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Katoite Ca3 Al2 (SiO4 )3¡x (OH)4x (x = 1.5 to 3.

0)
°
c 2001 Mineral Data Publishing, version 1.2

Crystal Data: Cubic. Point Group: 4=m 3 2=m: Octahedra crystals, typically rounded, to
0.3 mm, in thin crusts of columnar aggregates.

Physical Properties: Hardness = n.d. D(meas.) = n.d. D(calc.) = 2.76

Optical Properties: Transparent to translucent. Color: Milky white; in transmitted light,


colorless.
Optical Class: Isotropic; may be weakly birefringent. n = 1.632(1)

Cell Data: Space Group: Ia3d: a = 12.358(2) Z=8

X-ray Powder Pattern: Campomorto quarry, Italy.


2.763 (100), 2.257 (58), 2.004 (58), 3.089 (50), 5.046 (37), 1.6507 (37), 3.303 (32)

Chemistry: (1)
SiO2 10.58
Al2 O3 24.01
MgO 0.07
CaO 42.27
H2 O 20.8
SO3 2.27
Total [100.00]

(1) Campomorto quarry, Italy; by electron microprobe, H2 O by TGA, recalculated slightly to


100.00%; corresponds to Ca2:96 (Al1:85 Mg0:01 )§=1:86 (Si0:69 S0:11 )§=0:80 [(OH)9:07 O2:93 ]§=12:00 :

Polymorphism & Series: Forms a series with grossular and hibschite.

Mineral Group: Garnet group.

Occurrence: A hydrothermal mineral in cavities in a phonolitic lava °ow that erupted through
an argillaceous marl.

Association: Tobermorite, afwillite, gehlenite, hydrocalumite, \opal," portlandite, apophyllite,


cordierite, jennite, strÄatlingite, chabazite, gismondine, phillipsite, vertumnite, ettringite, garnet,
wollastonite, gypsum, calcite, quartz, hematite.

Distribution: In the Campomorto quarry, near Montalto di Castro, Lazio, Italy.

Name: In honor of Akira Kato, mineralogist of the National Science Museum, Tokyo, Japan.

Type Material: Municipal Museum of Natural History, Milan, Italy; National Museum of
Natural History, Washington, D.C., USA, 163797.

References: (1) Passaglia, E. and R. Rinaldi (1984) Katoite, a new member of the
Ca3 Al2 (SiO4 )3 { Ca3 Al2 (OH)12 series and a new nomenclature for the hydrogrossular group of
minerals. Bull. Min¶eral., 107, 605{618. (2) (1985) Amer. Mineral., 70, 873 (abs. ref. 1).

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