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Boothite

A valid IMA mineral species - grandfathered
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About BoothiteHide

Formula:
CuSO4 · 7H2O
Colour:
Light blue; light blue in transmitted light
Lustre:
Vitreous, Silky, Pearly
Hardness:
2 - 2½
Specific Gravity:
1.94
Crystal System:
Monoclinic
Name:
After Edward Booth (July 1857 – 24 August 1917, California, USA) chemist at the University of California. He directed Waldemar Schaller, who described the mineral, to the sulfate occurrence where boothite was discovered.
Melanterite Group.

This mineral, fully hydrated copper sulphate, is very rare. The partially hydrated copper sulphate mineral, chalcanthite, is much more common.


Unique IdentifiersHide

Mindat ID:
720
Long-form identifier:
mindat:1:1:720:3
GUID
(UUID V4):
da6d9d5b-9014-42a5-b7de-c49e972fa73a

IMA Classification of BoothiteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Cu(SO4) · 7H2O
First published:
1903

Classification of BoothiteHide

7.CB.35

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
C : Sulfates (selenates, etc.) without additional anions, with H2O
B : With only medium-sized cations
29.6.10.2

29 : HYDRATED ACID AND NORMAL SULFATES
6 : AXO4·xH2O
25.2.4

25 : Sulphates
2 : Sulphates of Cu and Ag

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
BooIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of BoothiteHide

Vitreous, Silky, Pearly
Transparency:
Transparent, Translucent
Comment:
Silky or pearly luster on fibrous material.
Colour:
Light blue; light blue in transmitted light
Hardness:
2 - 2½ on Mohs scale
Tenacity:
Brittle
Cleavage:
Imperfect/Fair
On {001} imperfect.
Fracture:
Irregular/Uneven
Density:
1.94 g/cm3 (Measured)    
Comment:
Value approximate.

Optical Data of BoothiteHide

Type:
Biaxial (+/-)
RI values:
nα = 1.470 nβ = 1.480 nγ = 1.490
Max Birefringence:
δ = 0.020
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
relatively weak
Optical Extinction:
Y = b; X ≃ c.
Comments:
2V(meas.) = Large

Chemistry of BoothiteHide

Mindat Formula:
CuSO4 · 7H2O

Crystallography of BoothiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Setting:
P21/c
Cell Parameters:
a = 14.190(10) Å, b = 6.537(2) Å, c = 10.825(6) Å
α = 106.02(5)°
Ratio:
a:b:c = 2.171 : 1 : 1.656
Unit Cell V:
0.00 ų (Calculated from Unit Cell)
Morphology:
Crystals rare. Commonly massive with crystalline or fibrous structure.
Comment:
Cell parameters and space group from Leverett et al. (2004).

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
5.358 Å(22)
5.378 Å(13)
4.890 Å(100)
4.826 Å(43)
2.798 Å(33)
3.269 Å(20)
2.730 Å(11)
Comments:
Data from Leverett et al. (2004).

Geological EnvironmentHide

Type Occurrence of BoothiteHide

General Appearance of Type Material:
Fibrous or crystalline massive.
Place of Conservation of Type Material:
n.d.
Geological Setting of Type Material:
Zone of oxidation.
Associated Minerals at Type Locality:
Reference:
Schaller, W.T. (1903) Minerals from Leona Heights, Alameda Co., California. University of California Publications. Bulletin of the Department of Geology: 3: 191-217.

Synonyms of BoothiteHide

Other Language Names for BoothiteHide

German:Boothit
Spanish:Boothita

Varieties of BoothiteHide

Iron-bearing BoothiteAn iron-rich boothite.
Originally reported from Salvadora Mine, Calama, El Loa Province, Antofagasta Region, Chile.
Magnesium-bearing BoothiteA Mg-bearing variety of boothite.

Relationship of Boothite to other SpeciesHide

Other Members of this group:
Alpersite(Mg,Cu)(SO4) · 7H2OMon. 2/m : P21/b
BieberiteCoSO4 · 7H2OMon. 2/m : P2/m
MallarditeMnSO4 · 7H2OMon. 2/m : P2/m
MelanteriteFe2+(H2O)6SO4 · H2OMon. 2/m : P21/b
Zincmelanterite(Zn,Cu,Fe)SO4 · 7H2OMon. 2/m : P21/b

Common AssociatesHide

Associated Minerals Based on Photo Data:
2 photos of Boothite associated with ArseniosideriteCa2Fe3+3(AsO4)3O2 · 3H2O
2 photos of Boothite associated with CuprocopiapiteCu2+Fe3+4(SO4)6(OH)2 · 20H2O
1 photo of Boothite associated with PyriteFeS2

Related Minerals - Strunz-mindat GroupingHide

7.CB.SarvodaiteAl2(SO4)3 · 5H2O Mon. 2/m : P21/m
7.CB.02VoudourisiteCdSO4 · H2OMon. 2/m : P21/m
7.CB.05DwornikiteNi(SO4) · H2OMon. 2/m : B2/b
7.CB.05GunningiteZnSO4 · H2OMon. 2/m : B2/b
7.CB.05KieseriteMgSO4 · H2OMon. 2/m : B2/b
7.CB.05Poitevinite(Cu,Fe)SO4 · H2OTric. 1 : P1
7.CB.05SzmikiteMnSO4 · H2OMon. 2/m : B2/b
7.CB.05SzomolnokiteFeSO4 · H2OMon. 2/m : B2/b
7.CB.05CobaltkieseriteCoSO4 · H2OMon. 2/m : B2/b
7.CB.07SanderiteMgSO4 · 2H2OOrth. 2 2 2 : P21 21 21
7.CB.10BonattiteCuSO4 · 3H2OMon. m : Bb
7.CB.12BelogubiteCuZn(SO4)2 · 10H2OTric. 1 : P1
7.CB.15Aplowite(Co,Mn,Ni)SO4 · 4H2OMon. 2/m
7.CB.15Boyleite(Zn,Mg)SO4 · 4H2OMon. 2/m : P21/b
7.CB.15Ilesite(Mn,Zn,Fe)SO4 · 4H2OMon. 2/m
7.CB.15RozeniteFeSO4 · 4H2OMon. 2/m : P21/b
7.CB.15StarkeyiteMgSO4 · 4H2OMon. 2/m : P21/b
7.CB.15DrobeciteCdSO4 · 4H2OMon. 2/m : P21/m
7.CB.15CranswickiteMgSO4 · 4H2OMon. m : Bb
7.CB.20ChalcanthiteCuSO4 · 5H2OTric. 1 : P1
7.CB.20JôkokuiteMnSO4 · 5H2OTric. 1 : P1
7.CB.20PentahydriteMgSO4 · 5H2OTric. 1 : P1
7.CB.20SiderotilFeSO4 · 5H2OTric.
7.CB.25BianchiteZn(SO4) · 6H2OMon. 2/m : P2/m
7.CB.25ChvaleticeiteMn(SO4) · 6H2OMon. 2/m : B2/b
7.CB.25FerrohexahydriteFeSO4 · 6H2OMon. 2/m : B2/b
7.CB.25HexahydriteMgSO4 · 6H2OMon. 2/m : P2/m
7.CB.25MoorhouseiteCo(SO4) · 6H2OMon. 2/m : B2/b
7.CB.25NickelhexahydriteNi(SO4) · 6H2OMon. 2/m : B2/b
7.CB.30RetgersiteNiSO4 · 6H2OTet. 4 2 2 : P41 21 2
7.CB.35BieberiteCoSO4 · 7H2OMon. 2/m : P2/m
7.CB.35MallarditeMnSO4 · 7H2OMon. 2/m : P2/m
7.CB.35MelanteriteFe2+(H2O)6SO4 · H2OMon. 2/m : P21/b
7.CB.35Zincmelanterite(Zn,Cu,Fe)SO4 · 7H2OMon. 2/m : P21/b
7.CB.35Alpersite(Mg,Cu)(SO4) · 7H2OMon. 2/m : P21/b
7.CB.40EpsomiteMgSO4 · 7H2OOrth. 2 2 2 : P21 21 21
7.CB.40GoslariteZnSO4 · 7H2OOrth. 2 2 2 : P21 21 21
7.CB.40MorenositeNiSO4 · 7H2OOrth. 2 2 2 : P21 21 21
7.CB.45AlunogenAl2(SO4)3 · 17H2OTric. 1 : P1
7.CB.45Meta-alunogenAl2(SO4)3 · 12H2OOrth.
7.CB.50AluminocoquimbiteAl2Fe2(SO4)6(H2O)12 · 6H2OTrig. 3m (3 2/m) : P3 1c
7.CB.50Lazaridisite3CdSO4 · 8H2OMon. 2/m : B2/b
7.CB.52PararaisaiteCuMg[Te6+O4(OH)2] · 6H2OMon. 2/m : P21/b
7.CB.55CoquimbiteAlFe3(SO4)6(H2O)12 · 6H2OTrig. 3m (3 2/m) : P3 1c
7.CB.55ParacoquimbiteFe4(SO4)6(H2O)12 · 6H2OTrig. 3 : R3
7.CB.55Rhomboclase(H5O2)Fe3+(SO4)2 · 2H2OOrth. mmm (2/m 2/m 2/m) : Pnma
7.CB.55RaisaiteCuMg[Te6+O4(OH)2] · 6H2OMon. 2/m : B2/b
7.CB.57CaichengyuniteFe2+3Al2(SO4)6 · 30H2OMon.
7.CB.60KorneliteFe2(SO4)3 · 7H2OMon. 2/m : P21/m
7.CB.65QuenstedtiteFe2(SO4)3 · 11H2OTric. 1 : P1
7.CB.70LauseniteFe2(SO4)3 · 5H2OMon. 2/m : P21/m
7.CB.75LishizheniteZnFe2(SO4)4 · 14H2OTric. 1 : P1
7.CB.75RömeriteFe2+Fe3+2(SO4)4 · 14H2OTric. 1 : P1
7.CB.80RansomiteCuFe2(SO4)4 · 6H2OMon. 2/m : P21/b
7.CB.85ApjohniteMn2+Al2(SO4)4 · 22H2OMon. 2/m : P21/b
7.CB.85BíliniteFe2+Fe3+2(SO4)4 · 22H2OMon. 2/m : P21/b
7.CB.85Dietrichite(Zn,Fe2+,Mn2+)Al2(SO4)4 · 22H2OMon. 2/m : P21/b
7.CB.85HalotrichiteFeAl2(SO4)4 · 22H2OMon. 2 : P2
7.CB.85PickeringiteMgAl2(SO4)4 · 22H2OMon. 2/m : P21/b
7.CB.85Redingtonite(Fe2+,Mg,Ni)(Cr,Al)2(SO4)4 · 22H2OMon. 2
7.CB.85Wupatkiite(Co,Mg,Ni)Al2(SO4)4 · 22H2OMon. 2/m : P21/b
7.CB.90MeridianiiteMgSO4 · 11H2OTric. 1 : P1

Other InformationHide

Notes:
Readily soluble in cold water.
Special Storage/
Display Requirements:
Dehydrates to chalcanthite. Virtually impossible to preserve in an artificial environment.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for BoothiteHide

References for BoothiteHide

Localities for BoothiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Australia
 
  • New South Wales
    • Georgiana Co.
      • Burraga
Leverett et al. (2004) +1 other reference
  • Tasmania
    • West Coast municipality
      • Queenstown district
        • Queenstown
Ralph Bottrill et al in prep. +1 other reference
Bottrill et al. (2008)
Chile
 
  • Antofagasta
    • El Loa Province
      • Calama
Hey +1 other reference
France
 
  • Auvergne-Rhône-Alpes
    • Rhône
      • Villefranche-sur-Saône
        • Chessy
Coueille (1988)
        • Sain-Bel
Palache et al. (1951) +1 other reference
Greece
 
  • Attica
    • East Attica
      • Lavreotiki
        • Lavrion Mining District
          • Km 3
            • Kaminiza mines
Rieck et al. (2022)
Italy
 
  • Campania
    • Naples
      • Somma-Vesuvius Complex
Scacchi (1872) +2 other references
Scacchi (1872) +1 other reference
  • Trentino-Alto Adige (Trentino-South Tyrol)
    • Trento Province (Trentino)
      • Levico Terme
Exel (1987)
Norway
 
  • Agder
    • Evje og Hornnes
      • Flåt
Garmo (1974) +2 other references
  • Vestland
    • Kvinnherad
      • Ølve mining district
Ellingsen (1989) +1 other reference
Russia
 
  • Kamchatka Krai
    • Milkovsky District
maurice.strahlen.org (n.d.)
USA
 
  • Arizona
    • Cochise County
      • Bisbee
        • Hendricks Gulch
Grant et al. (2005)
    • Graham County
      • Aravaipa Mining District
        • Klondyke
          • Grand Reef Mountain
            • Laurel Canyon
Mineralogical Record 11:225 +1 other reference
    • Yavapai County
      • Bradshaw Mountains (Bradshaw Range)
        • Agua Fria Mining District
          • Mayer
Brian Beck Collected
  • California
    • Alameda County
      • Oakland Hills (San Leandro Hills)
        • Oakland
          • Leona Heights
            • Leona Heights deposit
Van Nostrand Reinholt Press: 296. +5 other references
[Mineralogical Record 20 129-142]
    • Calaveras County
      • Foothill Copper Belt
        • Campo Seco Mining District
Palache et al. (1951)
Van Nostrand Reinholt Press: 297. +6 other references
    • San Bernardino County
      • Silver Lake Mining District
        • Soda Mountains
    • Santa Barbara County
      • San Rafael Mountains
        • Cachuma Mining District
          • Cachuma Village
            • Figueroa Mountain
              • Tunnel Ranch
Murdoch (1966)
  • Massachusetts
    • Franklin County
      • Rowe
  • Montana
    • Silver Bow County
      • Butte Mining District (Summit Valley Mining District)
Mineralogical Society of America - ...
  • Nevada
Castor et al. (2004)
      • Battle Mountain Mining District
Rob Lavinsky
  • Utah
    • San Juan County
Finnell et al. (1963)
Finnell et al. (1963) +1 other reference
 
Mineral and/or Locality  
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