Abstract
On the basis of their high adsorption and cation exchange capacity, swelling potential and low toxicity, layered sodium silicate magadiite (Na–magadiite) is an attractive solid for intercalation of polymers. This study envisages the intercalation of cationic biopolymer chitosan (Chit) in Na–magadiite to prepare a Chit/magadiite micro/nanocomposite. Characterisation of starting-magadiite, pure chitosan and Chit/magadiite were investigated using powder X-ray diffraction analysis (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy and thermal analysis. XRD confirmed that the chitosan had been intercalated into the interlayer space of magadiite by increasing the basal spacing, d001 from 15.6 Å to 21.45 Å. The presence of characteristic bands of biopolymer and layered silicate in Chit/magadiite were confirmed by FTIR analysis. The thermal stability of micro/nanocomposite was evaluated by thermogravimetry analysis. The results suggested the formation of electrostatic interactions by protonated amine groups with the negatively charged magadiite surface as well as intercalation in the form of a predominant monolayer arrangement of chitosan chains in layered silicate magadiite.
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References
D. Rahangdale, A. Kumar, Biopolymer Grafting (Elsevier, Elsevier, 2018), p. 251
D. Elieh-Ali-Komi, M.R. Hamblin, Int. J. Adv. Res. 4, 3 (2016)
M. Rinaudo, Prog. Polym. Sci. 31, 7 (2006)
S. Wang, L. Shen, Y. Tong, L. Chen, I. Phang, P. Lim, T. Liu, Polym. Degrad. Stab. 90, 1 (2005)
M.N.R. Kumar, React. Funct. Polym. 46, 1 (2000)
P. Monvisade, P. Siriphannon, Appl. Clay Sci. 42, 3 (2009)
H.P. Eugster, L.A. Hardie, Lakes (Springer, 1978), p. 237
S.M. Auerbach, K.A. Carrado, P.K. Dutta, Handbook of Layered Materials (CRC Press, Boca Raton, 2004)
Y.-R. Wang, S.-F. Wang, L.-C. Chang, Appl. Clay Sci. 33, 1 (2006)
G.G. Almond, R.K. Harris, K.R. Franklin, P. Graham, J. Mater. Chem. 6, 5 (1996)
A. Mokhtar, Z.A.K. Medjhouda, A. Djelad, A. Boudia, A. Bengueddach, M. Sassi, Chem. Pap. 72, 39 (2018)
G.L. Paz, E.C. Munsignatti, H.O. Pastore, J. Mol. Catal. A: Chem. 422, 43 (2016)
A. Mokhtar, A. Djelad, A. Boudia, M. Sassi, A. Bengueddach, J. Porous Mater. 27, 1627 (2017)
S. Benkhatou, A. Djelad, M. Sassi, M. Bouchekara, A. Bengueddach, Desalination Water Treat. 57, 20 (2016)
S. Peng, Q. Gao, Z. Du, J. Shi, Appl. Clay Sci. 31, 3 (2006)
A. Giannakas, K. Grigoriadi, A. Leontiou, N.-M. Barkoula, A. Ladavos, Carbohydr. Polym. 108, 103 (2014)
M. Darder, M. Colilla, E. Ruiz-Hitzky, Chem. Mater. 15, 20 (2003)
R.M.B. Vieira, H.O. Pastore, Environ. Sci. Technol. 48, 4 (2014)
M. Ogawa, Y. Ide, M. Mizushima, Chem. Commun. 46, 13 (2010)
M. Ogawa, Y. Takizawa, J. Phys. Chem. B 103, 24 (1999)
R. Celis, M. Adelino, M. Hermosin, J. Cornejo, J. Hazard. Mater. 209, 67 (2012)
Y. Huang, Z. Jiang, W. Schwieger, Chem. Mater. 11, 5 (1999)
A.R. Nunes, A.O. Moura, A.G. Prado, J. Therm. Anal. Calorim. 106, 2 (2011)
Y. Chen, G. Yu, F. Li, J. Wei, Appl. Clay Sci. 88, 163 (2014)
S. Farhoudian, M. Yadollahi, H. Namazi, Int. J. Biol. Macromol. 82, 273 (2016)
V.A. Pereira, I.N.Q. de Arruda, R. Stefani, Food Hydrocoll. 43, 180 (2015)
S. Bensalem, B. Hamdi, S. Del Confetto, M. Iguer-Ouada, A. Chamayou, H. Balard, R. Calvet, Colloids Surf. A Physicochem. Eng. Asp. 516, 336 (2017)
N. Bleiman, Y.G. Mishael, J. Hazard. Mater. 183, 1 (2010)
P. Sun, P. Li, Y.M. Li, Q. Wei, L.H. Tian, J. Biomed. Mater. Res. Part B Appl. Biomater. 97, 1 (2011)
S. Hua, H. Yang, W. Wang, A. Wang, Appl. Clay Sci. 50, 1 (2010)
C. Paluszkiewicz, E. Stodolak, M. Hasik, M. Blazewicz, Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 79, 4 (2011)
F. Feng, K.J. Balkus, J. Porous Mater. 10, 1 (2003)
H.O. Pastore, M. Munsignatti, A.J. Mascarenhas, Clays Clay Miner. 48, 2 (2000)
X. Qu, A. Wirsen, A.-C. Albertsson, Polymer 41, 12 (2000)
W. Tan, Y. Zhang, Y.-S. Szeto, L. Liao, Compost. Sci. Technol. 68, 14 (2008)
Y.-S. Han, S.-H. Lee, K.H. Choi, I. Park, J. Phys. Chem. Solids 71, 4 (2010)
J.-W. Rhim, S.-I. Hong, H.-M. Park, P.K. Ng, J. Agric. Food Chem. 54, 16 (2006)
N. Belhouchat, H. Zaghouane-Boudiaf, C. Viseras, Appl. Clay Sci. 135, 9 (2017)
F. Leroux, J. Gachon, J.-P. Besse, J. Solid State Chem. 177, 1 (2004)
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Mokhtar, A., Djelad, A., Bengueddach, A. et al. Biopolymer-layered polysilicate micro/nanocomposite based on chitosan intercalated in magadiite. Res Chem Intermed 44, 6469–6478 (2018). https://doi.org/10.1007/s11164-018-3502-1
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DOI: https://doi.org/10.1007/s11164-018-3502-1