Hierarchical hollow and direct Z-scheme nanocomposites were two prominent representatives of an efficient photocatalyst due to their unique structure advantages and strong photoredox properties. In this report, two types of Z-scheme photocatalysts, namely In₂S₃-Bi₂S₃ (IBS) and In₂O₃-Bi₂O₃ (IBO) have been successfully prepared from the same bimetallic metal-organic frameworks (InBi-MOFs). The IBS was constructed with a full hollow structure owing to the different diffusion velocity of the metal ions and S²⁻ ions, while the IBO was formed with a yolk-shell structure due to the existence of the temperature gradient from the exterior shell to the inner yolk in the pyrolysis process. The IBS and IBO showed superior H₂ production rate of 22.73 and 3.6 mmol g^-1 h^-1, which were approximately 13.2 and 4.1 times higher than that of single In₂S₃ and In₂O₃ due to the effects of hierarchical hollow structures and Z-scheme heterojunction. The unique full hollow and yolk-shell structures could be clearly revealed by transmission electron microscopy, while the Z-scheme electron migrate pathway was thoroughly confirmed by various experimental studies and density functional theory calculation.