Skip to main content

Natural and Synthetic Layered Pb(II) Oxyhalides

  • Chapter
  • First Online:
Minerals as Advanced Materials II

Abstract

Lead oxyhalides occur under variety of natural and technological conditions. They can be found as secondary minerals in oxidation zones of mineral deposits. For instance, Merehead quarry in England is the famous place for many findings of lead oxyhalides first described in 1923 by Spencer and Mountain (1923). Genesis of these deposits is still a topic of discussions. The most recent version points out that galena deposits were emplaced into limestones during the Triassic period (Turner 2006). Afterwards, they were locally exposed to the action of seawater. Oxidation of galena initiated deposition of manganate minerals from the seawater as well as adsorption of heavy metals from both seawater and local environment.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  • Aurivillius B (1982) On the crystal structure of a number of non-stoichiometric mixed lead oxide halides composed of PbO like blocks and single halogen layers. Chem Scr 19:97–107

    Google Scholar 

  • Boher P, Garnier P, Gavarri JR (1985) Monoxyde quadratique PbO alpha (I): description de la transition structurale ferroelastique. J Solid State Chem 57:343–350. doi:10.1016/0022-4596(85)90197-5

    Article  Google Scholar 

  • Edwards R, Gillard RD, Williams PA, Pollard AM (1992) Studies of secondary mineral formation in the PbO-H2O-HCl system. Miner Mag 56:53–65

    Article  Google Scholar 

  • Gabuda SP, Kozlova SG, Terskikh VV, Dybowski C, Neue G, Perry DL (1999) 207Pb NMR study of novel Pb-Pb chemical bonding in lead monoxides, α-PbO and β-PbO. Chem Phys Lett 305:353–358. doi:10.1016/S0009-2614(99)00407-8

    Article  Google Scholar 

  • Krivovichev SV (2004) Crystal structures and cellular automata. Acta Crystallogr A60:257–262. doi:10.1107/S0108767304007585

    Google Scholar 

  • Krivovichev SV (2008) Minerals with antiperovskite structure: a review. Z Kristallogr 223:109–113. doi:10.1524/zkri.2008.0008

    Article  Google Scholar 

  • Krivovichev SV, Burns PC (2006) The crystal structure of Pb8O5(OH)2Cl4, a synthetic analogue of blixite? Can Miner 44:515–522. doi:10.2113/gscanmin.44.2.515

    Article  Google Scholar 

  • Krivovichev SV, Filatov SK (1999) Metal arrays in structural units based on anion-centered metal tetrahedra. Amer Miner 84:1099–1106

    Google Scholar 

  • Krivovichev SV, Armbruster T, Depmeier W (2004) Crystal structures of Pb8O5(AsO4)2 and Pb5O4(CrO4), and review of PbO-related structural units in inorganic compounds. J Solid State Chem 77:1321–1332. doi:10.1016/j.jssc.2003.11.005

    Article  Google Scholar 

  • Krivovichev SV, Siidra OI, Nazarchuk EV, Burns PC, Depmeier W (2006) Exceptional topological complexity of lead oxide blocks in Pb31O22X18 (X = Br, Cl). Inorg Chem 45:3846–3848. doi:10.1021/ic060166m

    Article  Google Scholar 

  • Krivovichev SV, Turner R, Rumsey M, Siidra OI, Kirk CA (2009) The crystal structure and chemistry of mereheadite. Miner Mag 73:75–89. doi:10.1180/minmag.2009.073.1.103

    Article  Google Scholar 

  • Lepore GO, Welch MD (2010) The crystal structure of parkinsonite, nominally Pb7MoO9Cl2: a naturally occurring Aurivillius phase. Miner Mag 74:269–275. doi:10.1180/minmag. 2010.074.2.269

    Article  Google Scholar 

  • Liao J-H, Kanatzidis MG (1993) Quaternary rubidium copper tin sulfides (Rb2Cu2SnS4, A2Cu2Sn2S6 (A = Na, K, Rb, Cs), A2Cu2Sn2Se6 (A = K, Rb), potassium gold tin sulfides, K2Au2SnS4, and K2Au2Sn2S6. Syntheses, structures, and properties of new solid-state chalcogenides based on tetrahedral [SnS4]4- units. Chem Mater 5:1561–1569. doi:10.1021/cm00034a029

    Article  Google Scholar 

  • Post J, Buseck PR (1985) Quantitative energy dispersive analysis of lead halide particles from the Phoenix urban aerosol. Environ Sci Technol 19:682–685. doi:10.1021/es00138a004

    Article  Google Scholar 

  • Pyykkö P (1988) Relativistic effects in structural chemistry. Chem Rev 88:563–594. doi:10.1021/cr00085a006

    Article  Google Scholar 

  • Sigman MB Jr, Korgel BA (2005) Strongly birefringent Pb3O2Cl2 nanobelts. J Am Chem Soc 127:10089–10095. doi:10.1021/ja051956i

    Article  Google Scholar 

  • Siidra OI, Krivovichev SV, Depmeier W (2006) Method of square lattices for the description of structural topologies of minerals and inorganic compounds derivatives of tetragonal PbO (litharge). Vestn S-Peterb U Geol 3:18–26

    Google Scholar 

  • Siidra OI, Krivovichev SV, Depmeier W (2007) Structure and mechanism of the ionic conductivity of the nonstoichiometric compound Pb2+xOCl2+2x. Dokl Phys Chem 414:128–131. doi:10.1134/S0012501607060024

    Article  Google Scholar 

  • Siidra OI, Krivovichev SV, Filatov SK (2008) Minerals and synthetic Pb(II) compounds with oxocentered tetrahedra: review and classification. Z Kristallogr 223:114–126. doi:10.1524/zkri.2008.0009

    Article  Google Scholar 

  • Siidra OI, Krivovichev SV, Depmeier W (2009) Crystal structure of Pb6O[(Si6Al2)O20]. Glass Phys Chem 35:406–410. doi:10.1134/S1087659609040099

    Article  Google Scholar 

  • Smith WH (1976) Lead contamination of the roadside ecosystem. J Air Pollut Control Assoc 26:753–766

    Article  Google Scholar 

  • Spencer LJ, Mountain ED (1923) New lead-copper minerals from the Mendip Hills, Somerset, England. Miner Mag 20:67–92

    Article  Google Scholar 

  • Steele IM, Pluth JJ, Jr Richardson JW (1997) Crystal structure of tribasic lead sulfate (3PbO·PbSO4·H2O) by X-rays and neutrons: an intermediate phase in the production of lead acid batteries. J Solid State Chem 132:173–181. doi:10.1006/jssc.1997.7440

    Article  Google Scholar 

  • Turner R (2006) A mechanism for the formation of the mineralized Mn deposits at Merehead Quarry, Cranmore, Somerset, England. Miner Mag 70:629–653. doi:10.1180/0026461067060359

    Article  Google Scholar 

  • Welch MD (2004) Pb-Si ordering in sheet-oxychloride minerals: the super-structure of asisite, nominally Pb7SiO8Cl2. Miner Mag 68:247–254. doi:10.1180/0026461046820185

    Article  Google Scholar 

  • Welch MD, Criddle AJ, Symes RF (1998) Mereheadite, Pb2O(OH)Cl: a new litharge-related oxychloride from Merehead Quarry, Cranmore, Somerset. Miner Mag 62:387–393

    Article  Google Scholar 

Download references

Acknowledgements

This work was financially supported by Russian President grant (MК-1645.2009.5), Deutsche Forschungsgemeinschaft (DE 412/45-1) and Russian Federal Programme “Scientific Cadres for Innovative Russia” (state contract # 02.740.11.0326).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Oleg I. Siidra .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2011 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Siidra, O.I., Krivovichev, S.V., Turner, R.W., Rumsey, M.S. (2011). Natural and Synthetic Layered Pb(II) Oxyhalides. In: Krivovichev, S. (eds) Minerals as Advanced Materials II. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-20018-2_30

Download citation

Publish with us

Policies and ethics