Kärnefelt), Massjukiella tenax (for Xanthoria tenax L. Lindblom), and Massjukiella tenuiloba (for Xanthoria tenuiloba L. Lindblom), Pyrenodesmia albopruinosa (for Biatorina albopruinosa Arnold), Pyrenodesmia ceracea (for Caloplaca ceracea J. R. Laundon), Pyrenodesmia cretensis (for Blastenia cretensis Zahlbr.), Pyrenodesmia erythrocarpa (for Patellaria erythrocarpa Pers.), Pyrenodesmia haematites (for Lecanora haematites Chaub. ex St.-Amans), Pyrenodesmia percrocata (for Blastenia percrocata Arnold), Pyrenodesmia soralifera (for Caloplaca soralifera Vondrák et Hrouzek), Pyrenodesmia transcaspica (for Lecanora transcaspica Nyl.), Pyrenodesmia viridirufa (for Lecidea viridirufa Ach.), Pyrenodesmia xerica (for Caloplaca xerica Poelt et Vezda), as well as Rehmanniella leucoxantha (for Amphiloma leucoxanthum Müll. Arg.), Rehmanniella syvashica (for Caloplaca syvashica Khodos., Vondrák et Šoun), and Rehmanniella subgyalectoides (for Caloplaca subgyalectoides S. Y. Kondr. et Kärnefelt) are proposed. Buelliella inops and Zwackhiomyces aff. berengerianus are for the first time recorded from South America as well as from Follmannia orthoclada (as lichenicolous fungi). Caloplaca poliotera, Rinodina convexula and Rinodina kozukensis are new to the Republic of Korea, and new localities as well as illustrations for the further 13 new and rare lichen species recently described from Eastern Asia are provided too. Key words: Antarctica, Bryostigma, Caloplaca, Chile, Enterographa, Follmannia, Lecidea, Massjukiella, Neobrownliella, Pyrenodesmia, Rehmanniella, Rufoplaca, South America, South Korea, Squamulea