Murataite-(Y)
A valid IMA mineral species
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About Murataite-(Y)
Formula:
(Y,Na)6Zn(Zn,Fe3+)4(Ti,Nb,Na)12O29(O,F,OH)10F4
Colour:
Black
Lustre:
Sub-Metallic
Hardness:
6 - 6½
Specific Gravity:
4.69
Crystal System:
Isometric
Name:
Named in 1974 by John W. Adams, Theodore Botinelly, William N. Sharp, and Keith Robinson in honor of Kiguma Jack Murata [December 29, 1909 - December 27, 2001 Sacremento, Sacremento County, California, USA] geochemist at Menlo Park, U. S. Geological Survey.
Polysomatic pyrochlore-murataite series with modular structure and four structural varieties of murataite (3C, 5C, 7C, and 8C) are described by Laverov et al. (2011).
The structure is a derivative of that of fluorite. The synthetic 8C polytype is a candidate for long-term immobilization of high-level nuclear waste. Its octahedral framework is modular, consisting of alternate murataite and pyrochlore modules to form a transitional substructure combining parts of the struture of the 3C polytype and pyrochlore.
The structure is a derivative of that of fluorite. The synthetic 8C polytype is a candidate for long-term immobilization of high-level nuclear waste. Its octahedral framework is modular, consisting of alternate murataite and pyrochlore modules to form a transitional substructure combining parts of the struture of the 3C polytype and pyrochlore.
Unique Identifiers
Mindat ID:
2811
Long-form identifier:
mindat:1:1:2811:6
GUID
(UUID V4):
(UUID V4):
3ae748d5-1d68-4950-b356-45ab3c893101
IMA Classification of Murataite-(Y)
Approved
IMA Formula:
(Y,Na)6Zn(Zn,Fe3+)4(Ti,Nb,Na)12O29(O,F,OH)10F4
First published:
1974
Classification of Murataite-(Y)
4.DF.15
4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
D : Metal: Oxygen = 1:2 and similar
F : With large (+- medium-sized) cations; dimers and trimers of edgesharing octahedra
4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
D : Metal: Oxygen = 1:2 and similar
F : With large (+- medium-sized) cations; dimers and trimers of edgesharing octahedra
Dana 7th ed.:
8.7.1.1
8.7.1.1
8 : MULTIPLE OXIDES CONTAINING NIOBIUM,TANTALUM OR TITANIUM
7 : Miscellaneous
8 : MULTIPLE OXIDES CONTAINING NIOBIUM,TANTALUM OR TITANIUM
7 : Miscellaneous
18.2.20
18 : Niobates and Tantalates
2 : Niobates and tantalates containing rare earths but not U
18 : Niobates and Tantalates
2 : Niobates and tantalates containing rare earths but not U
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Mrat-Y | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Murataite-(Y)
Sub-Metallic
Transparency:
Opaque
Colour:
Black
Comment:
Dark brown in thin section
Streak:
Dark brown
Hardness:
6 - 6½ on Mohs scale
Hardness:
VHN100=782 - 870 kg/mm2 (15 s test time) - Vickers
Tenacity:
Brittle
Cleavage:
None Observed
Fracture:
Conchoidal
Density:
4.69 g/cm3 (Measured) 4.64 g/cm3 (Calculated)
Optical Data of Murataite-(Y)
Type:
Isotropic
RI values:
n = 2.13
Birefringence:
Isotropic minerals have no birefringence
Surface Relief:
Very High
Anisotropism:
Very weak
Bireflectance:
slight
Reflectivity:
Wavelength | R |
---|---|
546nm | 13.7% |
589nm | 13.1% |
630nm | 12.7% |
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 13.7%.
Colour in reflected light:
Gray, darker in oil
Internal Reflections:
Faint orange in air. Conspicuous and pale orange to white in oil.
Pleochroism:
Weak
Comments:
Slight in air, but distinct in oil.
Chemistry of Murataite-(Y)
Mindat Formula:
(Y,Na)6Zn(Zn,Fe3+)4(Ti,Nb,Na)12O29(O,F,OH)10F4
Crystallography of Murataite-(Y)
Crystal System:
Isometric
Class (H-M):
m3m (4/m 3 2/m) - Hexoctahedral
Space Group:
Fm3m
Cell Parameters:
a = 14.836 Å
Unit Cell V:
3,265.51 ų (Calculated from Unit Cell)
Z:
8
Comment:
Space Group: F43m
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0005476 | Murataite-(Y) | Ercit T S, Hawthorne F C (1995) Murataite, a UB12 derivative structure with condensed Keggin molecules The Canadian Mineralogist 33 1223-1229 | 1995 | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
8.51 Å | (30) |
7.38 Å | (10) |
3.414 Å | (10) |
3.028 Å | (10) |
2.858 Å | (100) |
2.468 Å | (60) |
2.265 Å | (10) |
2.141 Å | (20) |
2.080 Å | (20) |
1.746 Å | (80) |
1.489 Å | (80) |
Comments:
Adams et al. (1974)
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Near-surface Processes | |
22 : Hydration and low-𝑇 subsurface aqueous alteration (see also #23) | |
Stage 4b: Highly evolved igneous rocks | >3.0 |
35 : Ultra-alkali and agpaitic igneous rocks |
Type Occurrence of Murataite-(Y)
General Appearance of Type Material:
Anhedral black grains at the contact of astrophyllite and quartz.
Place of Conservation of Type Material:
National Museum of Natural History, Washington, D.C., USA, 133319–133321.
Geological Setting of Type Material:
Alkali granite pegmatite.
Associated Minerals at Type Locality:
Reference:
Adams J W, Botinelly T, Sharp W N, Robinson K (1974) Murataite, a new complex oxide from El Paso County, Colorado. American Mineralogist 59, 172-176
Other Language Names for Murataite-(Y)
Common Associates
Associated Minerals Based on Photo Data:
2 photos of Murataite-(Y) associated with Astrophyllite | K2NaFe2+7Ti2Si8O26(OH)4F |
2 photos of Murataite-(Y) associated with Quartz | SiO2 |
Related Minerals - Strunz-mindat Grouping
4.DF.05 | Aeschynite-(Ce) | (Ce,Ca,Fe,Th)(Ti,Nb)2(O,OH)6 |
4.DF.05 | Aeschynite-(Nd) | (Nd,Ln,Ca)(Ti,Nb)2(O,OH)6 |
4.DF.05 | Aeschynite-(Y) | (Y,Ln,Ca,Th)(Ti,Nb)2(O,OH)6 |
4.DF.05 | Nioboaeschynite-(Ce) | (Ce,Ca)(Nb,Ti)2(O,OH)6 |
4.DF.05 | Nioboaeschynite-(Nd) | (Nd,Ce,Ca,Th)(Nb,Ti,Fe,Ta)2(O,OH)6 |
4.DF.05 | Nioboaeschynite-(Y) | (Y,REE,Ca,Th,Fe)(Nb,Ti,Ta)2(O,OH)6 |
4.DF.05 | Rynersonite | CaTa2O6 |
4.DF.05 | Tantalaeschynite-(Y) | Y(Ta,Ti,Nb)2O6 |
4.DF.05 | Vigezzite | (Ca,Ce)(Nb,Ta,Ti)2O6 |
4.DF.10 | Changbaiite | PbNb2O6 |
Fluorescence of Murataite-(Y)
Not fluorescent
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Murataite-(Y)
mindat.org URL:
https://www.mindat.org/min-2811.html
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References for Murataite-(Y)
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Localities for Murataite-(Y)
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Russia | |
| Pekov (1998) +1 other reference |
Saudi Arabia | |
| Grainger et al. (1989) |
USA (TL) | |
| Adams et al. (1974) +1 other reference |
Eckel et al. (1997) |
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St Peters Dome, Cheyenne Mining District, El Paso County, Colorado, USA