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Flexible Frameworks and Physical Properties of Compounds with Transition Metals, Derived from Ellenbergerite and β-Tridymite

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Abstract

The specific features of crystal chemistry and physical properties of phosphates (arsenates, vanadates) of alkali and transition metals, crystallized as derivatives of minerals ellenbergerite (Mg,Ti,Zr,\(\square \))2Mg6(A1,Mg)6(Si,P)2Si6O28(OH)10 and β-tridymite SiO2, have been analyzed in the aspect of flexibility of their radically different frameworks. The crystal chemical function of cations of transition metals in the structures of ellenbergerite- and tridymite-like analogs has been discussed. The data on their formation methods and thermodynamic and electrical properties are given. The reasons for the structural differences of tridymite-like phases and the relationship between the polymorphism and variations in the coordination polyhedra of transition metals, tending to the most stable configuration, have been investigated.

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Funding

This study was supported by the Russian Foundation for Basic Research, project no. 18-03-00908а.

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  1. Moscow State University, Moscow, Russia

    L. V. Shvanskaya & O. V. Yakubovich

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  1. L. V. Shvanskaya
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Correspondence to L. V. Shvanskaya.

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Translated by Yu. Sin’kov

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Shvanskaya, L.V., Yakubovich, O.V. Flexible Frameworks and Physical Properties of Compounds with Transition Metals, Derived from Ellenbergerite and β-Tridymite. Crystallogr. Rep. 66, 10–28 (2021). https://doi.org/10.1134/S106377452101017X

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