Diacetamide
- Formula: C4H7NO2
- Molecular weight: 101.1039
- IUPAC Standard InChI: InChI=1S/C4H7NO2/c1-3(6)5-4(2)7/h1-2H3,(H,5,6,7)
- IUPAC Standard InChIKey: ZSBDPRIWBYHIAF-UHFFFAOYSA-N
- CAS Registry Number: 625-77-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: CH3C(O)NHC(O)CH3; Bisacetylamine; Acetamide, N-acetyl-; Dicetylamine; N-Acetylacetamide; Diacetylamine
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Reaction thermochemistry data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
B - John E. Bartmess
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Individual Reactions
+
=
+
By formula: C4H7NO2 + H2O = C2H5NO + C2H4O2
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -18.1 ± 0.2 | kJ/mol | Cm | Hill and Wadso, 1968 | solid phase; Heat of hydrolysis; ALS |
| ΔrH° | -18.1 ± 0.2 | kJ/mol | Cm | Wadso, 1965 | solid phase; Heat of hydrolysis; ALS |
C4H6NO2- + =
By formula: C4H6NO2- + H+ = C4H7NO2
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 1451. ± 15. | kJ/mol | G+TS | Cumming and Kebarle, 1978 | gas phase; B |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 1422. ± 8.4 | kJ/mol | IMRE | Cumming and Kebarle, 1978 | gas phase; B |
References
Go To: Top, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hill and Wadso, 1968
Hill, J.O.; Wadso, I.,
Some thermochemical properties of N,N,N-triacetylammonia,
Acta Chem. Scand., 1968, 22, 1590-1594. [all data]
Wadso, 1965
Wadso, I.,
Thermochemical properties of diacetimide, N-butyldiacetimide and N-phenyldiacetimide,
Acta Chem. Scand., 1965, 19, 1079-1087. [all data]
Cumming and Kebarle, 1978
Cumming, J.B.; Kebarle, P.,
Summary of gas phase measurements involving acids AH. Entropy changes in proton transfer reactions involving negative ions. Bond dissociation energies D(A-H) and electron affinities EA(A),
Can. J. Chem., 1978, 56, 1. [all data]
Notes
Go To: Top, Reaction thermochemistry data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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