Skip to main content
Log in

Xieite, a new mineral of high-pressure FeCr2O4 polymorph

  • Articles/Geology
  • Published:
Chinese Science Bulletin

Abstract

Xieite, a new mineral, occurs in the shock vein of the Suizhou meteorite. The mineral has an orthorhombic structure and its space group is Bbmm. The cell parameters are a = 9.462(6) Å, b = 9.562(9) Å, c = 2.916(1)Å. The crystal-chemical formula is (Fe0.87Mg0.13Mn0.01)1.01(Cr1.62Al0.25Ti0.08V0.02)1.97O4, or simply formula FeCr2O4. Stronger X-ray diffraction lines are [d (Å), lll o]: (2.675, 100), (2.389, 20), (2.089, 10), (1.953, 90), (1.566, 60), (1.439, 15), (1.425, 15), (1.337, 40). Xieite is a high pressure polymorph of FeCr2O4 and formed by solid-state transformation of chromite under shock-induced high pressure and temperature, in association with other high-pressure minerals including ringwoodite, majorite, lingunite and tuite. The P-T condition for the formation of xieite is estimated to be 18–23 GPa and 1800–1950°C, respectively. Xieite has recently been approved by the Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association (IMA 2007-056). The mineral name, xieite, is named after Xiande Xie.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Reid A F, Ringwood A E. Newly observed high pressure transformations in Mn3O4, CaAl2O4, and ZrSiO4. Earth Planet Sci Lett, 1969, 6: 205–208

    Article  CAS  Google Scholar 

  2. Irifune T, Fujino K, Ohtani E. A new high-pressure form of MgAl2O4. Nature, 1991, 349: 409–411

    Article  CAS  Google Scholar 

  3. Funamori N, Jeanloz R, Nguyen J H, et al. High-pressure transformations in MgAl2O4. J Geophys Res, 1998, 103: 20813–20818

    Article  CAS  Google Scholar 

  4. Fei Y, Frost D J, Mao H K, et al. In situ structure determination of the high-pressure phase of Fe3O4. Am Mineral, 1999, 84: 203–206

    CAS  Google Scholar 

  5. Andrault D, Bolfan-Casanova N. High-pressure phase transformations in the MgFe2O4 and Fe2O3-MgSiO3 system. Phys Chem Mineral, 2001, 28: 211–217

    Article  CAS  Google Scholar 

  6. Chen M, Shu J, Xie X, et al. Natural CaTi2O4-structured FeCr2O4 polymorph in the Suizhou meteorite and its significance in mantle mineralogy. Geochim Cosmochim Acta, 2003, 7: 3937–3942

    Article  Google Scholar 

  7. Xie X, Chen M, Wang D. Shock-related mineralogical features and P-T history of the Suizhou L6 chondrite. Eur J Mineral, 2001, 13: 1177–1190

    Article  CAS  Google Scholar 

  8. Xie X, Minitti M E, Chen M, et al. Tuite. γ-Ca3(PO4)2: A new mineral from the Suizhou L6 chondrite. Eur J Mineral, 2003, 15: 1001–1005

    Article  CAS  Google Scholar 

  9. Bertaut E F, Blum P. Determination de la Structure de Ti2CaO4 par la Méthode Self-Consistante d’Approche Directe. Acta Cryst, 1956, 9: 121–126

    Article  CAS  Google Scholar 

  10. Bright N F H, Rowland J F, Wurm J G. The compound CaO. Ti2O3. Can J Chem, 1958, 36: 492–495

    Article  CAS  Google Scholar 

  11. Chen M, Sharp T G, El Goresy A, et al. The majorite-pyrope + magnesiowüstite assemblage: constraints on the history of shock veins in chondrites. Science, 1996, 271: 1570–1573

    Article  CAS  Google Scholar 

  12. Gillet P, Chen M, Dubrovinsky L, et al. Natural NaAlSi3O8-hollandite in the shocked Sixiangkou meteorite. Science, 2000, 287: 1633–1636

    Article  PubMed  CAS  Google Scholar 

  13. Agee C B, Li J, Shannon M C, et al. Pressure-temperature phase diagram for the Allende meteorite. J Geophys Res, 1995, 100: 17725–17740

    Article  CAS  Google Scholar 

  14. Chen M, Shu J, Mao H K, et al. Natural occurrence and synthesis of two new post-spinel polymorphs of chromite. Proc Natl Acad Sci USA, 2003, 100: 14651–14654

    Article  PubMed  CAS  Google Scholar 

  15. Green H W II. Shock-induced minerals in meteorite provide prospecting tools for mineral physics. Proc Natl Acad Sci USA, 2004, 101: 6–7

    Article  PubMed  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Ming Chen.

Additional information

Supported by National Natural Science Foundation of China (Grant Nos. 40672035 and 40272028), and the Chinese Academy of Sciences (Grant No. KJCX2-SW-N20)

About this article

Cite this article

Chen, M., Shu, J. & Mao, Hk. Xieite, a new mineral of high-pressure FeCr2O4 polymorph. Chin. Sci. Bull. 53, 3341–3345 (2008). https://doi.org/10.1007/s11434-008-0407-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11434-008-0407-1

Keywords

Navigation