Sperrylite

Sperrylite belongs to the pyrite group of minerals and therefore it shares similar structure and crystal habits with them. Analyses typically show minor amounts of rhodium. Trace copper, iron, and antimony as well as intergrowths with Pt-Fe are reported from some occurrences. Sperrylite crystallizes in Pa3, with a =5.9681(l) A. (Szymański, 1979). It has very similar crystal structure as in platarsite (ideally PtAsS). Sperrylite crystals vary considerably in shape and size and are usually enclosed in a variety of host minerals. They are usually closely associated with basemetal sulfide. They are commonly at the edge and partially enclosed by pentlandite, pyrrhotite or chalcopyrite. Seabrook (2004). Sperrylite is composed of loose aggregate of bright silver cubes, some with octahedral modifications. The grains are mostly anhedral, but a few euhedral grains could also be encountered. Sperrylite is formed by contact metamorphism, as in indicated by the development of triple point annealing contacts with pyrrhotite grains. The grains of sperrylite are surrounded by later veins of pyrite. Sperrylite is cubic (2/m3) and is typically seen in well-developed cubes or cuboctahedra, some of which are so highly modified that crystal edges and comers appear rounded. (Nicol and Goldschmidt 1903) identified seventeen crystal forms exhibited by sperrylite, including four different trapezohedra, a trisoctahedron, five pyritohedra, and four diploids. Crystals to 2.5 cm have been reported.

Sperrylite is the most common platinum mineral, it generally occurs with a wide array of other unusual minerals, including cooperite [(Pt,Pd,Ni)S], laurite [RuS2], kotulskite [Pd(Te,Bi)], merenskyite [(Pd,Pt)(Te,Bi)2], iridium-osmium (Ir-Os) alloys, sudburyite [(Pd,Ni)Sb], omeiite [(Os,Ru)As2], testibiopalladite [PdTe(Sb,Te)], and niggliite [PtSn], to name a few. It does not readily decompose through normal weathering processes and, consequently, has been reported in widely scattered alluvial deposits. It was first found as tiny crystals found with rhodolite garnet and corundum during alluvial gem mining in streams draining Mason Mountain, Macon County, North Carolina (Hidden 1898). Sperrylite has been identified in Finland from sulfide deposits generally associated with layered mafic-ultramafic complexes.